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公开(公告)号：WO2009002710A1
公开(公告)日：2008-12-31
申请号：PCT/US2008/066582
申请日：2008-06-11
Applicant: H R D CORPORATION , BAGHERZADEH, Ebrahim , HASSAN, Abbas , ANTHONY, Rayford G. , BORSINGER, Gregory R. , HASSAN, Aziz
Inventor： BAGHERZADEH, Ebrahim , HASSAN, Abbas , ANTHONY, Rayford G. , BORSINGER, Gregory R. , HASSAN, Aziz
CPC classification number: C07C51/56 , B01F7/00766 , B01F13/1013 , B01F13/1016 , B01J8/025 , B01J8/20 , B01J19/0066 , B01J19/1806 , B01J2219/00006 , B01J2219/00779 , Y02P20/582 , C07C53/12
Abstract: A system and method for a high shear mechanical device incorporated into a process for the production of acetic anhydride as a reactor device is shown to be capable of decreasing mass transfer limitations, thereby enhancing the process. A system for the production of acetic anhydride including the mixing of catalyst and acetic acid via a high shear device.
Abstract translation: 结合到生产乙酸酐作为反应器装置的方法中的高剪切机械装置的系统和方法被证明能够降低传质限制，从而增强该方法。 一种用于生产乙酸酐的系统，包括通过高剪切装置混合催化剂和乙酸。
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公开(公告)号：WO2011068781A2
公开(公告)日：2011-06-09
申请号：PCT/US2010/058294
申请日：2010-11-30
Applicant: H R D CORPORATION , HASSAN, Abbas , HASSAN, Aziz , BORSINGER, Gregory, G. , VISWANATHAN, Krishnan , ANTHONY, Rayford, G. , BAGHERZADEH, Ebrahim
Inventor： HASSAN, Abbas , HASSAN, Aziz , BORSINGER, Gregory, G. , VISWANATHAN, Krishnan , ANTHONY, Rayford, G. , BAGHERZADEH, Ebrahim
IPC: C07C29/50 , C07C35/08 , C07C45/33 , C07C49/403 , B01J19/18
CPC classification number: B01F7/00766 , B01F13/1013 , B01F13/1016 , B01J8/22 , B01J19/008 , B01J19/1806 , B01J2219/00105 , C07C29/132 , C07C29/50 , C07C45/33 , C07C45/53 , C07C2601/14 , C07C49/403 , C07C35/08
Abstract: Disclosed herein is a method for cyclohexane oxidation. The method comprises a) forming a dispersion comprising liquid cyclohexane and an oxidant gas utilizing a high shear device, wherein the dispersion comprises oxidant gas bubbles with a mean diameter of less than about 5 µm, and wherein the high shear device comprises at least one rotor and at least one stator; and b) hydrogenating the dispersion in the presence of a hydrogenation catalyst to form a product comprising cyclohexanol or cyclohexanone. In some embodiments, the oxidant comprises air, oxygen-enriched air, oxygen, or an oxygen-containing gas. In some embodiments, step a) of the method comprises forming the dispersion in the presence of an oxidation catalyst. Also disclosed herein is a system for oxidizing cyclohexane.
Abstract translation: 本文公开了环己烷氧化法。 该方法包括：a）使用高剪切装置形成包含液体环己烷和氧化剂气体的分散体，其中分散体包含平均直径小于约5μm的氧化剂气泡，并且其中高剪切装置包括至少一个转子 和至少一个定子; 和b）在氢化催化剂存在下氢化分散体以形成包含环己醇或环己酮的产物。 在一些实施方案中，氧化剂包括空气，富氧空气，氧气或含氧气体。 在一些实施方案中，该方法的步骤a）包括在氧化催化剂存在下形成分散体。 本文还公开了一种用于氧化环己烷的体系。
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73.发明申请SYSTEM AND PROCESS FOR PRODUCTION OF FATTY ACIDS AND WAX ALTERNATIVES FROM TRIGLYCERIDES 审中-公开用于生产来自TRIGLYCERIDES的脂肪酸和WAX替代品的系统和方法
公开(公告)号：WO2009017909A2
公开(公告)日：2009-02-05
申请号：PCT/US2008/068169
申请日：2008-06-25
Applicant: H R D CORPORATION , HASSAN, Abbas , BAGHERZADEH, Ebrahim , ANTHONY, Rayford G. , BORSINGER, Gregory , HASSAN, Aziz
Inventor： HASSAN, Abbas , BAGHERZADEH, Ebrahim , ANTHONY, Rayford G. , BORSINGER, Gregory , HASSAN, Aziz
CPC classification number: B01F13/1013 , B01F7/00766 , B01F7/00791 , B01F13/1016 , C11C3/00 , C11C3/12 , C11C3/123 , C11C5/002
Abstract: A method of producing volatilized fatty acids by heating a feedstock comprising at least one fat or oil in a reactor under inert vacuum to volatilize fatty acids, and removing volatilized fatty acids from bottoms residue comprising cross-linked oil. A system for stripping fatty acids from triglycerides, the system comprising a reactor, heating apparatus and a vacuum pump capable of pulling a vacuum in the range of from 1 kPa to 50 kPa on the reactor. A system for producing a hydrogenated product including a reactor comprising an inlet for a stream comprising triglycerides, an outlet for volatilized fatty acids, and an outlet for a cross-linked product, heating apparatus, a vacuum pump capable of pulling a vacuum in the range of from 1 kPa to 50 kPa on the reactor, and a hydrogenation reactor, wherein an inlet of the hydrogenation reactor is fluidly connected to the outlet for cross-linked product.
