PROCESS FOR THE MANUFACTURE OF WATERADSORBING CELLULOSE ETHERS

    公开(公告)号:ZA762708B

    公开(公告)日:1977-04-27

    申请号:ZA762708

    申请日:1976-05-06

    Applicant: HOECHST AG

    Abstract: This invention relates to an improvement in the process for the production of water-adsorbing, but at least partially water-insoluble, cellulose ethers in which cellulose is alkalized in a liquid reaction medium and etherified in a manner such that by etherification only an at least largely water-soluble carboxymethyl cellulose, carboxymethyl hydroxyethyl cellulose, hydroxyethyl cellulose or methyl hydroxyethyl cellulose is produced, and in which the cellulose is reacted in an alkaline reaction medium before, during, or after the etherification with a cross-linking agent which is polyfunctional towards cellulose and selected from the group consisting of acrylamido methylene chloroacetamide, dichloroacetic acid, phosphorous oxychloride, or a compound in which at least two groups functional towards cellulose are the acrylamido group the chloroazomethine group the allyloxy azomethine group the improvement comprising effecting alkalization, etherification, and cross-linking in a liquid reaction medium other than isopropyl alcohol.

    PROCESS FOR THE MANUFACTURE OF WATERADSORBING BUT WATER-INSOLUBLE CELLULOSE ETHERS

    公开(公告)号:ZA762704B

    公开(公告)日:1977-04-27

    申请号:ZA762704

    申请日:1976-05-05

    Applicant: HOECHST AG

    Abstract: This invention relates to an improvement in the process for the production of water-adsorbing, but at least partially water-insoluble cellulose ethers in which cellulose is alkalized in a liquid reaction medium and etherified in a manner such that by etherification only an at least largely water-soluble carboxymethyl cellulose, carboxymethyl hydroxyethyl cellulose, hydroxyethyl cellulose or methyl hydroxyethyl cellulose is produced, and in which the cellulose is reacted in an alkaline reaction medium before, during, or after the etherification with a modification agent reactive with the still free hydroxyl groups of the cellulose anhydro glucose groups, said modification agent having one of the formulae I II in which R1 is hydroxyl, an acylamino or esterified carbamino group, and R2 is hydrogen or a carboxyl group, THE IMPROVEMENT COMPRISING EFFECTING ALKALIZATION, ETHERIFICATION, AND MODIFICATION IN A LIQUID REACTION MEDIUM OTHER THAN ISOPROPYL ALCOHOL.

    80.
    发明专利
    未知

    公开(公告)号:SE7610611L

    公开(公告)日:1977-03-28

    申请号:SE7610611

    申请日:1976-09-24

    Applicant: HOECHST AG

    Inventor: HOLST A KOSTRZEWA M

    Abstract: This invention relates to an improvement in the process for the manufacture of water-absorbing, but largely water-insoluble cellulose ethers, wherein cellulose is etherified with a halogen fatty acid in an alkaline medium to which organic solvents may be added, to such an extent that without a further reaction a water-soluble cellulose ether would be produced, and wherein, prior to, during, or after etherification, a further reaction is carried out with a cross-linking agent which is polyfunctional towards cellulose in an alkaline reaction medium, the improvement comprising that chips of regenerated cellulose film are used as cellulose.

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