公开(公告)号：KR1020040059912A

公开(公告)日：2004-07-06

申请号：KR1020020086417

申请日：2002-12-30

Applicant: 제일모직주식회사

Inventor： 홍상현 ,  안성희 ,  양재호 ,  배수학 ,  유영식

IPC: C08L51/04

CPC classification number: C08L51/04 ,  C08F212/08 ,  C08J2300/22 ,  C08K5/5357 ,  C08L25/12 ,  C08L2201/02

Abstract: PURPOSE: Provided is a flame resistant thermoplastic resin composition, which has excellent stability against fire and flame resistance, and is environmental-friendly due to the absence of halogen-containing flame retardant compounds. CONSTITUTION: The flame resistant thermoplastic resin composition comprises: (A) 100 parts by weight of a rubber-modified styrene-based resin composed of (a1) 20-100 wt% of a graft copolymer resin obtained by graft polymerization of 5-65 wt% of a rubbery polymer, 30-95 wt% of an aromatic vinyl monomer, 0-20 wt% of a monomer which can be copolymerized with the aromatic vinyl monomer and 0-15 wt% of a monomer for supplementing processability and heat resistance, and (a2) 0-80 wt% of a copolymer resin obtained by copolymerization of 60-90 wt% of an aromatic vinyl monomer, 10-40 wt% of a monomer which can be copolymerized with the aromatic vinyl monomer and 0-30 wt% of a monomer for supplementing processability and heat resistance; and (B) 15-40 parts by weight of a cyclic alkyl phosphonic acid compound.

Abstract translation: 目的：提供耐火耐火性优异的耐火热塑性树脂组合物，由于不存在含卤阻燃化合物，因此环保。 构成：耐火性热塑性树脂组合物包含：（A）100重量份的由（a1）20-100重量％的接枝共聚物树脂（a）将5-65重量份的接枝聚合得到的橡胶改性苯乙烯类树脂 ％的橡胶状聚合物，30-95重量％的芳族乙烯基单体，0-20重量％的可与芳族乙烯基单体共聚的单体和0-15重量％的用于补充加工性和耐热性的单体， 和（a2）0-80重量％的通过共聚60-90重量％的芳族乙烯基单体，10-40重量％的可与芳族乙烯基单体共聚的单体和0-30重量％ 用于补充加工性和耐热性的单体的％; 和（B）15-40重量份的环烷基膦酸化合物。

公开(公告)号：KR1020030082092A

公开(公告)日：2003-10-22

申请号：KR1020020020635

申请日：2002-04-16

Applicant: 제일모직주식회사

Inventor： 홍상현 ,  배수학 ,  양재호

IPC: C08L25/10 ,  C08L71/12 ,  C08K5/521

CPC classification number: C08L25/10 ,  C08K5/523 ,  C08K5/527 ,  C08L71/12 ,  C08L2201/02

Abstract: PURPOSE: A flame retardant styrene-based resin composition is provided, to improve the environmental friendliness, the flame retardancy, the heat resistance and the mechanical strength. CONSTITUTION: The styrene-based resin composition comprises 40-85 wt% of a rubber-reinforced polystyrene resin; 10-40 wt% of a polyphenylene ether resin; and 5-20 wt% of an organic phosphorus-based compound comprising 30-80 wt% of an oxaphosphorane compound and 20-70 wt% of an aromatic phosphoric ester compound. Preferably the oxaphosphorane compound is represented by the formula 1, wherein R1 is H, an alkyl group of C1-C4 or an aryl group of C6-C10; R2 and R3 are H or an alkyl group of C1-C4; and n is 1-3, and the aromatic phosphoric ester compound is represented by the formula 2, wherein R4, R5 and R6 are independently H, an alkyl group of C1-C4; X is an aryl group of C6-C20 unsubstituted or substituted with an alkyl group and is derived from the dialcohol comprising resorcinol, hydroquinol, bisphenol-A and bisphenol-S; and m is 0-4.

