公开(公告)号：US3652430A

公开(公告)日：1972-03-28

申请号：US3652430D

申请日：1968-11-08

Applicant: BASF AG

Inventor： BECK FRITZ ,  HIMMELE WALTER ,  HAUFE JUERGEN ,  BRUNOLD ANDREAS

IPC: C25B3/10 ,  B01D3/00

CPC classification number: C25B3/10

Abstract: Process for the electrochemical condensation of carboxylic acids by the electrolysis of monocarboxylic acids, half esters of dicarboxylic acids or aminocarboxylic acids in which current densities of more than 10 amp./dm.2 on vibrating electrode pairs are used, and in which the degree of neutralization of the carboxylic acids is kept below 10 percent, said process providing high space-time yields and a reaction product which can be worked up without difficulty.

Abstract translation: 通过电解一元羧酸，二羧酸的半酯或氨基羧酸的电化学缩合羧酸的方法，其中使用振动电极对上的电流密度大于10安培/平方米，其中 羧酸的中和保持在10％以下，所述方法提供高的时空产率和可以无困难地处理的反应产物。

公开(公告)号：CS188230B2

公开(公告)日：1979-02-28

申请号：CS511375

申请日：1975-07-18

Applicant: BASF AG

Inventor： HAUFE JUERGEN ,  RENTZEA COSTIN ,  DEGNER DIETER

IPC: C07D215/20 ,  C07C69/157 ,  C07C69/76 ,  C07D213/69 ,  C07D215/32 ,  C07D307/20 ,  C07D307/78 ,  C07D307/83 ,  C25B3/23 ,  C25B3/29 ,  C25B3/02 ,  C07C69/14

Abstract: 1507920 Esters BASF AG 18 July 1975 [19 July 1974] 30186/75 Heading C2C [Also in Division C7] In electrochemical manufacture of an aromatic or heterocyclic ester by anodic acyloxylation of an aromatic or heterocyclic compound with an alkanoic acid, electrolysis is carried out in the presence of a conducting salt where R 1 , R 2 , and R 3 are the same or different and are H or alkyl, at least one being alkyl, and R 4 is H or C 1 -C 6 alkyl. The aromatic compound may be a benzene derivative, a naphthalene, anthracene, phenanthrene, acenaphthene, acenaphthylene, tetracene, perylene or chrysene; the heterocyclic compound may be quinoline or benzofuran; substituent groups on the aromatics may be alkyl, aryl, alkoxy, aryloxy, halogen, acyloxy, acylamino, cyano, nitro, or sulphonate; examples are given. Alkanoic acids mentioned are formic, acetic, propionic, butyric, valeric, isovaleric, and caproic; said salt may be made by reacting a suitable amine with such acid and may be trimethylammonium formate, acetate or propionate; triethyl ammonium formate, acetate or propionate, tri-n-butylammonium acetate, dimethylammonium formate, acetate or propionate, or diethylammonium acetate. The anode may be graphite, PbO 2 , Pt or Au, and the cathode graphite, Fe, steel or Pb; the electrode spacing may be 0À25-2 mm. and the C.D. 0À1- 30 A/dm. 2 ; a charge of 0À4-1À5 F/mole causes monoacyloxylation, and >2F/mole a higher degree. The electrolyte may comprise 5-60 wt. per cent aromatic or heterocyclic compound, 5-70% alkanoic acid, 1-20% of the salt and 0-50% of an inert co-solvent; everything apart from the product may be removed afterwards by distillation.

公开(公告)号：AU8232875A

公开(公告)日：1976-12-23

申请号：AU8232875

申请日：1975-06-20

Applicant: BASF AG

Inventor： HAUFE JUERGEN ,  RENTZEA COSTIN ,  DEGNER DIETER

IPC: C07D215/20 ,  C07C69/157 ,  C07C69/76 ,  C07D213/69 ,  C07D215/32 ,  C07D307/20 ,  C07D307/78 ,  C07D307/83 ,  C25B3/23 ,  C25B3/29 ,  C25B3/00 ,  C07C63/36