Abstract translation: 通过在惰性真空下在反应器中加热包含至少一种脂肪或油的原料来挥发脂肪酸并从包含交联油的底部残留物中除去挥发的脂肪酸来生产挥发性脂肪酸的方法。 用于从甘油三酯中汽提脂肪酸的系统，该系统包括反应器，加热装置和真空泵，其能够在反应器上拉动1kPa至50kPa范围内的真空。 一种用于生产氢化产物的系统，其包括反应器，该反应器包括用于包含甘油三酯的流的入口，用于挥发的脂肪酸的出口和用于交联产物的出口，加热装置，能够拉伸该范围内的真空的真空泵 在反应器上为1kPa至50kPa，以及氢化反应器，其中氢化反应器的入口流体连接到用于交联产物的出口。
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公开(公告)号：WO2009003052A1
公开(公告)日：2008-12-31
申请号：PCT/US2008/068218
申请日：2008-06-25
Applicant: H R D CORPORATION , HASSAN, Abbas , BAGHERZADEH, Ebrahim , ANTHONY, Rayford G. , BORSINGER, Gregory , HASSAN, Aziz
Inventor： HASSAN, Abbas , BAGHERZADEH, Ebrahim , ANTHONY, Rayford G. , BORSINGER, Gregory , HASSAN, Aziz
CPC classification number: C07C29/04 , B01F7/00766 , B01F13/1013 , B01F13/1016 , B01J8/025 , B01J8/20 , B01J19/0066 , B01J19/1806 , B01J2219/00006 , B01J2219/00779 , C07C29/48 , C07C31/225
Abstract: Methods and systems for the hydroxylation of olefenic alcohols are described herein. The methods and systems incorporate the novel use of a high shear device to promote mixing and solubility of peroxides with the olefenic alcohol. The high shear device may allow for lower reaction temperatures and pressures and may also reduce hydroxylation time with existing catalysts.
Abstract translation: 本文描述了烯醇的羟基化的方法和系统。 该方法和系统结合了高剪切装置的新用途，以促进过氧化物与烯醇的混合和溶解。 高剪切装置可以允许较低的反应温度和压力，并且还可以用现有催化剂降低羟基化时间。
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公开(公告)号：WO2009003047A1
公开(公告)日：2008-12-31
申请号：PCT/US2008/068207
申请日：2008-06-25
Applicant: H R D CORPORATION , HASSAN, Abbas , BAGHERZADEH, Ebrahim , ANTHONY, Rayford G. , BORSINGER, Gregory , HASSAN, Aziz
Inventor： HASSAN, Abbas , BAGHERZADEH, Ebrahim , ANTHONY, Rayford G. , BORSINGER, Gregory , HASSAN, Aziz
IPC: C07C29/141 , C07C1/207 , C07C27/00 , B01F7/26
CPC classification number: B01J19/1806 , B01F7/00766 , B01F13/1027 , B01F2215/0481 , B01J8/025 , B01J8/20 , B01J19/0066 , B01J19/1862 , B01J2219/00006 , B01J2219/00779 , C07C29/141 , C07C29/145 , C07C31/02
Abstract: Methods and systems for the hydrogenation of aldehydes and/or ketones are described herein. The methods and systems incorporate the novel use of a high shear device to promote dispersion and solubility of the hydrogen-containing gas (e.g. H 2 gas) in the aldehydes and/or ketones. The high shear device may allow for lower reaction temperatures and pressures and may also reduce hydrogenation time with existing catalysts.