Abstract translation: 目的：提供阻燃苯乙烯基树脂组合物，以改善环境友好性，阻燃性，耐热性和机械强度。 构成：苯乙烯类树脂组合物包含40-85重量％的橡胶增强聚苯乙烯树脂; 10-40重量％的聚苯醚树脂; 和5-20重量％的包含30-80重量％的氧化磷杂环化合物和20-70重量％的芳族磷酸酯化合物的有机磷基化合物。 优选地，氧化磷烷化合物由式1表示，其中R 1是H，C 1 -C 4的烷基或C 6 -C 10的芳基; R2和R3是H或C1-C4的烷基; 并且n为1-3，芳族磷酸酯化合物由式2表示，其中R 4，R 5和R 6独立地为H，C 1 -C 4烷基; X是未被取代或被烷基取代的C 6 -C 20的芳基，衍生自包含间苯二酚，氢醌，双酚A和双酚-S的二醇; m为0-4。

公开(公告)号：KR100396405B1

公开(公告)日：2003-09-02

申请号：KR1020000081677

申请日：2000-12-26

Applicant: 제일모직주식회사

Inventor： 장영길 ,  장복남 ,  안성희 ,  배수학

IPC: C08L25/12 ,  C08L55/02 ,  C08L71/12 ,  C08K5/05

Abstract: PURPOSE: Provided is a thermoplastic and fire retardant resin composition which has excellent injection releasability, impact resistance, fire retardancy, and fluidity. CONSTITUTION: The composition comprises 100 parts by weight of base resin consisting of the following (A) and (B): (A) 40-95 parts by weight of rubber modified styrene-acrylonitrile copolymer resin consisting of (a1) 20-90 parts by weight of styrene-acrylonitrile graft copolymer resin containing 10-60 wt% of rubber component and 18-50 wt% of acrylonitrile(in components except for the rubber component), (a2) 0-80 parts by weight of styrene-acrylonitrile copolymer resin containing 18-50 wt% of acrylonitrile, and (a3) 5-40 parts by weight of styrene-based resin containing 0-20 wt% of rubber, (B) 60-5 parts by weight of polyphenylene ether resin; (C) 2-30 parts by weight of styrene-acrylonitrile copolymer containing 5-18 wt% of acrylonitrile; (D) 5-30 parts by weight of aromatic phosphate ester compound(formula 1); and (E) 0.05-3 parts by weight of montan wax.

Abstract translation: 目的：提供具有优异的注射释放性，耐冲击性，阻燃性和流动性的热塑性和阻燃性树脂组合物。 构成：该组合物包含100重量份由下列（A）和（B）组成的基体树脂：（A）40-95重量份橡胶改性苯乙烯 - 丙烯腈共聚物树脂，其由（a1）20-90份 （a2）0-80重量份的苯乙烯 - 丙烯腈共聚物（b），所述苯乙烯 - 丙烯腈共聚物树脂包含10-60重量％的橡胶组分和18-50重量％的丙烯腈（除了橡胶组分以外的组分） （a3）5〜40重量份含有0〜20重量％橡胶的苯乙烯系树脂，（B）60〜5重量份聚苯醚树脂， （C）2-30重量份含有5-18重量％丙烯腈的苯乙烯 - 丙烯腈共聚物; （D）5-30重量份芳香族磷酸酯化合物（式1）; 和（E）0.05-3重量份的褐煤蜡。

公开(公告)号：KR1020030033235A

公开(公告)日：2003-05-01

申请号：KR1020010064682

申请日：2001-10-19

Applicant: 제일모직주식회사

Inventor： 배수학 ,  이규철 ,  홍상현 ,  양재호

IPC: C08L51/04

CPC classification number: C08L51/04 ,  C08J2300/22 ,  C08K5/03 ,  C08K5/1515 ,  C08K5/523 ,  C08L25/12 ,  C08L71/12 ,  C08L2201/02

