FOAM PARTICLE MOULDED ARTICLE, SOLE CUSHION, AND METHOD FOR PRODUCING FOAM PARTICLES

    公开(公告)号:US20190276627A1

    公开(公告)日:2019-09-12

    申请号:US16349236

    申请日:2017-11-13

    Abstract: The present invention relates to an in-mold expanded beads molded article of expanded beads of an olefin thermoplastic elastomer, a cushion for shoe sole, and a method of producing expanded beads provided with through-holes and composed of a block copolymer of a polyethylene block and an ethylene/α-olefin copolymer block, and with respect to the in-mold expanded beads molded article of expanded beads of an olefin thermoplastic elastomer, a voidage of the expanded beads molded article is 5 to 40%; a density of the expanded beads molded article is 30 to 150 g/L; and a flexural modulus of the olefin thermoplastic elastomer that constitutes the expanded beads molded article is 10 to 100 MPa.

    Propylene resin foam particles and foam particle molded article

    公开(公告)号:US10336880B2

    公开(公告)日:2019-07-02

    申请号:US15542261

    申请日:2015-01-09

    Abstract: Provided is an expanded propylene resin bead including a core layer in a foamed state, which includes a propylene-based resin composition (a) satisfying the following (i) and (ii); and a cover layer which includes an olefin-based resin (b) satisfying the following (iii) or (iv): (i) the propylene-based resin composition (a) is a mixture of 65% by weight to 98% by weight of a propylene-based resin (a1) having a melting point of 145° C. to 165° C. and a flexural modulus of 1,200 MPa or more and 35% by weight to 2% by weight of a propylene-based resin (a2) having a melting point of 100° C. to 145° C. and a flexural modulus of 800 MPa to 1,200 MPa; (ii) a difference in a melting point between the resin (a1) and the resin (a2) is 5° C. to 25° C.; (iii) the olefin-based resin (b) is a crystalline olefin-based resin having a melting point (TmB) that is lower than a melting point (TmA) of the composition (a) and being in a relation of (0° C.

    POLYOLEFIN RESIN FOAM PARTICLES, FOAM-PARTICLE MOULDED BODY, AND COMPOSITE STACKED BODY INCLUDING SAID MOULDED BODY
    78.
    发明申请
    POLYOLEFIN RESIN FOAM PARTICLES, FOAM-PARTICLE MOULDED BODY, AND COMPOSITE STACKED BODY INCLUDING SAID MOULDED BODY 审中-公开
    聚烯烃树脂泡沫颗粒,泡沫塑料体,以及复合层压体,包括模压体

    公开(公告)号:US20170009038A1

    公开(公告)日:2017-01-12

    申请号:US14914598

    申请日:2015-03-20

    Abstract: The present invention relates to polyolefin resin expanded beads containing multi-layer expanded beads containing a core layer in a foamed state containing a polyolefin resin and a cover layer coated on the core layer, the cover layer containing a mixed resin of a polyolefin resin (A) and at least one resin (B) selected from a polystyrene resin and a polyester resin, and the mixed resin having a weight ratio (A/B) of the polyolefin resin (A) and the resin (B) of from 15/85 to 90/10, and a composite laminated body using an expanded beads molded body thereof, and the expanded beads molded body is excellent in solvent resistance and also excellent in adhesiveness to a thermosetting resin on the surface of the molded body, and can provide a composite laminated body excellent in productivity with a thermosetting resin.

    Abstract translation: 本发明涉及含有多层发泡珠粒的聚烯烃树脂发泡珠,该多层发泡珠含有包含聚烯烃树脂的发泡状态的核心层和涂覆在芯层上的覆盖层,该覆盖层含有聚烯烃树脂(A )和至少一种选自聚苯乙烯树脂和聚酯树脂的树脂(B),聚烯烃树脂(A)和树脂(B)的重量比(A / B)为15/85 90/10以及使用其发泡珠粒成型体的复合层压体,发泡珠成型体的耐溶剂性优异,且与成型体的表面的热固性树脂的粘合性优异,可以提供 复合层叠体,其热固性树脂的生产率优异。

    POLYOLEFIN RESIN PARTICLES, POLYOLEFIN RESIN FOAMED PARTICLES, AND METHOD FOR PRODUCING POLYOLEFIN RESIN FOAMED PARTICLES
    79.
    发明申请
    POLYOLEFIN RESIN PARTICLES, POLYOLEFIN RESIN FOAMED PARTICLES, AND METHOD FOR PRODUCING POLYOLEFIN RESIN FOAMED PARTICLES 有权
    聚烯烃树脂颗粒,聚烯烃树脂泡沫颗粒和生产聚烯烃树脂泡沫颗粒的方法