Abstract translation: 本文描述了醛和/或酮的氢化的方法和系统。 所述方法和系统包括高剪切装置的新用途，以促进含氢气体（例如H 2气体）在醛和/或酮中的分散和溶解度。 高剪切装置可以允许较低的反应温度和压力，并且还可以减少现有催化剂的氢化时间。
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Patent Agency Ranking
公开(公告)号：WO2009003046A1
公开(公告)日：2008-12-31
申请号：PCT/US2008/068206
申请日：2008-06-25
Applicant: H R D CORPORATION , HASSAN, Abbas , BAGHERZADEH, Ebrahim , ANTHONY, Rayford G. , BORSINGER, Gregory , HASSAN, Aziz
Inventor： HASSAN, Abbas , BAGHERZADEH, Ebrahim , ANTHONY, Rayford G. , BORSINGER, Gregory , HASSAN, Aziz
CPC classification number: B01F7/00766 , B01F13/1013 , B01F13/1016 , B01J14/00 , B01J19/0066 , B01J19/185 , B01J2219/00006 , B01J2219/00189 , C07C67/08 , Y02P20/127 , C07C69/80
Abstract: Methods and systems for the production of phthalic acid diesters are described herein. The methods and systems incorporate the novel use of a high shear device to promote dispersion and mixing of a phtalic acid derivative with alcohol. The high shear device may allow for lower reaction temperatures and pressures and may also reduce reaction time with existing catalysts.
Abstract translation: 本文描述了用于生产邻苯二甲酸二酯的方法和系统。 方法和系统包括高剪切装置的新用途，以促进邻苯二甲酸衍生物与醇的分散和混合。 高剪切装置可以允许较低的反应温度和压力，并且还可以减少与现有催化剂的反应时间。
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公开(公告)号：WO2009002962A1
公开(公告)日：2008-12-31
申请号：PCT/US2008/067977
申请日：2008-06-24
Applicant: H R D CORPORATION , HASSAN, Abbas , BAGHERZADEH, Ebrahim , ANTHONY, Rayford G. , BORSINGER, Gregory , HASSAN, Aziz
Inventor： HASSAN, Abbas , BAGHERZADEH, Ebrahim , ANTHONY, Rayford G. , BORSINGER, Gregory , HASSAN, Aziz
CPC classification number: B01J8/025 , B01F7/00766 , B01F13/1013 , B01F13/1016 , B01F2215/0036 , B01J8/20 , B01J19/0066 , B01J19/1806 , B01J2208/00876 , B01J2219/00006 , B01J2219/00779 , C10G11/10 , C10G47/00 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/4081
Abstract: A method for hydrocracking a feedstream comprising liquid hydrocarbon by forming a dispersion comprising hydrogen-containing gas bubbles dispersed in the liquid hydrocarbon, wherein the bubbles have a mean diameter of less than about 5 microns, and introducing the dispersion into a hydrocracker comprising hydrocracking catalyst. A method for hydrocracking by subjecting a fluid mixture comprising hydrogen-containing gas and liquid hydrocarbons to a shear rate greater than 20,000 s -1 to produce a dispersion of hydrogen in a continuous phase of the liquid hydrocarbons, and introducing the dispersion into a fixed bed hydrocracking reactor from which a hydrocracked product is removed. A system for hydrocracking a hydrocarbonaceous feedstream including at least one high shear device capable of producing a tip speed of the at least one rotor of greater than 5.0 m/s, and a hydrocracker containing hydrocracking catalyst and comprising an inlet fluidly connected to an outlet of the high shear device.
Abstract translation: 一种用于通过形成包含分散在液态烃中的含氢气泡的分散体来加氢裂化含有液态烃的进料流的方法，其中气泡具有小于约5微米的平均直径，并将该分散体引入包含加氢裂化催化剂的加氢裂化器中。 一种通过使包含含氢气体和液体烃的流体混合物经受大于20,000s -1的剪切速率的加氢裂化的方法，以产生氢气在液体烃的连续相中的分散体，并将该分散体引入固定床 加氢裂化反应器从其中除去加氢裂化产物。 一种用于加氢裂化含烃原料流的系统，包括至少一个能够产生大于5.0m / s的至少一个转子的尖端速度的高剪切装置和含有加氢裂化催化剂的加氢裂化器，并且包括流体连接到 高剪切装置。
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公开(公告)号：WO2009002734A1
公开(公告)日：2008-12-31
申请号：PCT/US2008/066909
申请日：2008-06-13
Applicant: H R D CORPORATION , HASSAN, Abbas , BAGHERZADEH, Ebrahim , ANTHONY, Rayford, G. , BORSINGER, Gregory , HASSAN, Aziz
Inventor： HASSAN, Abbas , BAGHERZADEH, Ebrahim , ANTHONY, Rayford, G. , BORSINGER, Gregory , HASSAN, Aziz
IPC: C07C205/06 , C01B17/88 , B01J23/24
CPC classification number: C07C201/08 , B01F7/00766 , B01F13/1013 , B01F13/1016 , C07C205/06
Abstract: A method for producing nitrobenzene is disclosed which comprises forming a dispersion comprising benzene-containing droplets or particles dispersed in a mixture of concentrated nitric acid and concentrated sulfuric acid, wherein said particles have a mean diameter less than one micron, and subjecting the dispersion to reaction conditions comprising a pressure in the range of about 203 kPa (2 atm) to about 6080 kPa (60 atm) and a temperature in the range of about 20°C to about 230°C, whereby at least a portion of said benzene is nitrated to form nitrobenzene. A system for carrying out the method is also disclosed.
