公开(公告)号：EP0249150A1

公开(公告)日：1987-12-16

申请号：EP87108080.0

申请日：1987-06-04

Applicant: STAUFFER CHEMICAL COMPANY

Inventor： Knudsen, Christopher Glade

IPC: C07C323/52 ,  C07C323/22 ,  C07C331/02 ,  C07C323/28 ,  C07C315/02 ,  A01N35/06 ,  C07C317/24 ,  C07C317/44

CPC classification number: C07C323/65 ,  A01N35/06 ,  A01N37/36 ,  A01N41/10 ,  C07C317/00 ,  C07C317/24 ,  C07C323/22 ,  C07C2601/16

Abstract: A compound of the formula
wherein R is halogen, C₁-C₂ alkyl, C₁-C₂ alkoxy, nitro; cyano; C₁-C₂ halo­alkyl, or R a SO n - wherein n is 0 or 2 and R a is C₁-C₂ alkyl; R¹ is hydrogen or C₁-C₄ alkyl; R² is hydrogen or C₁-C₄ alkyl; or R¹ and R² together are alkylene having 2 to 5 carbon atoms; R³ is hydrogen or C₁-C₄ alkyl; R⁴ is hydrogen or C₁-C₄ alkyl; or R³ and R⁴ can be oxo; R⁵ is hydrogen or C₁-C₄ alkyl; R⁶ is hydrogen or C₁-C₄ alkyl; or R⁵ and R⁶ together are alkylene having 2 to 5 carbon atoms; and R⁷ and R⁸ independently are (1) hydrogen; (2) halogen; (3) C₁-C₄ alkyl; (4) C₁-C₄ alkoxy; (5) trifluoromethoxy; (6) cyano; (7) nitro; (8) C₁-C₄ haloalkyl; (9) R b SO n - wherein n is the integer 0, 1 or 2; and R b is (a) C₁-C₄ alkyl; (b) C₁-C₄ alkyl substituted with halogen or cyano; (c) phenyl; or (d) benzyl; (10) -NR c R d wherein R c and R d independently are hydrogen or C₁-C₄ alkyl; (11) R e C(O)- wherein R e is C₁-C₄ alkyl or C₁-C₄ alkoxy; (12) SO₂NR c R d wherein R c and R d are as defined; or (13) -N(R c )C(O)R d wherein R c and R d are as defined; m is the integer 0, 1 or 2; and R⁹ is C₁-C₄ alkyl, phenyl, cyano, substituted phenyl, or -(CH₂) x -C(O)O- (C₁-C₄ alkyl) wherein X is the integer 1, 2 or 3.

Abstract translation: 式CHEM的化合物，其中R是卤素，C 1 -C 2烷基，C 1 -C 2烷氧基，硝基; 氰基; C 1 -C 2卤代烷基或R a SO n - ，其中n为0或2，R a为C 1 -C 2烷基; R 1是氢或C 1 -C 4烷基; R 2是氢或C 1 -C 4烷基; 或R 1和R 2一起是具有2至5个碳原子的亚烷基; R 3是氢或C 1 -C 4烷基; R 4是氢或C 1 -C 4烷基; 或R 3和R 4可以是氧代; R 5是氢或C 1 -C 4烷基; R 6是氢或C 1 -C 4烷基; 或R 5和R 6一起是具有2至5个碳原子的亚烷基; 和R 7和R 8独立地是（1）氢; （2）卤素; （3）C 1 -C 4烷基; （4）C1-C4烷氧基; （5）三氟甲氧基; （6）氰基; （7）硝基; （8）C 1 -C 4卤代烷基; （9）R bnn-其中n是整数0,1或2; 和R b是（a）C 1 -C 4烷基; （b）被卤素或氰基取代的C 1 -C 4烷基; （c）苯基; 或（d）苄基; （10）-NR c R d其中R c和R d独立地是氢或C 1 -C 4烷基; （11）R e（O） - 其中R e是C 1 -C 4烷基或C 1 -C 4烷氧基; （12）SO 2 NR c R d其中R c和R d如所定义; 或（13）-N（R c）C（O）R d，其中R c和R d如定义; m是整数0,1或2; 并且R 9是C 1 -C 4烷基，苯基，氰基，取代的苯基或 - （CH 2）x -C（O）O-（C 1 -C 4烷基），其中X是整数1,2或3。

