Carbamoyl carboxylic acid amide derivs.

    公开(公告)号:DE4446458A1

    公开(公告)日:1996-07-04

    申请号:DE4446458

    申请日:1994-12-27

    Applicant: BASF AG

    Abstract: Carbamoyl carboxylic acid amide derivs. of formula (I) and their salts are new R = 1-8C alkyl, 2-8C alkenyl, or 2-8C alkynyl (these gps. being opt. partially or completely halogenated and/or mono-, di- or tri-substd. with T gps.); 3-7C cycloalkyl or 3-7C cycloalkyl (these last 2 gps. being opt. partially or completely halogenated and/or mono-, di- or tri-substd. with T gps. (excluding cycloalkyl, cycloalkenyl and heteroaryl) or with 1-4C alkyl or aryl(1-4C)alkyl (this last gp. itself opt. substd. with T gps. excluding cycloalkyl or cycloalkenyl)); a non-aromatic 4-8 membered ring contg. in the ring, in addition to C, 1 or 2 heteroatoms chosen from O, S and N (the ring C being opt. mono-, di- or tri-substd. with halogen, 1-4C alkyl, T gps. (excluding cycloalkyl, cycloalkenyl and heteroaryl) and the second and any further N heteroatom carrying H or 1-4C alkyl); aryl or heteroaryl (these 2 gps. opt. mono-, di- or tri-substd. with halogen, 1-4C alkyl or T gps. (excluding cycloalkyl and cycloalkenyl)) or W W C=N; W = 1-8C alkyl (opt. partially or completely halogenated and/or opt. mono-, di- or tri-substd. with T gps. (excluding alkoxycarbonyl, cycloalkyl and cycloalkenyl)), 2-8C alkenyl, 2-8C alkynyl (opt. partially or completely halogenated and opt. mono-, di- or tri-substd. with 1-4C alkyl or T gps. (excluding cycloalkyl, cycloalkenyl and heteroaryl), 3-7C cycloalkyl or 3-7C cycloalkenyl (opt. mono-, di- or tri-substd. with halogen, 1-4C alkyl, aryl(1-4C)alkyl (this last gp. itself opt. substd. with halogen, 1-4C alkyl or T gps., excluding cycloalkyl, cycloalkenyl or heteroaryl) or T gps. (excluding cycloalkyl, cycloalkenyl, aryloxy or heteroaryl)), aryl or heteroaryl (these last 2 gps. opt. substd. with T gps., excluding cycloalkyl, cycloalkenyl or heteroaryl); W = H or a gp. W ; R = H, 1-8C alkyl or 3-7C cycloalkyl (these last 2 gps. opt. partially or completely halogenated); R = 1-8C alkyl, 3-7C cycloalkyl (opt. mono-, di- or tri-substd. with halogen, 1-4C alkyl, phenyl(1-4C)alkyl (in which the Ph gp. is opt. mono-, di- or tri-substd. with halogen, 1-4C alkyl or T gps., excluding cycloalkyl, cycloalkenyl, aryl, aryloxy or heteroaryl)); R = one of the R gps.; or R and R together with the C atom to which they are attached form a 4-8 membered ring which contains, in addition to C, 1 or 2 heteroatoms chosen from O, S and N (the ring C being opt. mono- or di-substd. with halogen, 1-4C alkyl and T gps. (excluding cycloalkyl, cycloalkenyl and heteroaryl) and the N heteroatom carrying H or 1-4C alkyl); R = a R gp.; X = H, 1-8C alkyl and/or 2-8C alkenyl (these last 2 gps. opt. partially or completely halogenated and opt. mono-, di- or tri-substd. with T gps., excluding cycloalkyl, cycloalkenyl or heteroaryl), 3-7C cycloalkyl and/or 3-7C cycloalkenyl (these 2 gps. opt. partially or completely halogenated and opt. mono-, di- or tri-substd. with 1-4C alkyl, aryl(1-4C) alkyl (this last opt. substd. with halogen, 1-4C alkyl and T gps., excluding cycloalkyl, cycloalkenyl and heteroaryl), or T gps. (excluding cycloalkyl, cycloalkenyl or heteroaryl)); m = 0-2; A = 3-7C cycloalkyl or 3-7C cycloalkenyl (opt. partially or completely halogenated and/or opt. mono-, di- or tri-substd. with 1-4C alkyl, aryl(1-4C)alkyl (thus last opt. mono-, di- or tri-substd. on aryl with halogen, 1-4C alkyl or T gps., excluding cycloalkyl, cycloalkenyl and heteroaryl) or T gps. excluding cycloalkyl, cycloalkenyl, aryloxy and heteroaryl); R = aryl or heteroaryl (these gps. opt. mono-, di- or tri-substd. with halogen or T gps., excluding cycloalkyl, cycloalkenyl or heteroaryl); T = CN, 1-4C alkoxyalkyl, 1-4C haloalkyl, 1-4C alkoxy, 1-4C haloalkoxy, 1-4C alkylthio, 1-4C alkoxycarbonyl, 3-7C cycloalkyl, 3-7C cycloalkenyl, aryl, aryloxy or heteroaryl, the cyclic gps. themselves being opt. mono-, di- or tri-substd. with halogen, CN, 1-4C alkyl, 1-4C alkoxy alkyl, 1-4C haloalkyl, 1-4C alkoxy, 1-4C haloalkoxy, 1-4C alkylthio, 1-4C alkoxycarbonyl, aryl, aryloxy or heteroaryl.