    公开(公告)号:US20160333162A1

    公开(公告)日:2016-11-17

    申请号:US15111150

    申请日:2015-01-13

    Inventor: Hidehiro SASAKI

    Abstract: The present invention provides polyolefin resin particles that are capable of producing expanded polyolefin resin beads having a favorable fine cell structure, expanded polyolefin resin beads that suffer less volume shrinkage under a high temperature environment and are excellent in recovery property on repeated compression, and a method for producing the expanded beads. The polyolefin resin particles of the present invention have a peak temperature (T1) of a melting peak on first heating in a DSC curve obtained by heating the resin particles from 20° C. to 200° C. at a heating rate of 10° C./min that is higher by 1.5° C. or more than a peak temperature (T2) of a melting peak on second heating in a DSC curve obtained by, subsequent to the first heating, cooling the resin particles from 200° C. to 20° C. at a cooling rate of 10° C./min, and then heating the resin particles from 20° C. to 200° C. at a heating rate of 10° C./min. The method for producing expanded polyolefin resin beads of the present invention includes: a step of preparing preliminary resin particles containing a polyolefin resin; a step of heat-treating the preliminary resin particles at a temperature that is higher by from 15 to 25° C. than a melting point of the preliminary resin particles, so as to produce resin particles; and a step of expanding the resin particles.

    Abstract translation: 本发明提供能够制造具有良好细孔结构的发泡聚烯烃树脂珠粒的聚烯烃树脂颗粒,在高温环境下具有较小体积收缩率的膨胀聚烯烃树脂珠粒,并且在重复压缩时的回收性能优异的方法 用于生产发泡珠。 本发明的聚烯烃树脂颗粒在通过以10℃的加热速度将树脂颗粒从20℃加热到200℃而获得的DSC曲线中,在第一次加热时具有熔融峰的峰值温度(T1) 。/ min,高于1.5℃或高于DSC曲线中的第二次加热时的熔融峰的峰值温度(T2),通过在第一次加热之后,将树脂颗粒从200℃冷却至 20℃,以10℃/分钟的冷却速度,然后以10℃/分钟的加热速率将树脂颗粒从20℃加热至200℃。 本发明的发泡聚烯烃树脂珠粒的制造方法包括:制备含有聚烯烃树脂的预备树脂粒子的工序; 在比预备树脂颗粒的熔点高15至25℃的温度下对预备树脂颗粒进行热处理以生产树脂颗粒的步骤; 和使树脂粒子膨胀的工序。

    POLYLACTIC ACID-BASED RESIN EXPANDED BEADS AND MOLDED ARTICLE THEREOF
    80.
    发明申请
    POLYLACTIC ACID-BASED RESIN EXPANDED BEADS AND MOLDED ARTICLE THEREOF 审中-公开
    基于聚氨酯的树脂膨胀珠及其成型品

    公开(公告)号:US20160032070A1

    公开(公告)日:2016-02-04

    申请号:US14881800

    申请日:2015-10-13

    Abstract: Polylactic acid-based resin expanded beads obtained by releasing a softened, pressurized foamable resin composition, which has a polylactic acid-based resin and a physical blowing agent, to a low pressure atmosphere to foam and expand the resin composition, where the polylactic acid-based resin satisfies the conditions (1) to (3) shown below, and exhibits excellent secondary expansion properties and fusion bonding properties. A polylactic acid-based resin expanded beads molded article obtained by in-mold molding of the polylactic acid-based resin expanded beads exhibits excellent mechanical properties. MT≦30 mN  (1) log MT≦0.93 log η−1.75  (2) CT1/2≧600 sec  (3) where MT represents a melt tension [mN] at 190° C., η represents a melt viscosity [Pa·s] at 190° C. and a shear speed of 20 sec−1, and CT1/2 represents a half crystallization time [sec] at 110° C.

    Abstract translation: 通过将具有聚乳酸类树脂和物理发泡剂的软化的加压发泡树脂组合物释放到低压气氛中以使树脂组合物发泡和膨胀而获得的聚乳酸类树脂发泡珠粒,其中聚乳酸 - 基于树脂的树脂满足下述条件(1)至(3),并且显示出优异的二次膨胀性和熔融粘合性。 通过聚乳酸类树脂发泡粒子的模内成型得到的聚乳酸类树脂发泡粒子成型体的机械特性优异。 MT≦̸ 30mN(1)log MT≦̸ 0.93log&eegr; -1.75(2)CT1 /2≥600秒(3)其中MT表示在190℃下的熔体张力[mN] 表示190℃下的熔融粘度[Pa·s],剪切速度为20秒-1,CT1 / 2表示110℃下的半结晶时间[秒]。

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