公开(公告)号：US5789510A

公开(公告)日：1998-08-04

申请号：US859820

申请日：1997-05-19

Applicant: Matthias Krull ,  Werner Reimann

Inventor： Matthias Krull ,  Werner Reimann

IPC: C10M159/12 ,  C08F2/38 ,  C08F4/32 ,  C08F4/36 ,  C08F210/02 ,  C08L23/08 ,  C08L31/04 ,  C10L1/197 ,  C10M145/02 ,  C10M145/08 ,  C10M157/04 ,  C10M161/00 ,  C08F232/08 ,  C08F218/08

CPC classification number: C10L1/1973 ,  C08F210/02 ,  C10M145/02 ,  C10M145/08 ,  C10M157/04 ,  C10M161/00 ,  C10M2207/12 ,  C10M2209/02 ,  C10M2209/04 ,  C10M2209/06 ,  C10M2209/062 ,  C10M2209/086 ,  C10M2215/08 ,  C10M2215/082 ,  C10M2215/086 ,  C10M2215/12 ,  C10M2215/122 ,  C10M2217/024 ,  C10M2217/06

Abstract: Terpolymers obtained by copolymerization of ethylene, a vinyl ester of at least one aliphatic monocarboxylic acid of 2 to 20 carbon atoms in the molecule and bicyclo�2.2.1!hept-2-ene (also referred to as norbornene) or its derivatives, a process for their preparation and their use as additives for mineral oils and mineral oil distillates.

Abstract translation: 通过乙烯，分子中至少一个2至20个碳原子的脂族单羧酸的乙烯基酯和双环[2.2.1]庚-2-烯（也称为降冰片烯）或其衍生物共聚获得的三元共聚物， 其制备方法及其作为矿物油和矿物油馏分的添加剂使用。

公开(公告)号：US09039870B2

公开(公告)日：2015-05-26

申请号：US12444678

申请日：2007-10-05

Applicant: Matthias Krull ,  Christoph Kayser ,  Roman Morschhaeuser ,  Helmut Ritter ,  Sarah Schmitz

Inventor： Matthias Krull ,  Christoph Kayser ,  Roman Morschhaeuser ,  Helmut Ritter ,  Sarah Schmitz

IPC: B01J19/12 ,  C07C231/02 ,  C07D213/75 ,  C07D249/08

CPC classification number: C07C231/02 ,  B01J19/126 ,  C07D213/75 ,  C07D249/08 ,  C07C233/38 ,  C07C233/44

Abstract: The invention relates to a method for producing alkaline amides or imides of ethylenically unsaturated C3 to C6 carboxylic acids by reacting amines that contain at least one primary and/or secondary amino group and at least one tertiary amino group with ethylenically unsaturated C3 to C6 carboxlic acids to form an ammonium salt and said ammonium salt is subsequently converted into the alkaline amide or imide by means of microwave radiation, with the proviso that the primary and/or secondary amino group is devoid of alkoxy groups.

Abstract translation: 本发明涉及通过使含有至少一个伯氨基和/或仲氨基和至少一个叔氨基的胺与烯键式不饱和C3至C6羧酸反应生产烯属不饱和C3至C6羧酸的碱性酰胺或酰亚胺的方法 以形成铵盐，然后所述铵盐随后通过微波辐射转化成碱性酰胺或酰亚胺，条件是伯和/或仲氨基没有烷氧基。

公开(公告)号：US09029160B2

公开(公告)日：2015-05-12

申请号：US14001325

申请日：2012-02-14

Applicant: Michael Feustel ,  Michael Brauchle ,  Dominko Andrin ,  Matthias Krull

Inventor： Michael Feustel ,  Michael Brauchle ,  Dominko Andrin ,  Matthias Krull

IPC: G01N33/28 ,  C10G21/14

CPC classification number: G01N33/287 ,  C10G21/14 ,  C10G2300/1033 ,  C10G2300/1048 ,  C10G2300/202 ,  C10G2300/207 ,  C10G2300/4006 ,  C10G2300/44 ,  G01N33/28 ,  Y10T436/182 ,  Y10T436/184

Abstract: The subject of the invention is a method for determining the H2S content arising during the warm storage of sulfur-containing crude and residual oils and mineral distillates containing sulfur-containing crude and/or residual oils, in which a sample of the sulfur-containing mineral oil is dissolved in a solvent or solvent mixture that boils at more than 200° C. and a carrier gas is caused to flow through the solution of the sulfur-containing mineral oil at temperatures above 80° C., and the quantity of hydrogen sulfide carried out with the carrier gas is analyzed quantitatively.

