公开(公告)号：PL318113A1

公开(公告)日：1997-05-12

申请号：PL31811395

申请日：1995-06-16

Applicant: BASF AG

Inventor： FUCHS EBERHARD ,  WITZEL TOM

IPC: C07D201/08 ,  C07D223/10

Abstract: Cyclic lactams are prepared by reacting an aminocarboxylic acid compound of the formula I H2N-(CH2)m-COR1 I where R1 is -OH, -O-C1-C12-alkyl or -NR2R3 and R2 and R3, independently of one another, are each hydrogen, C1-C12-alkyl or C5-C8-cycloalkyl and m is an integer from 3 to 12, with water by a process in which the reaction is carried out in the liquid phase using a heterogeneous catalyst.

公开(公告)号：AU6000196A

公开(公告)日：1996-12-18

申请号：AU6000196

申请日：1996-05-24

Applicant: BASF AG

Inventor： WEISS FRANZ-JOSEF ,  FUCHS HUGO ,  FUCHS EBERHARD ,  WITZEL TOM

IPC: B01J23/42 ,  B01J27/045 ,  C07B61/00 ,  C07C51/41 ,  C07C249/08 ,  C07C251/44 ,  C07D201/04 ,  C01B21/14

Abstract: The production of cyclohexanonoxim by the reaction of cyclohexanone with a hydroxyl ammonium salt, i.e. hydroxyl ammonium formiate, and the production of caprolactam by the Beckmann rearrangement of cyclohexanonoxim in a C1-C4 carboxylic acid.

公开(公告)号：DE19519894A1

公开(公告)日：1996-12-05

申请号：DE19519894

申请日：1995-05-31

Applicant: BASF AG

Inventor： HOLDERBAUM MARTIN ,  BECK KARL ,  AUMUELLER ALEXANDER ,  WITZEL TOM ,  VOIT GUIDO

IPC: C07C253/30 ,  C07C255/41 ,  C07C255/23 ,  C07C253/00

Abstract: A process for producing 2-cyano-3,3-diary acrylic acid esters of general formula (I) in which R and R are hydrogen, C1-C12 alkoxy groups or di-(C1-C4 alkyl) amino groups and R is a C4-C18 alkyl group which may be interrupted by oxygen atoms in the ether function, by the reaction of benzophenonimine of general formula (II) with a cyanic acid ester of general formula (III), in which the reaction is conducted at 20 to 60 DEG C and the ammonia released is continuously removed from the reaction mixture with the aid of a stream of gas or by reducing the pressure to 900 to 100mbar.

公开(公告)号：AU5813496A

公开(公告)日：1996-11-29

申请号：AU5813496

申请日：1996-05-04

Applicant: BASF AG

Inventor： FUCHS EBERHARD ,  ZIMMERMANN HORST ,  WITZEL TOM ,  BREITSCHEIDEL BORIS ,  BECKER RAINER ,  NEUHAUSER HORST

IPC: B01J23/40 ,  C07C213/02 ,  C07C213/06

Abstract: PCT No. PCT/EP96/01861 Sec. 371 Date Jan. 23, 1998 Sec. 102(e) Date Jan. 23, 1998 PCT Filed May 4, 1996 PCT Pub. No. WO96/36589 PCT Pub. Date Nov. 21, 1996A process for preparing N-methyl-2-(3,4-dimethoxyphenyl)-ethylamine comprises hydrogenating 3,4-dimethoxyphenylacetonitrile with a methylamine of the general formula I (I) where R1 is hydrogen, benzyl or tert-butyl, and hydrogen in the presence of a supported catalyst which comprises from 0.05 to 50% by weight of copper chromite, copper, silver, gold, iron, cobalt, nickel, ruthenium, rhodium, palladium, osmium, iridium, platinum or mixtures thereof, in the presence or absence of water at from 20 DEG to 200 DEG C. under from 1 to 300 bar.

公开(公告)号：DE19518038A1

公开(公告)日：1996-11-21

申请号：DE19518038

申请日：1995-05-17

Applicant: BASF AG

Inventor： FUCHS EBERHARD ,  WITZEL TOM ,  BREITSCHEIDEL BORIS

IPC: B01J23/40 ,  C07C213/02 ,  C07C211/03 ,  B01J23/00 ,  B01J23/89 ,  C07C209/22 ,  C07F1/08 ,  C07F1/10 ,  C07F1/12 ,  C07F15/00 ,  C07F15/04 ,  C07F15/06

Abstract: Process for prodn. of N-methyl-2-(3,4-dimethoxyphenyl)-ethylamine (I) by hydrogenating 3,4-dimethoxyphenyl-methylnitrile (II) with a methylamine cpd. of formula NHMeR1 (III) and hydrogen in the presence of a catalyst contg. 0.05-50 wt. % (C), opt. in the presence of water, at 20-200 deg C and 1-300 bar. (C) = copper chromite, copper, silver, gold, iron, cobalt, nickel, ruthenium, rhodium, palladium, osmium, iridium, and/or platinum; R1 = H, benzyl or tert. butyl.

