Method of recovering valuable metals from waste materials, particularly from spent petroleum cracking catalysts
    71.
    发明公开
    Method of recovering valuable metals from waste materials, particularly from spent petroleum cracking catalysts 失效
    从废物中回收有价值金属的方法,特别是从石油裂化催化剂

    公开(公告)号:EP0150438A3

    公开(公告)日:1988-03-16

    申请号:EP84115725

    申请日:1984-12-18

    CPC classification number: C22B23/02 C22B7/009 C22B34/22 Y02P10/214

    Abstract: The invention is directed to a process of treating waste materials, particularly petroleum cracking catalyst waste containing contaminating and/or valuable metals to decontaminate the waste and/or recover the metals therefrom which process comprises the reduction of the metals contained in the waste in the presence of a slag former such as a silica-alumina composite, a flux such as a Group IA or IIA oxide and a phosphate containing compound. The metals are recovered as metals or metal phosphides in a distinct ferrophos layer. The accumulated metals can be further processed to recover the metal content thereof. The process parallels the electrothermal process for producing phosphorus which is desirably utilized as disclosed herein to recover valuable Group VB to Group VIII metals.

    Abstract translation: 本发明涉及处理废物的方法,特别是含有污染和/或有价值金属的石油裂化催化剂废物以净化废物和/或从中回收金属,该方法包括在存在下还原废弃物中所含的金属 的诸如二氧化硅 - 氧化铝复合材料的助熔剂,诸如IAA或IIA族氧化物的助熔剂和含磷酸盐的化合物。 金属作为金属或金属磷化物在不同的磷酸盐层中回收。 可以进一步处理积聚的金属以回收其金属含量。 该方法与用于生产磷的电热方法相似,如本文所公开的,其被期望地用于回收有价值的VB族至VIII族金属。

    Method of preparation and use of solid, phytoactive compositions
    72.
    发明公开
    Method of preparation and use of solid, phytoactive compositions 失效
    Verfahren zur Herstellung und Verwendung fester,pflanzenwirksamer Zusammensetzungen。

    公开(公告)号:EP0256608A2

    公开(公告)日:1988-02-24

    申请号:EP87201554.0

    申请日:1987-08-17

    CPC classification number: C07F9/3813 A01N25/30 A01N57/20 A01N2300/00

    Abstract: A method for the preparation of a solid, phytoactive composition comprising: (a) reacting an acid form of a phytoactive N-phosphonomethyl-­N-carboxylmethyl compound with a liquid amine to form the amine salt of said N-phosphonomethyl-N-carboxylmethyl compound; (b) admixing said amine salt of said N-phosphonomethyl-N-carboxylmethyl compound with a molten surfactant, the surfactant being solid at ambient temperatures; and (c) cooling said mixture to a temperature below the melting point of the sur­factant to form a composition comprising said surfactant and said amine salt of N-phosphonomethyl-N-carboxylmethyl compound interdispersed in the matrix thereof and which is solid at ambient temperatures.

    Abstract translation: 一种制备固体植物组合物的方法,包括:(a)将酸形式的植物活性N-膦酰基甲基-N-羧基甲基化合物与液体胺反应,形成所述N-膦酰基甲基-N-羧基甲基化合物的胺盐 ; (b)将所述N-膦酰基甲基-N-羧基甲基化合物的所述胺盐与熔融的表面活性剂混合,所述表面活性剂在环境温度下为固体; 和(c)将所述混合物冷却至低于表面活性剂熔点的温度,以形成包含所述表面活性剂和所述N-膦酰基甲基-N-羧甲基化合物的胺盐的组合物,其分散于其基质中,并且在环境温度下为固体。

    Process for preparing tin alkoxides
    73.
    发明公开
    Process for preparing tin alkoxides 失效
    Verfahren zur Herstellung von Zinnalkoholaten。

    公开(公告)号:EP0252543A2

    公开(公告)日:1988-01-13

    申请号:EP87201065.7

    申请日:1987-06-05

    CPC classification number: C07C29/70 C07C31/28

    Abstract: Tin tetra-alkoxides absent halogenic impurities are prepared by a two-step process comprising a first step reaction of tin tetrahalide with an alcohol and ammonia. A second step reacts the product of the first step with a metal amide and additional alcohol. An alternative second step reacts the product of the first step with a metal alkoxide.