Abstract translation: 本发明的主题是确定在含硫含粗油和/或残余油的含硫原油和残余油和矿物馏出物的热储存期间产生的H 2 S含量的方法，其中含硫矿物样品 油溶解在沸点高于200℃的溶剂或溶剂混合物中，并使载气在高于80℃的温度下流过含硫矿物油的溶液，并且硫化氢的量 对载气进行定量分析。

公开(公告)号：US08974743B2

公开(公告)日：2015-03-10

申请号：US13378258

申请日：2010-06-09

Applicant: Matthias Krull ,  Roman Morschhaeuser

Inventor： Matthias Krull ,  Roman Morschhaeuser

IPC: A62D3/00 ,  C07C1/32 ,  B01J19/12 ,  C07C67/08 ,  C07C231/02 ,  C07D307/60 ,  H05B6/80 ,  B01J19/00 ,  B01J19/24 ,  B01J7/00 ,  B01J8/00 ,  B01J10/00 ,  B01J12/00 ,  H05B6/64 ,  H05B6/68 ,  H05B6/70 ,  A62D3/10 ,  A62D3/17

CPC classification number: C07C1/321 ,  B01J19/126 ,  B01J2219/0871 ,  B01J2219/1227 ,  C07C67/08 ,  C07C231/02 ,  C07C2531/24 ,  C07D307/60 ,  H05B6/80 ,  H05B6/806 ,  C07C15/14 ,  C07C69/24 ,  C07C69/52 ,  C07C233/05 ,  C07C233/09 ,  C07C233/36

Abstract: The invention relates to a device for continuously carrying out chemical reactions. The device comprises a microwave generator, a microwave applicator accommodating a microwave-transparent tube, and an isothermal reaction section which is arranged such that the material to be reacted is guided inside the microwave-transparent tube through a microwave applicator which is used as the heating zone and in which it is heated to reaction temperature by means of microwaves that are emitted from the microwave generator into the microwave applicator. The material to be reacted, which is heated and optionally under pressure, is transferred from the microwave applicator to an isothermal reaction zone once it has left the heating zone, said reaction zone being arranged downstream of the heating zone, and is cooled once it has left the isothermal reaction zone.

Abstract translation: 本发明涉及连续进行化学反应的装置。 该装置包括微波发生器，容纳微波透明管的微波加热器和等温反应部分，该等温反应部分被布置为使得待反应的材料通过微波加热器被引导到微波透明管内部，该微波加热器用作加热 区域，并且通过从微波发生器发射到微波施加器中的微波将其加热至反应温度。 待加热和任选在压力下的材料一旦离开加热区，就从微波加热器转移到等温反应区，所述反应区设置在加热区的下游，并且一旦冷却 离开等温反应区。

公开(公告)号：US08734542B2

公开(公告)日：2014-05-27

申请号：US12664997

申请日：2008-06-17

Applicant: Matthias Krull ,  Robert Janssen

Inventor： Matthias Krull ,  Robert Janssen

IPC: C10L1/18

CPC classification number: C10L1/146 ,  C10L1/1641 ,  C10L1/1963 ,  C10L1/1973 ,  C10L1/1981 ,  C10L1/2222 ,  C10L1/224 ,  C10L1/2383

Abstract: The invention relates to the use of at least one oil-soluble compound B) which acts as a nucleating agent for paraffin crystallization and which is selected from ethylene copolymers and 2 to 10.5 mole % of at least one ethylenically unsaturated carbonic ester for improving the response of cold flow improvers for mineral oils C), which are different from B), in middle distillates that contain at least one ashless, nitrogenous detergent additive A), which is an oil-soluble, amphiphilic compound that comprises at least one alkyl or alkenyl group bound to a polar group, said alkyl or alkenyl group having 10 to 500 C atoms and the polar group having 2 or more nitrogen atoms.