公开(公告)号：EP0249812A2

公开(公告)日：1987-12-23

申请号：EP87108078.4

申请日：1987-06-04

Applicant: STAUFFER CHEMICAL COMPANY

Inventor： Knudsen, Christopher Glade ,  Michaely, William James ,  James, Donald Richard ,  Chin, Hsiao-Ling Mao

IPC: C07D309/32 ,  C07D335/02 ,  A01N43/16 ,  A01N43/18

CPC classification number: C07D309/32 ,  A01N43/16 ,  A01N43/18 ,  C07D335/02

Abstract: Compounds having the formula
wherein

X is oxygen or sulfur;
R is halogen; C 1 -C 2 alkyl; C 1 -C 2 alkoxy; nitro; cyano; C 1 -C 2 haloalkyl; or R a SO n - wherein n is 0 or 2 and R a is C 1 -C 2 alkyl;
R 1 is hydrogen or C 1 -C 4 alkyl;
R 2 is hydrogen or C 1 -C 4 alkyl;
R 3 is hydrogen or C 1 -C 4 alkyl;
R 4 is hydrogen or C 1 -C 4 alkyl; or
R 3 and R 4 together form a single bond; or
R 1 and R 3 together are alkylene having 2-5 carbon atoms; or
R 2 and R 4 together are alkylene having 2-5 carbon atoms; and
R 5 and R 6 independently are (1) hydrogen; (2) halogen; (3) C 1 -C 4 alkyl; (4) C 1 -C 4 alkoxy; (5) trifluoromethoxy; (6) cyano; (7) nitro; (8) C 1 -C 4 haloalkyl; (9) R b SO n - wherein n is the integer 0, or 2; and R b is (a) C 1 -C 4 alkyl; (b) C 1 -C 4 alkyl substituted with halogen or cyano; (c) phenyl; or (d) benzyl; (10) -NR c R d wherein R c and R d independently are hydrogen or C 1 -C 4 alkyl; (11) R e C(O)- wherein R e is C 1 -C 4 alkyl or C 1 -C 4 alkoxy; or (12) -SO 2 NR c R d wherein R c and R d are as defined; and (13) -N(R c )C(O)R d wherein R c and R d are as defined and their salts are useful as herbicides.

Abstract translation: 具有式CHEM的化合物，其中X是氧或硫; R是卤素; C1-C2烷基; C1-C2烷氧基; 硝基; 氰基; C 1 -C 2卤代烷基; 或R a SO n - ，其中n为0或2，R a为C 1 -C 2烷基; R 1是氢或C 1 -C 4烷基; R 2是氢或C 1 -C 4烷基; R 3是氢或C 1 -C 4烷基; R 4是氢或C 1 -C 4烷基; 或R 3和R 4一起形成单键; 或R 1和R 3一起是具有2-5个碳原子的亚烷基; 或R 2和R 4一起是具有2-5个碳原子的亚烷基; 和R 5和R 6独立地是（1）氢; （2）卤素; （3）C 1 -C 4烷基; （4）C1-C4烷氧基; （5）三氟甲氧基; （6）氰基; （7）硝基; （8）C 1 -C 4卤代烷基; （9）R bnn-其中n是整数0,1或2; 和R b是（a）C 1 -C 4烷基; （b）被卤素或氰基取代的C 1 -C 4烷基; （c）苯基; 或（d）苄基; （10）-NR c R d其中R c和R d独立地是氢或C 1 -C 4烷基; （11）R e（O） - 其中R e是C 1 -C 4烷基或C 1 -C 4烷氧基; 或（12）-SO 2 NR c R d其中R c和R d如定义; 和（13）-N（R c）C（O）R d其中R c和R d如上所定义，并且它们的盐可用作除草剂。