Abstract: PURPOSE: Provided is a fire retardant and heat resistant thermoplastic resin composition which dose not produce toxic gas such as dioxin, furan or halogenated hydrogen gas when processed and burned. CONSTITUTION: The composition comprises: (A)(a1) 20-100wt.% of graft copolymer resin containing 10-60wt.% of rubber and 90-40wt.% of styrene copolymer and (a2) 40-95wt.% of rubber modified styrene copolymer containing 80-0wt.% of copolymer resin containing styrene, which 18-50wt.% of acrylonitrile in the components except a rubber; (B) 5-60wt.% of polyphenylene ether resin; (C); 2-30wt.% of SAN(styrene-acrylonitrile) copolymer resin containing 5-17wt.% of acrylonitrile on the basis of 100wt.% of the above (A)+(B) basic resin; (D) 0.1-50wt.% of epoxy derivatives on the basis of 100wt.% of the above (A)+(B) basic resin; (E) 5-30wt.% of aromatic phosphorous ester compound on the basis of 100wt.% of the above (A)+(B) basic resin; (F) 0.1-5wt.% of aromatic halogen compound on the basis of 100wt.% of the above (A)+(B) basic resin; and (G) 0.1-3wt.% of antimony compound on the basis of 100wt.% of the above (A)+(B) basic resin.

Abstract translation: 目的：提供一种阻燃耐热热塑性树脂组合物，在加工和燃烧时不会产生二恶英，呋喃或卤化氢等有毒气体。 组成：该组合物包括：（A）（a1）含有10-60重量％橡胶和90-40重量％苯乙烯共聚物的接枝共聚物树脂20-100重量％，（a2）40-95重量％的橡胶改性 苯乙烯共聚物，含有80〜0重量％的含苯乙烯的共聚物树脂，18-50重量％的丙烯腈除橡胶外; （B）5-60重量％的聚苯醚树脂; （C）; 基于100重量％的上述（A）+（B）碱性树脂，含有5-17重量％丙烯腈的SAN（苯乙烯 - 丙烯腈）共聚物树脂的2-30重量％ （D）基于100重量％的上述（A）+（B）碱性树脂的0.1-50重量％的环氧衍生物; （E）基于100重量％上述（A）+（B）碱性树脂的5-30重量％的芳族亚磷酸酯化合物; （F）基于100重量％的上述（A）+（B）碱性树脂的0.1-5重量％的芳族卤素化合物; 和（G）基于100重量％的上述（A）+（B）碱性树脂的0.1-3重量％的锑化合物。

公开(公告)号：KR1020030030420A

公开(公告)日：2003-04-18

申请号：KR1020010062555

申请日：2001-10-11

Applicant: 제일모직주식회사

Inventor： 장영길 ,  홍상현 ,  배수학

IPC: C08L55/02

CPC classification number: C08L51/04 ,  C08J2300/22 ,  C08L25/12 ,  C08L51/06 ,  C08L55/02 ,  C08L101/00 ,  C08L2205/035

Abstract: PURPOSE: Provided is a thermoplastic resin composition which shows improved compatibility of a blend of a resin based on rubber modified styrene and a polyphenylene ether, and has excellent physical properties. CONSTITUTION: The composition comprises 100 parts by weight of base resin consisting of (A) 40-95 wt% of rubber modified resin consisting of (a1) 20-100 wt% of graft copolymer resin having 10-60 wt% of rubber component, 50-82 wt% of aromatic vinyl monomer except for rubber component, and 18-50 wt% of unsaturated nitrile-based monomer, (a2) 0-80 wt% of copolymer having 18-50 wt% of unsaturated nitrile-based monomer and 50-82 wt% of aromatic vinyl monomer, (B) 60-5 wt% of polyphenylene ether resin; and (C) 0.1-5 parts by weight of styrene-acrylonitrile containing copolymer comprising maleic anhydride; and (D) 0.1-5 parts by weight of ethylene-glycidyl methacrylate containing graft copolymer.

