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    PRODUCTION OF AMINE FROM IMINE OR NITRILE
    2.
    发明专利
    PRODUCTION OF AMINE FROM IMINE OR NITRILE 失效

    公开(公告)号：JPH11222465A

    公开(公告)日：1999-08-17

    申请号：JP30855598

    申请日：1998-10-29

    Applicant: DEGUSSA

    Inventor： HAAS THOMAS DR ,  WEBER KARL-LUDWIG DR ,  STADTMUELLER KLAUS ,  HOFEN WILLI ,  VANHEERTUM RUDOLF DR

    IPC: B01J23/75 ,  C07B61/00 ,  C07C209/48 ,  C07C209/52 ,  C07C211/36

    Abstract: PROBLEM TO BE SOLVED: To obtain the subject compound in a high yield with reducing the formation of by-product, by using an imine or nitrile and hydrogen, hydrogenating the imine or nitrile by amination in the presence of a specific hydrogenation catalyst under specific conditions. SOLUTION: An imine or nitrile, especially isophoronenitrile is hydrogenated by using hydrogen by amination in the presence of a hydrogenating catalyst basically comprising ammonium, cobalt, nickel, ruthenium or these metal mixture and a hydroxide, especially quaternary ammonium hydroxide at 50-250 deg.C under 0.3-30 MPa and the reaction mixture is subjected to after-treatment to give a primary amine and/or a secondary amine, especially isophoronediamine. Isophoronenitrile-imine is 3-cyano-3,5,5-trimethylcyclohexaneimine and isophoronediamine is 3-aminomethyl-3,5,5-trimethylcyclohexylamine.

    PROCESS FOR PREPARING TRIALLYL ISOCYANURATE (TAIC)
    3.
    发明申请
    PROCESS FOR PREPARING TRIALLYL ISOCYANURATE (TAIC) 审中-公开
    制备三烯异氰脲酸酯（TAIC）的方法

    公开(公告)号：WO2008006661A3

    公开(公告)日：2008-02-28

    申请号：PCT/EP2007055879

    申请日：2007-06-14

    Applicant: EVONIK DEGUSSA GMBH ,  WERLE PETER ,  KRIMMER HANS-PETER ,  SCHMIDT MANFRED ,  STADTMUELLER KLAUS ,  TRAGESER MARTIN

    Inventor： WERLE PETER ,  KRIMMER HANS-PETER ,  SCHMIDT MANFRED ,  STADTMUELLER KLAUS ,  TRAGESER MARTIN

    IPC: C07D251/34

    CPC classification number: C07D251/34

    Abstract: The invention is directed to an improved, reliably performable process for preparing triallyl isocyanurate (TAIC) by Cu 2+ -catalysed rearrangement of triallyl cyanurate (TAC) at at least 90°C. According to the invention, TAC and, if required, also a Cu 2+ catalyst and solvent are fed continuously to a start reaction mixture after onset of the initially inhibited isomerization reaction, the isomerization is performed at from 90 to 160°C and an amount of reaction mixture equivalent to the amount of reactant is drawn off continuously and sent to the workup. Preference is given to effecting the isomerization in TAIC as the reaction medium.

    Abstract translation: 本发明涉及一种通过在至少90℃下氰脲酸三烯丙酯（TAC）的Cu2 + +催化重排制备三烯丙基异氰脲酸酯（TAIC）的改进的，可靠实施的方法。 根据本发明，在最初抑制的异构化反应开始后，将TAC和如果需要的还有Cu +2 + /催化剂和溶剂连续加入到起始反应混合物中，异构化在90℃ 加热至160℃，连续排出与反应物量相当的量的反应混合物并送至后处理。 优选在TAIC中作为反应介质进行异构化。

    PROCESS FOR PREPARING TRIALLYL ISOCYANURATE (TAIC)
    6.
    发明专利
    PROCESS FOR PREPARING TRIALLYL ISOCYANURATE (TAIC) 未知

    公开(公告)号：CA2655739A1

    公开(公告)日：2008-01-17

    申请号：CA2655739

    申请日：2007-06-14

    Applicant: EVONIK DEGUSSA GMBH

    Inventor： STADTMUELLER KLAUS ,  WERLE PETER ,  KRIMMER HANS-PETER ,  SCHMIDT MANFRED ,  TRAGESER MARTIN

    IPC: C07D251/34

    Abstract: The invention is directed to an improved, reliably performable process fo r preparing triallyl isocyanurate (TAIC) by Cu2+-catalysed rearrangement of triallyl cyanurate (TAC) at at least 90øC. According to the invention, TAC a nd, if required, also a Cu2+ catalyst and solvent are fed continuously to a start reaction mixture after onset of the initially inhibited isomerization reaction, the isomerization is performed at from 90 to 160øC and an amount o f reaction mixture equivalent to the amount of reactant is drawn off continu ously and sent to the workup. Preference is given to effecting the isomeriza tion in TAIC as the reaction medium.

