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公开(公告)号：CA2655739C
公开(公告)日：2014-03-25
申请号：CA2655739
申请日：2007-06-14
Applicant: EVONIK DEGUSSA GMBH
Inventor： WERLE PETER , KRIMMER HANS-PETER , SCHMIDT MANFRED , STADTMUELLER KLAUS , TRAGESER MARTIN
IPC: C07D251/34
Abstract: The invention is directed to an improved, reliably performable process for preparing triallyl isocyanurate (TAIC) by Cu2+-catalysed rearrangement of triallyl cyanurate (TAC) at at least 90°C. According to the invention, TAC and, if required, also a Cu2+ catalyst and solvent are fed continuously to a start reaction mixture after onset of the initially inhibited isomerization reaction, the isomerization is performed at from 90 to 160°C and an amount of reaction mixture equivalent to the amount of reactant is drawn off continuously and sent to the workup. Preference is given to effecting the isomerization in TAIC as the reaction medium.
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公开(公告)号：PT2066622E
公开(公告)日：2014-02-05
申请号：PT06793479
申请日：2006-09-13
Applicant: EVONIK DEGUSSA GMBH
Inventor： WERLE PETER , MERZ FRIEDHELM , TRAGESER MARTIN
IPC: C07C277/08 , C07C279/28
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公开(公告)号：BRPI0714426A2
公开(公告)日：2013-02-13
申请号：BRPI0714426
申请日：2007-06-14
Applicant: EVONIK DEGUSSA GMBH
Inventor： WERLE PETER , KRIMMER HANS-PETER , SCHMIDT MANFRED , STADTMUELLER KLAUS , TRAGESER MARTIN
IPC: C07D251/34
Abstract: Preparation of triallylisocyanurate comprises rearranging triallylcyanurate in the presence of copper (II) salts (0.01-1 wt.%) at at least 90[deg]C, preferably 90-160[deg]C; introducing separately or in a mixture of triallylcyanurate and copper (II) salts into the triallylisocyanurate; cooling the reaction mixture at less than 90[deg]C; continuously adding the reaction mixture and isolating the triallylisocyanurate from the reaction mixture.
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公开(公告)号：AU2007271863B2
公开(公告)日：2012-04-05
申请号：AU2007271863
申请日：2007-06-14
Applicant: EVONIK DEGUSSA GMBH
Inventor： STADTMULLER KLAUS , WERLE PETER , KRIMMER HANS-PETER , SCHMIDT MANFRED , TRAGESER MARTIN
IPC: C07D251/34
Abstract: The invention is directed to an improved, reliably performable process for preparing triallyl isocyanurate (TAIC) by Cu-catalysed rearrangement of triallyl cyanurate (TAC) at at least 90°C. According to the invention, TAC and, if required, also a Cu catalyst and solvent are fed continuously to a start reaction mixture after onset of the initially inhibited isomerization reaction, the isomerization is performed at from 90 to 160°C and an amount of reaction mixture equivalent to the amount of reactant is drawn off continuously and sent to the workup. Preference is given to effecting the isomerization in TAIC as the reaction medium.
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公开(公告)号：UA94110C2
公开(公告)日：2011-04-11
申请号：UAA200901027
申请日：2007-06-14
Applicant: EVONIK DEGUSSA GMBH
Inventor： WERLE PETER , KRIMMER HANS-PETER , SCHMIDT MANFRED , STADTMUELLER KLAUS , TRAGESER MARTIN
IPC: C07D251/34
Abstract: Взаявкеописанулучшенный, надежныйспособполучениятриаллилизоцианурата (ТАИЦ) спомощьюкатализированной Cu2+ перегруппировкитриаллилцианурата (ТАЦ) притемпературенениже 90 °C. ВконтекстеданногоизобретенияТАЦи, еслиэтонеобходимо, такжеудерживающий Cu2+ катализатори растворительнепрерывновводятв исходнуюреакционнуюсмесьпосленачалапротеканияпреждеподавленнойреакцииизомеризации, изомеризациюпроводятпритемпературеот 90 до 160 °C иколичествореакционнойсмеси, эквивалентноеколичествуреагента, непрерывноотбираюти направляютнаобработку. Изомеризациюпреимущественнопроводятв ТАИЦкакреакционнойсреде.
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Patent Agency Ranking
公开(公告)号：HK1132276A1
公开(公告)日：2010-02-19
申请号：HK09112349
申请日：2009-12-31
Applicant: EVONIK DEGUSSA GMBH
Inventor： WERLE PETER , HANS-PETER KRIMMER H , SCHMIDT MANFRED , STADTMUELLER KLAUS , TRAGESER MARTIN
IPC: C07D20060101
Abstract: Preparation of triallylisocyanurate comprises rearranging triallylcyanurate in the presence of copper (II) salts (0.01-1 wt.%) at at least 90[deg]C, preferably 90-160[deg]C; introducing separately or in a mixture of triallylcyanurate and copper (II) salts into the triallylisocyanurate; cooling the reaction mixture at less than 90[deg]C; continuously adding the reaction mixture and isolating the triallylisocyanurate from the reaction mixture.