    73.
    发明专利
    未知

    公开(公告)号:DK0607795T3

    公开(公告)日:1996-01-29

    申请号:DK94100084

    申请日:1994-01-05

    Applicant: BASF AG

    Abstract: Process for the preparation of alkyl 2-alkyl-4-fluoromethylthiazolecarboxylates of the formula I in which R is alkyl, R is difluoromethyl or trifluoromethyl and R is alkyl, by reacting thiocarboxamides of the formula II in which R has the abovementioned meaning with alkyl 2-chloro-4-fluoroacetoacetates of the formula III in which R and R have the abovementioned meanings, in an aprotic solvent at temperatures of below 100@C and reacting the product with a dehydrating agent at temperatures of below 80@C, if appropriate in the presence of bases.

    New O,N-di:acyl-para-hydroxy:aniline derivs.

    公开(公告)号:DE4418380A1

    公开(公告)日:1995-11-30

    申请号:DE4418380

    申请日:1994-05-26

    Applicant: BASF AG

    Abstract: 2,3-Disubstd. O,N-diacyl-p-hydroxyaniline derivs. of formula (I) and their salts are new. R = 6-15C bicycloalkyl or 7-15C bicycloalkenyl (both opt. partially or completely halogenated and/or opt. substd. by 1-5 of alkyl, haloalkyl, alkoxy, haloalkyl and Ar); R , R = halogen, alkyl, haloalkyl, alkoxy or haloalkoxy; R = (i) 1-6C alkyl or 2-6C alkenyl (both opt. partially or completely halogenated and/or opt. monosubstd. by alkoxy, haloalkoxy, alkylthio, 3-7C cycloalkyl, 5-7C cycloalkenyl or Ar'); (ii) 3-7C cycloalkyl or 5-7C cycloalkenyl (both opt. substd. by 1-3 of halogen, alkyl, haloalkyl and alkoxy); or (iii) Ar, OR or NR R ; R = as for R (i); as for R (ii); or Ar; R = H or 1-6C alkyl; Ar = aryl (opt. partially or completely halogenated and/or opt. substd. by 1-3 of NO2, CN, alkyl, haloalkyl, alkoxy, haloalkoxy and alkylthio); Ar = aryl (opt. substd. by 1-3 of NO2, CN, halogen, alkyl, haloalkyl, alkoxy, haloalkyloxy and alkylthio); unless specified otherwise, all alkyl moieties have 1-4C.