公开(公告)号：DE19518018A1

公开(公告)日：1996-11-21

申请号：DE19518018

申请日：1995-05-17

Applicant: BASF AG

Inventor： ZIMMERMANN HORST ,  WITZEL TOM ,  FUCHS EBERHARD

IPC: B01J23/40 ,  C07C213/06 ,  C07C211/03 ,  B01J23/00 ,  B01J23/89 ,  C07C209/22 ,  C07F1/08 ,  C07F1/10 ,  C07F1/12 ,  C07F15/04 ,  C07F15/06

Abstract: Process for prodn. of N-methyl-2-(3,4-dimethoxyphenyl)-ethylamine (I) by hydrogenating 3,4-dimethoxyphenyl-methylnitrile (II) with a methylamine cpd. of formula NHMeR1 (III) and hydrogen in the presence of a catalyst contg. 0.05-50 wt. % (C), opt. in the presence of water, at 20-200 deg C and 1-300 bar. (C) = copper chromite, copper, silver, gold, iron, cobalt, nickel, ruthenium, rhodium, palladium, osmium, iridium, and/or platinum; R1 = H, benzyl or tert. butyl.

公开(公告)号：HU9601337D0

公开(公告)日：1996-07-29

申请号：HU9601337

申请日：1994-11-15

Applicant: BASF AG

Inventor： FUCHS EBERHARD ,  WITZEL TOM

IPC: C07D223/10 ,  C07D201/08

Abstract: PCT No. PCT/EP94/03782 Sec. 371 Date May 16, 1996 Sec. 102(e) Date May 16, 1996 PCT Filed Nov. 15, 1994 PCT Pub. No. WO95/14665 PCT Pub. Date Jun. 1, 1995Cyclic lactams are prepared by reacting amino carbonitriles with water in liquid phase in a fixed bed reactor in the presence of heterogeneous catalysts which have no soluble constituents under the reaction conditions.

公开(公告)号：AU4254996A

公开(公告)日：1996-06-19

申请号：AU4254996

申请日：1995-11-22

Applicant: BASF AG

Inventor： FUCHS EBERHARD ,  WITZEL TOM

IPC: C07D201/12

Abstract: Caprolactam is prepared by cleaving oligomers or polymers containing essentially the repeating unit -[-N(H)-(CH2)5-C(O)-]- in the presence of a catalyst at elevated temperatures by a process in which the cleavage is carried out in the liquid phase in the presence of a heterogeneous catalyst and of an organic solvent.

公开(公告)号：NO962021L

公开(公告)日：1996-05-15

申请号：NO962021

申请日：1996-05-15

Applicant: BASF AG

Inventor： FUCHS EBERHARD ,  WITZEL TOM

IPC: C07D201/08 ,  C07D223/10

Abstract: PCT No. PCT/EP94/03782 Sec. 371 Date May 16, 1996 Sec. 102(e) Date May 16, 1996 PCT Filed Nov. 15, 1994 PCT Pub. No. WO95/14665 PCT Pub. Date Jun. 1, 1995Cyclic lactams are prepared by reacting amino carbonitriles with water in liquid phase in a fixed bed reactor in the presence of heterogeneous catalysts which have no soluble constituents under the reaction conditions.

公开(公告)号：AU8143594A

公开(公告)日：1995-06-13

申请号：AU8143594

申请日：1994-11-15

Applicant: BASF AG

Inventor： FUCHS EBERHARD ,  WITZEL TOM

IPC: C07D223/10 ,  C07D201/08

Abstract: PCT No. PCT/EP94/03782 Sec. 371 Date May 16, 1996 Sec. 102(e) Date May 16, 1996 PCT Filed Nov. 15, 1994 PCT Pub. No. WO95/14665 PCT Pub. Date Jun. 1, 1995Cyclic lactams are prepared by reacting amino carbonitriles with water in liquid phase in a fixed bed reactor in the presence of heterogeneous catalysts which have no soluble constituents under the reaction conditions.