    Abstract translation: 不含卤素杂质的四烷氧基锡通过两步法制备,包括四卤化锡与醇和氨的第一步反应。 第二步使第一步的产物与金属酰胺和另外的醇反应。 替代的第二步骤是使第一步的产物与金属醇盐反应。

    Certain 3-(substituted thio)-2-benzoyl-cyclohex-2-enones
    74.
    发明公开
    Certain 3-(substituted thio)-2-benzoyl-cyclohex-2-enones 失效
    3-(硫代substituierte)-2-苯甲酰 - 环己-2-烯酮。

    公开(公告)号:EP0249150A1

    公开(公告)日:1987-12-16

    申请号:EP87108080.0

    申请日:1987-06-04

    Abstract: A compound of the formula
    wherein R is halogen, C₁-C₂ alkyl, C₁-C₂ alkoxy, nitro; cyano; C₁-C₂ halo­alkyl, or R a SO n - wherein n is 0 or 2 and R a is C₁-C₂ alkyl; R¹ is hydrogen or C₁-C₄ alkyl; R² is hydrogen or C₁-C₄ alkyl; or R¹ and R² together are alkylene having 2 to 5 carbon atoms; R³ is hydrogen or C₁-C₄ alkyl; R⁴ is hydrogen or C₁-C₄ alkyl; or R³ and R⁴ can be oxo; R⁵ is hydrogen or C₁-C₄ alkyl; R⁶ is hydrogen or C₁-C₄ alkyl; or R⁵ and R⁶ together are alkylene having 2 to 5 carbon atoms; and R⁷ and R⁸ independently are (1) hydrogen; (2) halogen; (3) C₁-C₄ alkyl; (4) C₁-C₄ alkoxy; (5) trifluoromethoxy; (6) cyano; (7) nitro; (8) C₁-C₄ haloalkyl; (9) R b SO n - wherein n is the integer 0, 1 or 2; and R b is (a) C₁-C₄ alkyl; (b) C₁-C₄ alkyl substituted with halogen or cyano; (c) phenyl; or (d) benzyl; (10) -NR c R d wherein R c and R d independently are hydrogen or C₁-C₄ alkyl; (11) R e C(O)- wherein R e is C₁-C₄ alkyl or C₁-C₄ alkoxy; (12) SO₂NR c R d wherein R c and R d are as defined; or (13) -N(R c )C(O)R d wherein R c and R d are as defined; m is the integer 0, 1 or 2; and R⁹ is C₁-C₄ alkyl, phenyl, cyano, substituted phenyl, or -(CH₂) x -C(O)O- (C₁-C₄ alkyl) wherein X is the integer 1, 2 or 3.

    Abstract translation: 式CHEM的化合物,其中R是卤素,C 1 -C 2烷基,C 1 -C 2烷氧基,硝基; 氰基; C 1 -C 2卤代烷基或R a SO n - ,其中n为0或2,R a为C 1 -C 2烷基; R 1是氢或C 1 -C 4烷基; R 2是氢或C 1 -C 4烷基; 或R 1和R 2一起是具有2至5个碳原子的亚烷基; R 3是氢或C 1 -C 4烷基; R 4是氢或C 1 -C 4烷基; 或R 3和R 4可以是氧代; R 5是氢或C 1 -C 4烷基; R 6是氢或C 1 -C 4烷基; 或R 5和R 6一起是具有2至5个碳原子的亚烷基; 和R 7和R 8独立地是(1)氢; (2)卤素; (3)C 1 -C 4烷基; (4)C1-C4烷氧基; (5)三氟甲氧基; (6)氰基; (7)硝基; (8)C 1 -C 4卤代烷基; (9)R bnn-其中n是整数0,1或2; 和R b是(a)C 1 -C 4烷基; (b)被卤素或氰基取代的C 1 -C 4烷基; (c)苯基; 或(d)苄基; (10)-NR c R d其中R c和R d独立地是氢或C 1 -C 4烷基; (11)R e(O) - 其中R e是C 1 -C 4烷基或C 1 -C 4烷氧基; (12)SO 2 NR c R d其中R c和R d如所定义; 或(13)-N(R c)C(O)R d,其中R c和R d如定义; m是整数0,1或2; 并且R 9是C 1 -C 4烷基,苯基,氰基,取代的苯基或 - (CH 2)x -C(O)O-(C 1 -C 4烷基),其中X是整数1,2或3。