公开(公告)号：EP0249813B1

公开(公告)日：1991-07-24

申请号：EP87108081.8

申请日：1987-06-04

Applicant: STAUFFER CHEMICAL COMPANY

Inventor： Knudsen, Christopher Glade

IPC: C07C225/20 ,  C07C217/14 ,  C07C239/14 ,  C07D295/10 ,  C07D277/04 ,  A01N35/06 ,  A01N41/10 ,  A01N43/78

CPC classification number: C07D295/116 ,  A01N35/06 ,  A01N37/44 ,  A01N41/10 ,  A01N43/78 ,  C07C255/00 ,  C07D277/04

公开(公告)号：EP0249813A1

公开(公告)日：1987-12-23

申请号：EP87108081.8

申请日：1987-06-04

Applicant: STAUFFER CHEMICAL COMPANY

Inventor： Knudsen, Christopher Glade

IPC: C07C225/20 ,  C07C217/14 ,  C07C239/14 ,  C07D295/10 ,  C07D277/04 ,  A01N35/06 ,  A01N41/10 ,  A01N43/78

CPC classification number: C07D295/116 ,  A01N35/06 ,  A01N37/44 ,  A01N41/10 ,  A01N43/78 ,  C07C255/00 ,  C07D277/04

Abstract: A compound of the formula
wherein R is halogen, C₁-C₂ alkyl, C₁-C₂ alkoxy, nitro; cyano; C₁-C₂ halo­alkyl, or R a SO n - wherein n is 0 or 2 and R a is C₁-C₂ alkyl; R¹ is hydrogen or C₁-C₄ alkyl; R² is hydrogen or C₁-C₄ alkyl; or R¹ and R² together are alkylene having 2 to 5 carbon atoms; R³ is hydrogen or C₁-C₄ alkyl; R⁴ is hydrogen or C₁-C₄ alkyl; or R³ and R⁴ are oxo; R⁵ is hydrogen or C₁-C₄ alkyl; R⁶ is hydrogen or C₁-C₄ alkyl; and R⁷ and R⁸ independently are (1) hydrogen; (2) halogen; (3) C₁-C₄ alkyl; (4) C₁-C₄ alkoxy; (5) trifluoro­methoxy; (6) cyano; (7) nitro; (8) C₁-C₄ haloalkyl; (9) R b SO n - wherein n is the integer 0, 1 or 2; and R b is (a) C₁-C₄ alkyl; (b) C₁-C₄ alkyl sub­stituted with halogen or cyano; (c) phenyl; or (d) benzyl; (10) -NR c R d wherein R c and R d independently are hydrogen or C₁-C₄ alkyl; (11) R e C(O)-­wherein R e is C₁-C₄ alkyl or C₁-C₄ alkoxy; (12) SO₂NR c R d wherein R c and R d are as defined; or (13) -N(R c )C(O)R d wherein R c and R d are as defined; R⁹ is hydrogen or C₁-C₄ alkyl, R¹⁰ is (a) hydrogen; (b) C₁-C₆ alkyl, (c) C₄-C₆ cycloalkyl, (d) substituted C₁-C₆ alkyl, (e) phenyl; (f) substituted phenyl; (g) C₁-C₆ alkoxy; (h) benzyl; (i) phenethyl; (j) C₁-C₄ alkyl-C(O)-; (k) C₁-C₄ alkoxy-C(O)-; (l) C₂-C₆ alkenyl; or (m) C₂-C₆ alkynyl; and R⁹ and R¹⁰ together form a heterocyclic ring with the nitro­gen to which they are attached containing 0, 1 or 2 additional hetero atoms (nitrogen, sulfur or oxygen).