Abstract: 1507920 Esters BASF AG 18 July 1975 [19 July 1974] 30186/75 Heading C2C [Also in Division C7] In electrochemical manufacture of an aromatic or heterocyclic ester by anodic acyloxylation of an aromatic or heterocyclic compound with an alkanoic acid, electrolysis is carried out in the presence of a conducting salt where R 1 , R 2 , and R 3 are the same or different and are H or alkyl, at least one being alkyl, and R 4 is H or C 1 -C 6 alkyl. The aromatic compound may be a benzene derivative, a naphthalene, anthracene, phenanthrene, acenaphthene, acenaphthylene, tetracene, perylene or chrysene; the heterocyclic compound may be quinoline or benzofuran; substituent groups on the aromatics may be alkyl, aryl, alkoxy, aryloxy, halogen, acyloxy, acylamino, cyano, nitro, or sulphonate; examples are given. Alkanoic acids mentioned are formic, acetic, propionic, butyric, valeric, isovaleric, and caproic; said salt may be made by reacting a suitable amine with such acid and may be trimethylammonium formate, acetate or propionate; triethyl ammonium formate, acetate or propionate, tri-n-butylammonium acetate, dimethylammonium formate, acetate or propionate, or diethylammonium acetate. The anode may be graphite, PbO 2 , Pt or Au, and the cathode graphite, Fe, steel or Pb; the electrode spacing may be 0À25-2 mm. and the C.D. 0À1- 30 A/dm. 2 ; a charge of 0À4-1À5 F/mole causes monoacyloxylation, and >2F/mole a higher degree. The electrolyte may comprise 5-60 wt. per cent aromatic or heterocyclic compound, 5-70% alkanoic acid, 1-20% of the salt and 0-50% of an inert co-solvent; everything apart from the product may be removed afterwards by distillation.

公开(公告)号：CA872950A

公开(公告)日：1971-06-08

申请号：CA872950D

Applicant: BASF AG

Inventor： HAUFE JUERGEN ,  HIMMELE WALTER ,  BRUNOLD ANDREAS ,  BECK FRITZ

公开(公告)号：NO142449C

公开(公告)日：1980-08-20

申请号：NO752427

申请日：1975-07-04

Applicant: BASF AG

Inventor： HAUFE JUERGEN ,  RENTZEA COSTIN ,  DEGNER DIETER

IPC: C07C69/157 ,  C07C69/76 ,  C07D215/20 ,  C07D213/69 ,  C07D215/32 ,  C07D307/20 ,  C07D307/78 ,  C07D307/83 ,  C25B3/23 ,  C25B3/29 ,  C25B3/00 ,  C07C69/14

Abstract: 1507920 Esters BASF AG 18 July 1975 [19 July 1974] 30186/75 Heading C2C [Also in Division C7] In electrochemical manufacture of an aromatic or heterocyclic ester by anodic acyloxylation of an aromatic or heterocyclic compound with an alkanoic acid, electrolysis is carried out in the presence of a conducting salt where R 1 , R 2 , and R 3 are the same or different and are H or alkyl, at least one being alkyl, and R 4 is H or C 1 -C 6 alkyl. The aromatic compound may be a benzene derivative, a naphthalene, anthracene, phenanthrene, acenaphthene, acenaphthylene, tetracene, perylene or chrysene; the heterocyclic compound may be quinoline or benzofuran; substituent groups on the aromatics may be alkyl, aryl, alkoxy, aryloxy, halogen, acyloxy, acylamino, cyano, nitro, or sulphonate; examples are given. Alkanoic acids mentioned are formic, acetic, propionic, butyric, valeric, isovaleric, and caproic; said salt may be made by reacting a suitable amine with such acid and may be trimethylammonium formate, acetate or propionate; triethyl ammonium formate, acetate or propionate, tri-n-butylammonium acetate, dimethylammonium formate, acetate or propionate, or diethylammonium acetate. The anode may be graphite, PbO 2 , Pt or Au, and the cathode graphite, Fe, steel or Pb; the electrode spacing may be 0À25-2 mm. and the C.D. 0À1- 30 A/dm. 2 ; a charge of 0À4-1À5 F/mole causes monoacyloxylation, and >2F/mole a higher degree. The electrolyte may comprise 5-60 wt. per cent aromatic or heterocyclic compound, 5-70% alkanoic acid, 1-20% of the salt and 0-50% of an inert co-solvent; everything apart from the product may be removed afterwards by distillation.

公开(公告)号：NO142449B

公开(公告)日：1980-05-12

申请号：NO752427

申请日：1975-07-04

Applicant: BASF AG

Inventor： HAUFE JUERGEN ,  RENTZEA COSTIN ,  DEGNER DIETER

IPC: C07C69/157 ,  C07C69/76 ,  C07D215/20 ,  C07D213/69 ,  C07D215/32 ,  C07D307/20 ,  C07D307/78 ,  C07D307/83 ,  C25B3/23 ,  C25B3/29 ,  C25B3/00 ,  C07C69/14