Abstract translation: 目的：提供一种热塑性树脂组合物，其显示出基于橡胶改性苯乙烯和聚苯醚的树脂共混物的相容性提高，并具有优异的物理性能。 组成：该组合物包含100重量份由（A）40-95重量％的由（a1）20-100重量％的具有10-60重量％橡胶组分的接枝共聚物树脂组成的（A）40-95重量％ 50〜82重量％的除橡胶成分以外的芳香族乙烯基单体和18〜50重量％的不饱和腈类单体，（a2）0〜80重量％的具有18〜50重量％的不饱和腈系单体的共聚物和 50-82重量％的芳族乙烯基单体，（B）60-5重量％的聚苯醚树脂; 和（C）0.1-5重量份含马来酸酐的含苯乙烯 - 丙烯腈的共聚物; 和（D）0.1-5重量份的含有接枝共聚物的乙烯 - 含甲基丙烯酸缩水甘油酯。

公开(公告)号：KR1020030000415A

公开(公告)日：2003-01-06

申请号：KR1020010036185

申请日：2001-06-25

Applicant: 제일모직주식회사

Inventor： 홍상현 ,  양재호 ,  배수학

IPC: C08K13/02

Abstract: PURPOSE: A fire retardant thermoplastic resin composition is provided, to improve the heat resistance and the mechanical properties by employing an organic phosphoric acid ester treated with an organoclay together with a phosphorus-based compound as a flame retardant. CONSTITUTION: The fire retardant thermoplastic resin composition comprises 100 parts by weight of a thermoplastic resin; 5-30 parts by weight of an organic phosphoric acid ester treated with an organoclay, which consists of 0.1-20 % of an organoclay and 80-99.9 % of an organic phosphoric acid ester; optionally 50 parts by weight or less of a phosphorus-based compound; optionally 5 parts by weight or less of a dropping preventer; and optionally 50 parts by weight or less of a plasticizer, a heat stabilizer, an antioxidizing agent, a photostabilizer, a compatibilizer, a pigment and/or a dye and an inorganic additive. Preferably the organoclay is prepared by reacting the plate clay having a cation exchange property of 50-200 mg eq. per 100 g with the organic cation represented by the formula 1, wherein R1, R2, R3 and R4 are independent each another and are an alkyl group of C1-C30, an alkyl-substituted or unsubstituted aryl group of C6-C30, an alkyl group of C1-C30 having 1-5 hydroxy groups, or an aryl group of C6-C30 having 1-5 hydroxy groups; X- is an anion.

Abstract translation: 目的：提供一种阻燃热塑性树脂组合物，通过使用用有机粘土处理的有机磷酸酯与磷基化合物作为阻燃剂一起提高耐热性和机械性能。 构成：阻燃热塑性树脂组合物包含100重量份的热塑性树脂; 5-30重量份用有机粘土处理的有机磷酸酯，其由0.1-20％的有机粘土和80-99.9％的有机磷酸酯组成; 任选地50重量份或更少的磷基化合物; 任选地5重量份或更少的防滴落剂; 和任选的50重量份或更少的增塑剂，热稳定剂，抗氧化剂，光稳定剂，增容剂，颜料和/或染料和无机添加剂。 有机粘土优选通过使阳离子交换性质为50-200mg当量的平板粘土反应来制备。 由式1表示的有机阳离子，其中R1，R2，R3和R4彼此独立，为C1-C30的烷基，C6-C30的烷基取代或未取代的芳基， 具有1-5个羟基的C1-C30基团或具有1-5个羟基的C6-C30的芳基; X-是阴离子。

公开(公告)号：KR1020020094307A

公开(公告)日：2002-12-18

申请号：KR1020010031959

申请日：2001-06-08

Applicant: 제일모직주식회사

Inventor： 양재호 ,  홍상현 ,  이규철 ,  장영길 ,  배수학

IPC: C08L55/02

CPC classification number: C08K5/1515 ,  C08K5/06 ,  C08K5/49 ,  C08L51/04 ,  C08L53/00 ,  C08L55/02 ,  C08L61/06 ,  C08L61/14 ,  C08L67/02 ,  C08L69/00 ,  C08L2666/14 ,  C08L2666/24 ,  C08L2666/02 ,  C08L2666/16

Abstract: PURPOSE: A flame retardant thermoplastic resin composition and a molded product prepared by using the composition are provided, to solve the discoloration problem due to the light generated by using a phenol resin and the compatibility with another resin, to improve the char production and to obtain a good flame retardancy irrespective of the kind of a resin. CONSTITUTION: The flame retardant thermoplastic resin composition comprises 100 parts by weight of a thermoplastic resin; 0.1-100 parts by weight of a phenol resin derivative represented by the formula 1; and 1-50 parts by weight of a phosphorus-based compound. In the formula 1, R1 is an alkyl group of C1-C34, an aryl group of C1-C34, an aryl group of C1-C34 substituted with an alkyl group, or an O, N, P or S-containing alkyl, aryl or alkyl-substituted aryl group; R2, R3 and R4 are independent each another and are H, an alkyl group of C1-C34, an aryl group of C1-C34, an aryl group of C1-C34 substituted with an alkyl group, or an O, N, P or S-containing alkyl, aryl or alkyl-substituted aryl group; and n is an integer of 1-10,000.