Abstract translation: 式CHEM的化合物，其中R是卤素，C 1 -C 2烷基，C 1 -C 2烷氧基，硝基; 氰基; C 1 -C 2卤代烷基或R a SO n - ，其中n为0或2，R a为C 1 -C 2烷基; R 1是氢或C 1 -C 4烷基; R 2是氢或C 1 -C 4烷基; 或R 1和R 2一起是具有2至5个碳原子的亚烷基; R 3是氢或C 1 -C 4烷基; R 4是氢或C 1 -C 4烷基; 或R 3和R 4是氧代; R 5是氢或C 1 -C 4烷基; R 6是氢或C 1 -C 4烷基; 和R 7和R 8独立地是（1）氢; （2）卤素; （3）C 1 -C 4烷基; （4）C1-C4烷氧基; （5）三氟甲氧基; （6）氰基; （7）硝基; （8）C 1 -C 4卤代烷基; （9）R bnn-其中n是整数0,1或2; 和R b是（a）C 1 -C 4烷基; （b）被卤素或氰基取代的C 1 -C 4烷基; （c）苯基; 或（d）苄基; （10）-NR c R d其中R c和R d独立地是氢或C 1 -C 4烷基; （11）R e（O） - 其中R e是C 1 -C 4烷基或C 1 -C 4烷氧基; （12）SO 2 NR c R d其中R c和R d如所定义; 或（13）-N（R c）C（O）R d，其中R c和R d如定义; R 9是氢或C 1 -C 4烷基，R 1是（a）氢; （b）C 1 -C 6烷基，（c）C 4 -C 6环烷基，（d）取代的C 1 -C 6烷基，（e）苯基; （f）取代的苯基; （g）C1-C6烷氧基; （h）苄基; （i）苯乙基; （j）C 1 -C 4烷基-C（O） - ; （k）C1-C4烷氧基-C（O） - ; （1）C 2 -C 6烯基; 或（m）C 2 -C 6炔基; 并且R 9和R 1一起形成与它们相连的氮含有0,1或2个另外的杂原子（氮，硫或氧）的杂环。

公开(公告)号：EP0249812A3

公开(公告)日：1989-01-25

申请号：EP87108078.4

申请日：1987-06-04

Applicant: STAUFFER CHEMICAL COMPANY

Inventor： Knudsen, Christopher Glade ,  Michaely, William James ,  James, Donald Richard ,  Chin, Hsiao-Ling Mao

IPC: C07D309/32 ,  C07D335/02 ,  A01N43/16 ,  A01N43/18

CPC classification number: C07D309/32 ,  A01N43/16 ,  A01N43/18 ,  C07D335/02

Abstract: Compounds having the formula
wherein
X is oxygen or sulfur; R is halogen; C 1 -C 2 alkyl; C 1 -C 2 alkoxy; nitro; cyano; C 1 -C 2 haloalkyl; or R a SO n - wherein n is 0 or 2 and R a is C 1 -C 2 alkyl; R 1 is hydrogen or C 1 -C 4 alkyl; R 2 is hydrogen or C 1 -C 4 alkyl; R 3 is hydrogen or C 1 -C 4 alkyl; R 4 is hydrogen or C 1 -C 4 alkyl; or R 3 and R 4 together form a single bond; or R 1 and R 3 together are alkylene having 2-5 carbon atoms; or R 2 and R 4 together are alkylene having 2-5 carbon atoms; and R 5 and R 6 independently are (1) hydrogen; (2) halogen; (3) C 1 -C 4 alkyl; (4) C 1 -C 4 alkoxy; (5) trifluoromethoxy; (6) cyano; (7) nitro; (8) C 1 -C 4 haloalkyl; (9) R b SO n - wherein n is the integer 0, or 2; and R b is (a) C 1 -C 4 alkyl; (b) C 1 -C 4 alkyl substituted with halogen or cyano; (c) phenyl; or (d) benzyl; (10) -NR c R d wherein R c and R d independently are hydrogen or C 1 -C 4 alkyl; (11) R e C(O)- wherein R e is C 1 -C 4 alkyl or C 1 -C 4 alkoxy; or (12) -SO 2 NR c R d wherein R c and R d are as defined; and (13) -N(R c )C(O)R d wherein R c and R d are as defined and their salts are useful as herbicides.