Abstract: 1507920 Esters BASF AG 18 July 1975 [19 July 1974] 30186/75 Heading C2C [Also in Division C7] In electrochemical manufacture of an aromatic or heterocyclic ester by anodic acyloxylation of an aromatic or heterocyclic compound with an alkanoic acid, electrolysis is carried out in the presence of a conducting salt where R 1 , R 2 , and R 3 are the same or different and are H or alkyl, at least one being alkyl, and R 4 is H or C 1 -C 6 alkyl. The aromatic compound may be a benzene derivative, a naphthalene, anthracene, phenanthrene, acenaphthene, acenaphthylene, tetracene, perylene or chrysene; the heterocyclic compound may be quinoline or benzofuran; substituent groups on the aromatics may be alkyl, aryl, alkoxy, aryloxy, halogen, acyloxy, acylamino, cyano, nitro, or sulphonate; examples are given. Alkanoic acids mentioned are formic, acetic, propionic, butyric, valeric, isovaleric, and caproic; said salt may be made by reacting a suitable amine with such acid and may be trimethylammonium formate, acetate or propionate; triethyl ammonium formate, acetate or propionate, tri-n-butylammonium acetate, dimethylammonium formate, acetate or propionate, or diethylammonium acetate. The anode may be graphite, PbO 2 , Pt or Au, and the cathode graphite, Fe, steel or Pb; the electrode spacing may be 0À25-2 mm. and the C.D. 0À1- 30 A/dm. 2 ; a charge of 0À4-1À5 F/mole causes monoacyloxylation, and >2F/mole a higher degree. The electrolyte may comprise 5-60 wt. per cent aromatic or heterocyclic compound, 5-70% alkanoic acid, 1-20% of the salt and 0-50% of an inert co-solvent; everything apart from the product may be removed afterwards by distillation.

公开(公告)号：HU173801B

公开(公告)日：1979-08-28

申请号：HUBA003303

申请日：1975-07-17

Applicant: BASF AG

Inventor： HAUFE JUERGEN ,  DEGNER DIETER ,  RENTZEA COSTIN

IPC: C07D215/20 ,  C07C69/157 ,  C07C69/76 ,  C07D213/69 ,  C07D215/32 ,  C07D307/20 ,  C07D307/78 ,  C07D307/83 ,  C25B3/23 ,  C25B3/29

Abstract: 1507920 Esters BASF AG 18 July 1975 [19 July 1974] 30186/75 Heading C2C [Also in Division C7] In electrochemical manufacture of an aromatic or heterocyclic ester by anodic acyloxylation of an aromatic or heterocyclic compound with an alkanoic acid, electrolysis is carried out in the presence of a conducting salt where R 1 , R 2 , and R 3 are the same or different and are H or alkyl, at least one being alkyl, and R 4 is H or C 1 -C 6 alkyl. The aromatic compound may be a benzene derivative, a naphthalene, anthracene, phenanthrene, acenaphthene, acenaphthylene, tetracene, perylene or chrysene; the heterocyclic compound may be quinoline or benzofuran; substituent groups on the aromatics may be alkyl, aryl, alkoxy, aryloxy, halogen, acyloxy, acylamino, cyano, nitro, or sulphonate; examples are given. Alkanoic acids mentioned are formic, acetic, propionic, butyric, valeric, isovaleric, and caproic; said salt may be made by reacting a suitable amine with such acid and may be trimethylammonium formate, acetate or propionate; triethyl ammonium formate, acetate or propionate, tri-n-butylammonium acetate, dimethylammonium formate, acetate or propionate, or diethylammonium acetate. The anode may be graphite, PbO 2 , Pt or Au, and the cathode graphite, Fe, steel or Pb; the electrode spacing may be 0À25-2 mm. and the C.D. 0À1- 30 A/dm. 2 ; a charge of 0À4-1À5 F/mole causes monoacyloxylation, and >2F/mole a higher degree. The electrolyte may comprise 5-60 wt. per cent aromatic or heterocyclic compound, 5-70% alkanoic acid, 1-20% of the salt and 0-50% of an inert co-solvent; everything apart from the product may be removed afterwards by distillation.

公开(公告)号：CA1056763A

公开(公告)日：1979-06-19

申请号：CA229506

申请日：1975-06-17

Applicant: BASF AG

Inventor： HAUFE JUERGEN ,  RENTZEA COSTIN ,  DEGNER DIETER

IPC: C07D215/20 ,  C07C69/157 ,  C07C69/76 ,  C07D213/69 ,  C07D215/32 ,  C07D307/20 ,  C07D307/78 ,  C07D307/83 ,  C25B3/23 ,  C25B3/29 ,  C25B3/00

Abstract: Electrochemical manufacture of aromatic esters of the naphthalene series by acylation of naphthalene derivatives in an alkanoic acid, wherein the electroylsis is carried out in the presence of a conducting salt of the formula in which R1, R2 and R3 denote hydrogen and/or alkyl and R4 denotes hydrogen or alkyl of from 1 to 6 carbon atoms.