Abstract translation: 公开了一种制备硝基苯的方法，其包括形成包含分散在浓硝酸和浓硫酸的混合物中的含苯液滴或颗粒的分散体，其中所述颗粒的平均直径小于1微米，并使分散体反应 包括在约203kPa（2atm）至约6080kPa（60atm）范围内的压力和约20℃至约230℃范围内的温度的条件，由此至少一部分所述苯被硝化 形成硝基苯。 还公开了一种用于执行该方法的系统。
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公开(公告)号：WO2010002534A2
公开(公告)日：2010-01-07
申请号：PCT/US2009/045967
申请日：2009-06-02
Applicant: H R D CORPORATION , HASSAN, Abbas , ANTHONY, Rayford, G. , BORSINGER, Gregory , HASSAN, Aziz , BAGHERZADEH, Ebrahim
Inventor： HASSAN, Abbas , ANTHONY, Rayford, G. , BORSINGER, Gregory , HASSAN, Aziz , BAGHERZADEH, Ebrahim
CPC classification number: B01J19/1806 , B01F7/00766 , B01F7/00791 , B01F13/1013 , B01F13/1016 , B01J8/20 , B01J8/22 , B01J10/007 , B01J14/005 , B01J19/008 , B01J2219/00105 , B01J2219/1941 , C07C29/04 , C07C29/106 , C07C45/34 , C07C45/39 , C07C51/265 , C07C67/08 , C07C209/36 , C07C2601/16 , C12C11/02 , C07C31/22 , C07C31/225 , C07C35/14 , C07C31/202 , C07C31/207 , C07C31/205 , C07C47/06 , C07C49/04 , C07C49/08 , C07C63/06 , C07C69/003 , C07C211/46 , C07C211/50 , C07C69/14
Abstract: A reactor comprising at least one contact surface made from, coated with, or impregnated by a catalyst, wherein the contact surface comprises a sintered metal or a ceramic, and wherein the reactor is configured to subject a reactant stream to shear. A system for carrying out a heterogeneously catalyzed reaction, the system comprising a reactor as described above and a pump configured for delivering reactants to the at least one reactor. A method for carrying out a heterogeneously-catalyzed reaction by introducing reactants into a reactor comprising at least one contact surface made from, coated with, or impregnated by a catalyst under conditions which promote production of a desired product, wherein the contact surface comprises a sintered metal or a ceramic, and forming a dispersion of reactants within the reactor, wherein the dispersion comprises droplets or gas bubbles of reactant with an average diameter of less than about 5um.
Abstract translation: 一种反应器，包括由催化剂制成，涂覆或浸渍的至少一个接触表面，其中所述接触表面包括烧结金属或陶瓷，并且其中所述反应器构造成使反应物流受到剪切。 一种用于进行非均相催化反应的系统，该系统包括如上所述的反应器和构造成将反应物输送到至少一个反应器的泵。 一种通过将反应物引入反应器中进行非均相催化反应的方法，所述反应器包括在促进所需产物生产的条件下由催化剂制备，涂覆或浸渍的至少一个接触表面，其中所述接触表面包括烧结 金属或陶瓷，并且在反应器内形成反应物的分散体，其中分散体包含平均直径小于约5um的反应物的液滴或气泡。
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公开(公告)号：WO2009003053A2
公开(公告)日：2008-12-31
申请号：PCT/US2008/068219
申请日：2008-06-25
Applicant: H R D CORPORATION , HASSAN, Abbas , BAGHERZADEH, Ebrahim , ANTHONY, Rayford G. , BORSINGER, Gregory , HASSAN, Aziz
Inventor： HASSAN, Abbas , BAGHERZADEH, Ebrahim , ANTHONY, Rayford G. , BORSINGER, Gregory , HASSAN, Aziz
CPC classification number: C07C29/106 , B01F7/00766 , B01F13/1013 , B01F13/1016 , B01J8/025 , B01J8/20 , B01J19/0066 , B01J19/1806 , B01J2219/00006 , B01J2219/00779 , C07C31/202
Abstract: Methods and systems for preparing alkylene glycols are described herein. The methods and systems incorporate the novel use of a high shear device to promote dispersion and solubility of alkylene oxides with water. The high shear device may allow for lower reaction temperatures and pressures and may also reduce reaction time.
Abstract translation: 本文描述了制备亚烷基二醇的方法和系统。 该方法和系统结合了高剪切装置的新用途，以促进环氧烷与水分散和溶解。 高剪切装置可以允许较低的反应温度和压力，并且还可以减少反应时间。
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