.gamma.-AZOLYL COMPOUNDS AGENTS CONTAINING THEM FOR REGULATING PLANT GROWTH, AND THE MANUFACTURE THEREOF

    公开(公告)号:CA1137491A

    公开(公告)日:1982-12-14

    申请号:CA336988

    申请日:1979-10-04

    Applicant: BASF AG

    Abstract: A new ?-azolyl compound of the formula I, where R1 and R2 are identical or different and each denotes alkyl of 1 to 8 carbon atoms, furanyl, thienyl, naphthyl, or phenyl, phenyl being unsubstituted or substituted by fluoro, chloro, bromo, nitro, trifluoromethyl, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, or by alkenyl of 1 to 4 carbon atoms, R3 denotes alkyl of 1 to 8 carbon atoms, unsubstituted or chloro-substituted alkenyl of 2 to 5 carbon atoms, alkynyl of 3 to 4 carbon atoms, benzyl which is unsubstituted or substituted by fluoro, chloro, bromo, nitro, trifluoromethyl, or by alkyl or alkoxy of 1 to 4 carbon atoms, R3 further denotes -CO-R4, R4 denoting alkyl of 1 to 5 carbon atoms which 18 unsubstituted or substituted by halogen, alkoxy, oxo (=0) or carboxyalkyl, or R4 denoting phenyl, and R3 further denotes -CO-NH-R5, R5 denoting alkyl of 1 to 4 carbon atoms or phenyl or chlorophenyl, and Az denotes imidazoyl, 1,2,4-triazolyl or 1,2,3triazolyl; processes for their manufacture; agents for influencing plant growth which contain these compounds as active ingredients; and processes for regulating plant growth with these compounds.

    77.
    发明专利
    未知

    公开(公告)号:NO142449C

    公开(公告)日:1980-08-20

    申请号:NO752427

    申请日:1975-07-04

    Applicant: BASF AG

    Abstract: 1507920 Esters BASF AG 18 July 1975 [19 July 1974] 30186/75 Heading C2C [Also in Division C7] In electrochemical manufacture of an aromatic or heterocyclic ester by anodic acyloxylation of an aromatic or heterocyclic compound with an alkanoic acid, electrolysis is carried out in the presence of a conducting salt where R 1 , R 2 , and R 3 are the same or different and are H or alkyl, at least one being alkyl, and R 4 is H or C 1 -C 6 alkyl. The aromatic compound may be a benzene derivative, a naphthalene, anthracene, phenanthrene, acenaphthene, acenaphthylene, tetracene, perylene or chrysene; the heterocyclic compound may be quinoline or benzofuran; substituent groups on the aromatics may be alkyl, aryl, alkoxy, aryloxy, halogen, acyloxy, acylamino, cyano, nitro, or sulphonate; examples are given. Alkanoic acids mentioned are formic, acetic, propionic, butyric, valeric, isovaleric, and caproic; said salt may be made by reacting a suitable amine with such acid and may be trimethylammonium formate, acetate or propionate; triethyl ammonium formate, acetate or propionate, tri-n-butylammonium acetate, dimethylammonium formate, acetate or propionate, or diethylammonium acetate. The anode may be graphite, PbO 2 , Pt or Au, and the cathode graphite, Fe, steel or Pb; the electrode spacing may be 0À25-2 mm. and the C.D. 0À1- 30 A/dm. 2 ; a charge of 0À4-1À5 F/mole causes monoacyloxylation, and >2F/mole a higher degree. The electrolyte may comprise 5-60 wt. per cent aromatic or heterocyclic compound, 5-70% alkanoic acid, 1-20% of the salt and 0-50% of an inert co-solvent; everything apart from the product may be removed afterwards by distillation.

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