    Dicalcium phosphate dihydrate for fluoride dentifrice compositions
    75.
    发明公开
    Dicalcium phosphate dihydrate for fluoride dentifrice compositions 失效
    DikalziumphosphatdihydratfürFluoridzahnpastezusammensetzungen。

    公开(公告)号:EP0240880A2

    公开(公告)日:1987-10-14

    申请号:EP87104630.6

    申请日:1987-03-27

    Inventor: Li, Rosa

    CPC classification number: H01G4/2325 A61K8/24 A61Q11/00 C01B25/322 C01B25/327

    Abstract: The monofluorophosphate compatibility of dicalcium phosphate dihydrate can be improved in processes in which a slaked lime slurry is reacted with phosphoric acid to form a monocalcium phosphate solution to which is added magnesium oxide, additional lime slurry and pyrophosphoric acid with later removal of the dicalcium phosphate dihydrate. The improvement involved adding the magnesium oxide at O.3% - 2% and adding O.1% - less than O.5% of trimagnesium phosphate to the recovered dicalcium phosphate dihydrate.

    Abstract translation: 磷酸二钙的一氟磷酸盐相容性可以在熟石灰浆与磷酸反应形成磷酸一钙溶液的方法中得到改善,其中加入氧化镁,另外的石灰浆和焦磷酸,随后除去磷酸二钙二水合物 。 该改进涉及将氧化镁加入O.3%-2%,并向回收的磷酸二钙二水合物中加入O.1% - 少于磷酸三钙的0.5%。

    Inhalation exposure apparatus
    77.
    发明公开
    Inhalation exposure apparatus 失效
    吸入接触装置

    公开(公告)号:EP0121795A3

    公开(公告)日:1987-08-12

    申请号:EP84102591

    申请日:1984-03-09

    CPC classification number: A01K13/001 A01K1/031 A61B5/08 A61D7/04 Y10S128/91

    Abstract: An inhalation apparatus for exposing small laboratory animals, e.g., rats, to a test atmosphere in such a manner that the animals are exposed to a uniform concentration of the test atmosphere containing substantially no exhaled materials. The apparatus comprises an animal holding tube means capable of positioning the nose of an animal at a fixed point within the tube means. The tube means is provided with a test atmosphere inlet means located in the vicinity of the nose and an exhaust outlet means such that the test atmosphere can be inhaled by the animal then exhausted rearward of the nose of the animal. A plurality of these animal holding tube means can be combined by connecting their inlet means to a first plenum duct that is in communication with a source of the test atmosphere and connecting their outlet means to a second plenum duct for exhausting substantially all exhaled materials and excess test atmosphere.

    Method of improved residual herbicidal activity and compositions
    79.
    发明公开
    Method of improved residual herbicidal activity and compositions 失效
    改善残留除草活性和组合物的方法

    公开(公告)号:EP0190724A3

    公开(公告)日:1987-07-15

    申请号:EP86101432

    申请日:1986-02-04

    Abstract: Herbicide combinations with improved residual activity comprising (a) compounds of the formula
    wherein R 1 is selected from the group consisting of lower alkyl having from 2 to 6 carbon atoms, haloalkyl, benzyl and substituted benzyl, phenethyl, pyridylmethyl, cycloalkyl having from 3 to 6 carbon atoms, and haloalkenyl having from 3 to 6 carbon atoms, and R 2 and R 3 are each independently selected from the group consisting of C 2 -C 6 alkyl, C 2 -C 6 alkenyl, and C 3 -C 8 cycloalkyl, provided furtherthat R 2 and R 3 can join with the nitrogen to which they are attached to form a 5 to 6 carbon ring structure, and (b) an herbicidally effective amount of a chloroacetanilide having the formula
    in which R 4 is a straight or branched chain lower alkyl group having from 1 to 6 carbon atoms; R 5 is a straight or branched chain lower alkyl group having from 1 to 6 carbon atoms; and R 6 is O || (-C-O-R 7 ), or (-O-R 7 ), where R 7 is a straight or branched chain lower alkyl group having from 1 to 6 carbon atoms.

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