公开(公告)号：DE3718898A1

公开(公告)日：1988-12-22

申请号：DE3718898

申请日：1987-06-05

Applicant: BASF AG

Inventor： KOEHLER HERMANN DR ,  DOCKNER TONI DR

IPC: C07D233/92 ,  C07D401/12 ,  C07D473/38 ,  C07D473/00

Abstract: Preparation of 4-nitro-5-mercaptoimidazoles of the formula I in which the radicals R denotes alkyl, alkoxyalkyl, cycloalkyl, aryl, arylalkyl or alkylaryl; R denotes hydrogen, alkyl, cycloalkyl, aryl, arylalkyl or alkylaryl and R denotes alkyl, cycloalkyl, aryl, arylalkyl, alkylaryl or a heterocyclic or heteroaromatic radical as well as hydrogen or a counterion of the corresponding thiolate where the organic radicals mentioned can still carry inert substituents under the reaction conditions, by reacting dinitroimidazoles of the formula II in which R and R have the abovementioned meaning, with mercapto compounds of the formula III R -SH in which R denotes hydrogen, alkoxyalkyl, alkyl, cycloalkyl, aryl, arylalkyl, alkylaryl or a heterocyclic or heteroaromatic radical, in a solvent or diluent at a pH of at least 4 and isolating the products in a manner known per se.

公开(公告)号：DE3716293A1

公开(公告)日：1988-11-24

申请号：DE3716293

申请日：1987-05-15

Applicant: BASF AG

Inventor： DOCKNER TONI DR ,  KRUG HERBERT ,  ROTERMUND GERHARD W DR ,  WEYRAUCH VOLKER DR

IPC: C07B61/00 ,  C07D231/12 ,  C07D231/16 ,  C07D231/18 ,  C07D231/20 ,  C07D521/00 ,  C07D231/10

公开(公告)号：DE3660680D1

公开(公告)日：1988-10-13

申请号：DE3660680

申请日：1986-06-25

Applicant: BASF AG

Inventor： DOCKNER TONI DR

IPC: C07F9/50

Abstract: Tertiary phosphine oxides, phosphine sulfides and/or phosphine dihalides are reduced to tertiary phosphines by reaction with a hydrocarbon in the presence of carbon at elevated temperatures.

公开(公告)号：DE3600609A1

公开(公告)日：1987-07-16

申请号：DE3600609

申请日：1986-01-11

Applicant: BASF AG

Inventor： DOCKNER TONI DR ,  KRUG HERBERT ,  SAUERWALD MANFRED DR

IPC: C07C1/00 ,  C07B31/00 ,  C07B35/02 ,  C07B35/06 ,  C07B43/04 ,  C07C1/207 ,  C07C1/22 ,  C07C1/32 ,  C07C5/03 ,  C07C5/11 ,  C07C5/50 ,  C07C5/52 ,  C07C9/06 ,  C07C9/08 ,  C07C13/18 ,  C07C13/20 ,  C07C13/48 ,  C07C15/06 ,  C07C45/00 ,  C07C45/62 ,  C07C47/00 ,  C07C47/02 ,  C07C47/228 ,  C07C67/00 ,  C07C209/00 ,  C07C209/40 ,  C07C209/42 ,  C07C209/48 ,  C07C209/52 ,  C07C211/44 ,  C07C253/00 ,  C07C255/00 ,  C07D333/06 ,  C07D333/08 ,  C07D333/10 ,  C07D335/02 ,  C07D521/00

公开(公告)号：DE3369844D1

公开(公告)日：1987-04-02

申请号：DE3369844

申请日：1983-09-22

Applicant: BASF AG

Inventor： DOCKNER TONI DR ,  FRANK ANTON

IPC: B01J23/72 ,  C07B61/00 ,  C07D233/06

公开(公告)号：DE3363817D1

公开(公告)日：1986-07-03

申请号：DE3363817

申请日：1983-12-01

Applicant: BASF AG

Inventor： DOCKNER TONI DR ,  KRUG HERBERT ,  SANN WERNER

IPC: B01J12/00 ,  C07D249/08

公开(公告)号：DE3427136A1

公开(公告)日：1986-02-06

申请号：DE3427136

申请日：1984-07-24

Applicant: BASF AG

Inventor： KEMPE UWE DR ,  DOCKNER TONI DR ,  SCHLICK ROLF

IPC: C07D233/60 ,  C07D233/66 ,  C07D233/90

Abstract: Imidazole-4(5)-monocarboxylic acids and their salts or betaines are prepared by reacting an imidazole with carbon dioxide and an alkali metal carbonate, an alkali metal bicarbonate and/or an alkali metal hydroxide at from 140 DEG to 230 DEG C. and under from 2 to 350 bar and, if desired, then reacting the product with an acid. The imidazole-4(5)-monocarboxylic acids which can be prepared by the process of the invention are useful starting materials for the preparation of dyes, crop protection agents and drugs.

公开(公告)号：DE3427404A1

公开(公告)日：1986-01-30

申请号：DE3427404

申请日：1984-07-25

Applicant: BASF AG

Inventor： SAUERWALD MANFRED DR ,  DOCKNER TONI DR ,  ROHR WOLFGANG DR ,  REISSENWEBER GERNOT DR

IPC: A01N43/18 ,  C07D335/02

Abstract: 5,6-Dihydro-2H-thiopyran-3-carboxaldehydes of the formula where R denotes hydrogen or methyl, are prepared by a method in which acrolein or crotonaldehyde is reacted with hydrogen sulfide in a mineral oil whose boiling point is higher than those of the starting materials and of the end product, and the 5,6-dihydro-2H-thiopyran-3-carboxaldehyde is obtained by distillation. These aldehydes are important intermediates for the preparation of some crop protection agents.

公开(公告)号：DE3426081A1

公开(公告)日：1986-01-16

申请号：DE3426081

申请日：1984-07-14

Applicant: BASF AG

Inventor： KEMPE UWE DR ,  DOCKNER TONI DR

IPC: C07D233/00 ,  C07D233/54 ,  C07D233/64

公开(公告)号：DE3330192A1

公开(公告)日：1985-03-07

申请号：DE3330192

申请日：1983-08-20

Applicant: BASF AG

Inventor： DOCKNER TONI DR ,  POMMER ERNST-HEINRICH DR ,  DRESSEL JUERGEN DR

IPC: C05G3/90 ,  C07D233/60 ,  C07D233/61 ,  C07D233/68 ,  C09K17/00 ,  A01N43/50

Abstract: 4-Alkylimidazole derivatives of the formula I I where R1 is C1-C4-alkyl, R2 is chlorine or bromine and R3 is an -OR4 or -NR5R6 group in which R4 is C1-C4-alkyl, R5 is hydrogen or C1-C4-alkyl and R6 is C1-C4-alkyl or is phenyl which is unsubstituted or substituted by 1 or 2 halogen atoms, and its salts, their preparation and their use as nitrification inhibitors.