公开(公告)号：EP0253124A3

公开(公告)日：1988-07-06

申请号：EP87108077

申请日：1987-06-04

Applicant: STAUFFER CHEMICAL COMPANY

Inventor： Knudsen, Christopher Glade ,  Michaely, William James

IPC: C07C49/84 ,  C07C69/62 ,  C07C79/36 ,  C07C143/68 ,  A01N35/06

CPC classification number: C07C205/45 ,  A01N35/06 ,  A01N37/02 ,  A01N37/10 ,  A01N41/04 ,  C07C45/68 ,  C07C49/84 ,  C07C309/00

Abstract: A compound of the formula
wherein R is halogen, C₁-C₂ alkyl, C₁-C₂ alkoxy, nitro; cyano; C₁-C₂ halo­alkyl, or R a SO m - wherein m is 0 or 2 and R a is C₁-C₂ alkyl; R¹ is hydrogen or C₁-C₄ alkyl; R² is hydrogen or C₁-C₄ alkyl; or R¹ and R² together are alkylene having 2 to 5 carbon atoms; R³ is hydrogen or C₁-C₄ alkyl; R⁴ is hydrogen or C₁-C₄ alkyl;or R³ and R⁴ together are oxo; R⁵ is hydrogen or C₁-C₄ alkyl; R⁶ is hydrogen or C₁-C₄ alkyl; or R⁵ and R⁶ together are alkylene having 2 to 5 carbon atoms; R⁷ and R⁸ independently are (1) hydrogen; (2) halogen; (3) C₁-C₄ alkyl; (4) C₁-C₄ alkoxy; (5) trifluoro­methoxy; (6) cyano; (7) nitro; (8) C₁-C₄ haloalkyl; (9) R b SO n - wherein n is the integer 0, 1 or 2; and R b is (a) C₁-C₄ alkyl; (b) C₁-C₄ alkyl sub­stituted with halogen or cyano; (c) phenyl; or (d) benzyl; (10) -NR c R d wherein R c and R d independently are hydrogen or C₁-C₄ alkyl; (11) R e C(O)- wherein R e is C₁-C₄ alkyl or C₁-C₄ alkoxy; (12) SO₂NR c R d wherein R c and R d are as defined; or (13) -N(R c )C(O)R d wherein R c and R d are as defined; and R⁹ is (a) C₁-C₆ alkyl; (b) C₄-C₆ cycloalkyl; (c) substituted C₁-C₆ alkyl; (d) phenyl-SO₂-; (e) substituted phenyl-SO₂-; (f) C₁-C₆-alkyl-SO₂-, optionally substituted; (g) C₁-C₆ alkyl-C(O)-, optionally substituted; (h) phenyl-C(O)-, optionally substituted; (i) benzyl; or (h) C₃-C₆ alkenyl.

公开(公告)号：EP0249150B1

公开(公告)日：1991-05-29

申请号：EP87108080.0

申请日：1987-06-04

Applicant: STAUFFER CHEMICAL COMPANY

Inventor： Knudsen, Christopher Glade

IPC: C07C323/52 ,  C07C323/22 ,  C07C331/02 ,  C07C323/28 ,  C07C315/02 ,  A01N35/06 ,  C07C317/24 ,  C07C317/44

CPC classification number: C07C323/65 ,  A01N35/06 ,  A01N37/36 ,  A01N41/10 ,  C07C317/00 ,  C07C317/24 ,  C07C323/22 ,  C07C2601/16

公开(公告)号：EP0253124A2

公开(公告)日：1988-01-20

申请号：EP87108077.6

申请日：1987-06-04

Applicant: STAUFFER CHEMICAL COMPANY

Inventor： Knudsen, Christopher Glade ,  Michaely, William James

IPC: C07C49/84 ,  C07C69/62 ,  C07C79/36 ,  C07C143/68 ,  A01N35/06

CPC classification number: C07C205/45 ,  A01N35/06 ,  A01N37/02 ,  A01N37/10 ,  A01N41/04 ,  C07C45/68 ,  C07C49/84 ,  C07C309/00