    7.
    发明专利
    未知

    公开(公告)号：DE102005009322A1

    公开(公告)日：2006-09-14

    申请号：DE102005009322

    申请日：2005-03-01

    Applicant: DEGUSSA

    Inventor： GROEN HEIDI ,  SCHUETTE RUEDIGER ,  DRAUZ KARLHEINZ ,  STADTMUELLER KLAUS ,  GRAYSON JAMES IAN

    IPC: B01F23/00

    Abstract: The present invention relates to an oscillatory flow mixing reactor (OPM) oscillatory flow which is designed so that a flow with angular momentum is superposed by means effecting circular acceleration on the mixture flowing in with oscillation, with the result that good mixing of the individual phases of the mixture is achieved with the use of low shear forces. A use of the reactor according to the invention is also disclosed.

    9.
    发明专利
    未知

    公开(公告)号：DE10252413A1

    公开(公告)日：2004-05-27

    申请号：DE10252413

    申请日：2002-11-12

    Applicant: DEGUSSA

    Inventor： RUWWE JOHANNES ,  STADTMUELLER KLAUS

    IPC: C07C213/08 ,  C07C215/08 ,  C07C215/00 ,  C07C29/70 ,  C07C31/30 ,  C07C41/26 ,  C07C323/10

    Abstract: Production of solutions of alkali metal salts (I) of functionalized alcohols (II) in a solvent mixture including (II), by reacting (II) with an alkali metal alkoxide or hydroxide (III), comprises distilling off part of the released alkanol or water without adding an entrainer and then distilling off the rest using another organic solvent as entrainer. Production of solutions of alkali metal salts of formula MOYXR1 (I) by reacting a functionalized alcohol of formula HOYXR1 (II) with an alkali metal alkoxide or hydroxide of formula MOR2 (III) to form a solution of (I) in a solvent mixture including (II), comprises distilling off part of the released alkanol or water without adding an entrainer and then distilling off the rest using another organic solvent as entrainer. M = Li, Na, K, Rb or Cs; Y = 1-8C alkylene; X = O, S or NR1; R1 = H, 1-8C alkyl, 2-8C alkenyl, 2-8C alkynyl, 3-8C cycloalkyl, 6-18C aryl, 7-19C aralkyl, 3-18C heteroaryl or 4-19C heteroaralkyl, where cycloalkyl, aryl and heteroaryl are optionally substituted by 1-3 of 1-8C alkyl; and R2 = H, Me, Et, Pr, i-Pr, s-Bu, i-Bu or t-Bu.

    PROCESS FOR PREPARING SOLUTIONS OF ALKALI METAL SALTS OF FUNCTIONALIZED ALCOHOLS
    10.
    发明专利
    PROCESS FOR PREPARING SOLUTIONS OF ALKALI METAL SALTS OF FUNCTIONALIZED ALCOHOLS 未知

    公开(公告)号：CA2448839C

    公开(公告)日：2010-10-05

    申请号：CA2448839

    申请日：2003-11-10

    Applicant: DEGUSSA

    Inventor： RUWWE JOHANNES ,  STADTMUELLER KLAUS

    IPC: C07C31/30 ,  C07C31/08 ,  C07C31/12 ,  C07C31/28 ,  C07C213/08 ,  C07C215/08

    Abstract: Disclosed is a process for preparing an alkali metal salt of a functionalized alcohol of the formula (I): MOYXR1 (I), (wherein M is Li, Na, K, Rb, or Cs, Y is (C1-C6)-alkylene, X is O, S, or NR1, R1 is H, (C1-C8)-alkyl, (C2-C8)-alkenyl, (C2-C8)-alkynyl, (C3-C8)-cycloalkyl, (C6-C18)-aryl, (C7-C19)-aralkyl, (C3-C18)-heteroaryl, (C4-C19)-heteroaralkyl, ((C1-C8)-alkyl)1-3-(C3-C8)-cycloalkyl, ((C1-C8)-alkyl)1-3- (C6-C18)-aryl, or ((C1-C8)-alkyl)1-3- (C3-C18)-heteroaryl) by reacting the corresponding alcohol with an alkali metal hydroxide or an alkali metal alkoxide of the formula MOR2 (II) (where R2 is lower alkyl), and the distilling liberated alcohol HOR2 or the liberated water at first without an entrainer and then with an added entrainer.

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