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公开(公告)号：ZA200900459B
公开(公告)日：2010-01-27
申请号：ZA200900459
申请日：2009-01-20
Applicant: EVONIK DEGUSSA GMBH
Inventor： HAEFNER VOLKER , SUCHSLAND HELMUT , WERLE PETER
IPC: C07D20100101
Abstract: The invention relates to an improved process for preparing triallyl cyanurate (TAC) by reacting cyanuric chloride with allyl alcohol in the presence of an alkali metal acid acceptor and in the absence of an organic solvent other than allyl alcohol. According to the invention, TAC is obtained in over 99% purity with an APHA colour number below 10 in a yield of over 90% when 3.9 to 6.0 mol of allyl alcohol and 3.0 to 3.2 equivalents of acid acceptor are used per mole of cyanuric chloride, cyanuric chloride and acid acceptor are added simultaneously or successively to anhydrous or at least 50% by weight aqueous allyl alcohol, and the reaction is performed in one or more stages at a temperature in the range of -5 to +50°C.
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公开(公告)号：DE602006007957D1
公开(公告)日：2009-09-03
申请号：DE602006007957
申请日：2006-02-24
Applicant: EVONIK DEGUSSA GMBH
Inventor： HARREN JOERG , ISSBERNER JOERG , WALDEN MIRKO , TENI RAINER , FURNO FRANCK , WERLE PETER , KRIMMER HANS-PETER
Abstract: The present invention relates to a process for producing postcrosslinked water-absorbing polymeric formations, comprising the steps of contacting water-absorbing polymeric formations P1 obtained by polymerization of ethylenically unsaturated acid-functional monomers or salts thereof in the presence of a crosslinker with a fluid F1 comprising a postcrosslinker, heating the water-absorbing polymeric formations in contact with the fluid F1 to a temperature in a range from 40 to 300° C. to obtain postcrosslinked water-absorbing polymeric formations P2, the water-absorbing polymeric formations P1 having a thermal stability, as determined in accordance with the test method described herein, of less than 3.0%. The invention also relates to water-absorbing polymeric formations, to the water-absorbing polymeric formations obtainable by this process, to water-absorbing polymeric formations based on crosslinked carboxyl-bearing monomers, to a composite comprising water-absorbing polymeric formations and a substrate, to a process for producing a composite, to a composite obtainable by this process, to chemical products comprising water-absorbing polymeric formations or a composite, to the use of water-absorbing polymeric formations or of a composite in chemical products and also to the use of triallyl isocyanurate as an internal crosslinker in the production of water-absorbing polymeric formations based on crosslinked carboxyl-bearing monomers.
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公开(公告)号：AT437197T
公开(公告)日：2009-08-15
申请号：AT06708497
申请日：2006-02-24
Applicant: EVONIK DEGUSSA GMBH
Inventor： HARREN JOERG , ISSBERNER JOERG , WALDEN MIRKO , TENI RAINER , FURNO FRANCK , WERLE PETER , KRIMMER HANS-PETER
Abstract: The present invention relates to a process for producing postcrosslinked water-absorbing polymeric formations, comprising the steps of contacting water-absorbing polymeric formations P1 obtained by polymerization of ethylenically unsaturated acid-functional monomers or salts thereof in the presence of a crosslinker with a fluid F1 comprising a postcrosslinker, heating the water-absorbing polymeric formations in contact with the fluid F1 to a temperature in a range from 40 to 300° C. to obtain postcrosslinked water-absorbing polymeric formations P2, the water-absorbing polymeric formations P1 having a thermal stability, as determined in accordance with the test method described herein, of less than 3.0%. The invention also relates to water-absorbing polymeric formations, to the water-absorbing polymeric formations obtainable by this process, to water-absorbing polymeric formations based on crosslinked carboxyl-bearing monomers, to a composite comprising water-absorbing polymeric formations and a substrate, to a process for producing a composite, to a composite obtainable by this process, to chemical products comprising water-absorbing polymeric formations or a composite, to the use of water-absorbing polymeric formations or of a composite in chemical products and also to the use of triallyl isocyanurate as an internal crosslinker in the production of water-absorbing polymeric formations based on crosslinked carboxyl-bearing monomers.
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公开(公告)号：DE102006032167A1
公开(公告)日：2007-02-22
申请号：DE102006032167
申请日：2006-07-12
Applicant: DEGUSSA
Inventor： WERLE PETER , KRIMMER HANS-PETER , SCHMIDT MANFRED , STADTMUELLER KLAUS , TRAGESER MARTIN
IPC: C07D251/34
Abstract: Preparation of triallylisocyanurate comprises rearranging triallylcyanurate in the presence of copper (II) salts (0.01-1 wt.%) at at least 90[deg]C, preferably 90-160[deg]C; introducing separately or in a mixture of triallylcyanurate and copper (II) salts into the triallylisocyanurate; cooling the reaction mixture at less than 90[deg]C; continuously adding the reaction mixture and isolating the triallylisocyanurate from the reaction mixture.
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