    New carbamoyl-oxime cpds.
    76.
    发明专利

    公开(公告)号:DE4409432A1

    公开(公告)日:1995-09-21

    申请号:DE4409432

    申请日:1994-03-19

    Applicant: BASF AG

    Abstract: Carbamoyl-oxime cpds. of formula (I), and their salts, are new: R = 1-8C alkyl (opt. halogenated and/or opt. substd. by 1-2 TO, T'O, TS, 3-7C cycloalkyl, 5-7C cycloalkenyl, aryl or heteroaryl (the cyclic gps. being themselves opt. substd. by 1-3Q);etc.; R = H or a gp. R ; or CR R = a fluorenyl gp. (opt. substd. by 1-3 halo, CN, NO2, T, T', 1-4C alkoxyalkyl, TO, T'O, TOCO,etc.;R = H, or 1-8C alkyl or 3-7C cycloalkyl (both opt. halogenated); R = e.g. 1-8C alkyl;R = H or a gp. R ; or CR R = e.g. a 3-8 membered ring; R = H, or 1-8C alkyl or 3-7C cycloalkyl (both opt. halogenated); R = e.g. 1-8C alkyl; or NR R = e.g. a 4-8 membered satd. ring;T = 1-4C alkyl; T' = 1-4C haloalkyl; Q = halo, CN, NO2,etc..

    78.
    发明专利
    未知

    公开(公告)号:DE59008825D1

    公开(公告)日:1995-05-11

    申请号:DE59008825

    申请日:1990-05-19

    Applicant: BASF AG

    Abstract: 5-(N-3,4,5,6-tetrahydrophthalimido)cinnamic acid esters of the general formula I … … in which n represents 1 or 2 and the substituents have the following meanings:… R represents hydrogen or fluorine,… R represents halogen,… R represents hydrogen, halogen or C1-C4-alkyl,… R represents hydrogen, optionally substituted C1-C6-alkyl, C3-C7- cycloalkyl, C3-C6-alkenyl, C3-C6-alkynyl or benzyl,… R represents C1-C4-alkyl,… their preparation, and herbicidal compositions containing them.

    79.
    发明专利
    未知

    公开(公告)号:DE59007992D1

    公开(公告)日:1995-01-26

    申请号:DE59007992

    申请日:1990-07-17

    Applicant: BASF AG

    Abstract: Cinnamic acid esters of the general formula I in which the dotted bond represents a single or double bond and the substituents have the following meanings: R is hydrogen or fluorine, R is halogen, R is hydrogen, halogen or C1-C4-alkyl, R is hydrogen, optionally substituted C1-C6-alkyl, C3-C6-alkenyl, C3-C6-alkynyl or benzyl, and X is oxygen or sulphur, preparation process, and agents containing them.

    80.
    发明专利
    未知

    公开(公告)号:DE59102319D1

    公开(公告)日:1994-09-01

    申请号:DE59102319

    申请日:1991-05-03

    Applicant: BASF AG

    Abstract: N-Aryltetrahydrophthalimides I … … in which the substituents have the following meanings: …… X is hydrogen or halogen; … R is C1-C4-alkyl which can have 1-5 halogen atoms, or one of the groups mentioned under X; … R is a 5-membered heteroaromatic ring which is bonded via nitrogen and contains 1-3 nitrogen atoms besides carbon ring members; … R is halogen, C1-C4-alkylthio, one of the groups mentioned under R , or the phenylthio group which, in turn, can be substituted by 1-3 of the following radicals: halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy or C1-C4-alkylthio, and where the phenylthio group can additionally have such a number of halogen atoms that the total number of the radicals is 4 or 5, … and their agriculturally utilisable salts. … The compounds I are suitable as herbicides.

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