Abstract translation: 目的：提供一种阻燃热塑性树脂组合物和通过使用该组合物制备的模制产品，以解决由于使用酚醛树脂产生的光和与另一种树脂的相容性引起的变色问题，以改善焦炭生产并获得 与树脂的种类无关，具有良好的阻燃性。 构成：阻燃热塑性树脂组合物包含100重量份的热塑性树脂; 0.1-100重量份由式1表示的酚醛树脂衍生物; 和1-50重量份的磷基化合物。 在式1中，R1是C1-C34的烷基，C1-C34的芳基，被烷基取代的C1-C34的芳基，或含有O，N，P或S的烷基，芳基 或烷基取代的芳基; R2，R3和R4彼此独立，为H，C1-C34的烷基，C1-C34的芳基，被烷基取代的C1-C34的芳基，或O，N，P或 含S的烷基，芳基或烷基取代的芳基; n为1-10,000的整数。

公开(公告)号：KR1020020053196A

公开(公告)日：2002-07-05

申请号：KR1020000082552

申请日：2000-12-27

Applicant: 제일모직주식회사

Inventor： 안성희 ,  장복남 ,  장영길 ,  양재호 ,  홍상현 ,  배수학

IPC: C08L25/08 ,  C08L55/02 ,  C08K5/521 ,  C08K3/22

CPC classification number: C08L51/04 ,  C08J2300/22 ,  C08K3/22 ,  C08K5/523 ,  C08K2003/2248 ,  C08K2201/003 ,  C08L25/12 ,  C08L71/12 ,  C08L2201/02 ,  C08L2205/025

Abstract: PURPOSE: A thermoplastic flame retardant resin composition and a product prepared by using the composition are provided, to improve the flame retardancy by employing copper compounds without adding char compounds. CONSTITUTION: The composition comprises 100 parts by weight of a rubber-modified styrene-acrylonitrile copolymer resin which comprises (a1) 20-90 wt% of a styrene-acrylonitrile grafted copolymer resin whose rubber content is 10-68 wt% and whose acrylonitrile content except the rubber component is 18-65 wt%, and (a2) 10-80 wt% of a styrene-acrylonitrile grafted copolymer resin whose acrylonitrile content is 18-65 wt%; 2-30 parts by weight of an aromatic phosphate ester compound; and 0.01-20 parts by weight of at least one copper compound selected from the group consisting of oxides, sulfides, chlorides, fluorides, phosphates, sulfates, nitrates and salts of organic acids including monovalent or divalent copper. Optionally the composition comprises further 0-60 parts by weight of a polyphenylene ether resin.

Abstract translation: 目的：提供一种热塑性阻燃树脂组合物和通过使用该组合物制备的产品，以通过使用不添加焦炭化合物的铜化合物来改善阻燃性。 构成：该组合物包含100重量份橡胶改性的苯乙烯 - 丙烯腈共聚物树脂，其包含（a1）20-90重量％的橡胶含量为10-68重量％的苯乙烯 - 丙烯腈接枝共聚物树脂，其丙烯腈含量 橡胶成分为18-65重量％，（a2）10-80重量％丙烯腈含量为18-65重量％的苯乙烯 - 丙烯腈接枝共聚物树脂; 2-30重量份芳族磷酸酯化合物; 和0.01-20重量份的选自氧化物，硫化物，氯化物，氟化物，磷酸盐，硫酸盐，硝酸盐和包括一价或二价铜的有机酸盐的至少一种铜化合物。 任选地，组合物还包含0-60重量份的聚苯醚树脂。