Abstract: A compound of the formula
wherein R is halogen, C₁-C₂ alkyl, C₁-C₂ alkoxy, nitro; cyano; C₁-C₂ halo­alkyl, or R a SO m - wherein m is 0 or 2 and R a is C₁-C₂ alkyl; R¹ is hydrogen or C₁-C₄ alkyl; R² is hydrogen or C₁-C₄ alkyl; or R¹ and R² together are alkylene having 2 to 5 carbon atoms; R³ is hydrogen or C₁-C₄ alkyl; R⁴ is hydrogen or C₁-C₄ alkyl;or R³ and R⁴ together are oxo; R⁵ is hydrogen or C₁-C₄ alkyl; R⁶ is hydrogen or C₁-C₄ alkyl; or R⁵ and R⁶ together are alkylene having 2 to 5 carbon atoms; R⁷ and R⁸ independently are (1) hydrogen; (2) halogen; (3) C₁-C₄ alkyl; (4) C₁-C₄ alkoxy; (5) trifluoro­methoxy; (6) cyano; (7) nitro; (8) C₁-C₄ haloalkyl; (9) R b SO n - wherein n is the integer 0, 1 or 2; and R b is (a) C₁-C₄ alkyl; (b) C₁-C₄ alkyl sub­stituted with halogen or cyano; (c) phenyl; or (d) benzyl; (10) -NR c R d wherein R c and R d independently are hydrogen or C₁-C₄ alkyl; (11) R e C(O)- wherein R e is C₁-C₄ alkyl or C₁-C₄ alkoxy; (12) SO₂NR c R d wherein R c and R d are as defined; or (13) -N(R c )C(O)R d wherein R c and R d are as defined; and R⁹ is (a) C₁-C₆ alkyl; (b) C₄-C₆ cycloalkyl; (c) substituted C₁-C₆ alkyl; (d) phenyl-SO₂-; (e) substituted phenyl-SO₂-; (f) C₁-C₆-alkyl-SO₂-, optionally substituted; (g) C₁-C₆ alkyl-C(O)-, optionally substituted; (h) phenyl-C(O)-, optionally substituted; (i) benzyl; or (h) C₃-C₆ alkenyl.

Abstract translation: 式CHEM的化合物，其中R是卤素，C 1 -C 2烷基，C 1 -C 2烷氧基，硝基; 氰基; C 1 -C 2卤代烷基或R a SO m - ，其中m为0或2，R a为C 1 -C 2烷基; R 1是氢或C 1 -C 4烷基; R 2是氢或C 1 -C 4烷基; 或R 1和R 2一起是具有2至5个碳原子的亚烷基; R 3是氢或C 1 -C 4烷基; R 4是氢或C 1 -C 4烷基;或者R 3和R 4一起是氧代; R 5是氢或C 1 -C 4烷基; R 6是氢或C 1 -C 4烷基; 或R 5和R 6一起是具有2至5个碳原子的亚烷基; R 7和R 8独立地为（1）氢; （2）卤素; （3）C 1 -C 4烷基; （4）C1-C4烷氧基; （5）三氟甲氧基; （6）氰基; （7）硝基; （8）C 1 -C 4卤代烷基; （9）R bnn-其中n是整数0,1或2; 和R b是（a）C 1 -C 4烷基; （b）被卤素或氰基取代的C 1 -C 4烷基; （c）苯基; 或（d）苄基; （10）-NR c R d其中R c和R d独立地是氢或C 1 -C 4烷基; （11）R e（O） - 其中R e是C 1 -C 4烷基或C 1 -C 4烷氧基; （12）SO 2 NR c R d其中R c和R d如所定义; 或（13）-N（R c）C（O）R d，其中R c和R d如定义; 和R 9是（a）C 1 -C 6烷基; （b）C 4 -C 6环烷基; （c）取代的C 1 -C 6烷基; （d）苯基-SO 2 - ; （e）取代的苯基-SO 2 - ; （f）任选取代的C 1 -C 6烷基-SO 2 - ; （g）任选取代的C 1 -C 6烷基-C（O） - （h）苯基-C（O） - ，任选取代的; （i）苄基; 或（h）C 3 -C 6烯基。