Abstract translation: 本发明涉及至少一种用作石蜡结晶的成核剂的油溶性化合物B），其选自乙烯共聚物和2至10.5摩尔％的至少一种烯键式不饱和碳酸酯，用于改善反应 在含有至少一种无灰，含氮洗涤剂添加剂A）的中间馏分中的与B）不同的矿物油C）的冷流改进剂，其是包含至少一个烷基或烯基的油溶性两亲化合物 基团与极性基团结合，所述烷基或烯基具有10至500个C原子，极性基团具有2个或更多个氮原子。

公开(公告)号：US08628591B2

公开(公告)日：2014-01-14

申请号：US12665010

申请日：2008-06-17

Applicant: Matthias Krull ,  Werner Reimann ,  Robert Janssen

Inventor： Matthias Krull ,  Werner Reimann ,  Robert Janssen

IPC: C10L1/18 ,  C10L1/22

CPC classification number: C10L1/143 ,  C10L1/1608 ,  C10L1/1641 ,  C10L1/1817 ,  C10L1/1981 ,  C10L1/2222 ,  C10L1/224 ,  C10L1/2383 ,  C10L10/14

Abstract: The invention relates to the use of at least one oil-soluble compound B) which acts as a nucleating agent for paraffin crystallization and which is selected from substantially linear hydrocarbons with at least 22 C atoms, for improving the response of cold flow improvers for mineral oils C) in middle distillates that contain at least one ashless, nitrogenous detergent additive A), which is an oil-soluble, amphiphilic compound that comprises at least one alkyl or alkenyl group bound to a polar group, said alkyl or alkenyl group having 10 to 500 C atoms and the polar group having 2 or more nitrogen atoms.

Abstract translation: 本发明涉及至少一种用作石蜡结晶的成核剂的油溶性化合物B）的用途，其选自具有至少22个C原子的基本上直链的烃，以改善用于矿物质的冷流改进剂的响应 油C）在含有至少一种无灰，含氮洗涤剂添加剂A）的中间馏分中，其是包含与极性基团结合的至少一个烷基或烯基的油溶性两亲化合物，所述烷基或烯基具有10 至500个C原子和具有2个或更多个氮原子的极性基团。

公开(公告)号：US20120103790A1

公开(公告)日：2012-05-03

申请号：US13378151

申请日：2010-06-09

Applicant: Matthias Krull ,  Roman Morschhaeuser

Inventor： Matthias Krull ,  Roman Morschhaeuser

IPC: C07C51/00

CPC classification number: C07C67/08 ,  B01J19/126 ,  B01J2219/1215 ,  B01J2219/1227 ,  B01J2219/1272 ,  B01J2219/1281 ,  B01J2219/1284 ,  B01J2219/129 ,  H05B6/701 ,  H05B6/806 ,  C07C69/68 ,  C07C69/54 ,  C07C69/14 ,  C07C69/24

Abstract: The invention relates to a continuous method for producing aliphatic carbonic acid esters by reacting at least one aliphatic carboxylic acid of formula (I) R1—COOH (I), wherein R1 represents hydrogen or an optionally substituted aliphatic hydrocarbon group with 1 to 50 carbon atoms, with at least one alcohol of formula (II) R2—(OH)n (II), wherein R2 represents an optionally substituted hydrocarbon group with 1 to 100 C atoms and n is an integer from 1 to 10, in the presence of at least one transesterification catalyst in a reaction tube the longitudinal axis of which extends in the direction of propagation of the microwaves of a monomode microwave applicator, under microwave irradiation to form the ester.

Abstract translation: 本发明涉及通过使至少一种式（I）R1-COOH（I）的脂族羧酸（其中R 1表示氢或任选取代的脂族烃基与1至50个碳原子）反应制备脂族碳酸酯的连续方法 与（II）R 2 - （OH）n（II）的至少一种醇，其中R 2表示任选取代的具有1至100个C原子的烃基，n为1至10的整数，在 在微波照射下，反应管中的至少一个酯交换催化剂的纵轴在微波微波施加器的微波的传播方向上延伸以形成酯。

公开(公告)号：US20120088918A1

公开(公告)日：2012-04-12

申请号：US13378167

申请日：2010-06-09

Applicant: Matthias Krull ,  Roman Morschhaeuser

Inventor： Matthias Krull ,  Roman Morschhaeuser

IPC: C07D213/803 ,  C07C67/08

CPC classification number: B01J19/126 ,  B01J2219/1215 ,  B01J2219/1227 ,  B01J2219/1272 ,  B01J2219/1281 ,  B01J2219/1284 ,  C07C67/08 ,  C07D213/79 ,  H05B6/701 ,  H05B6/806 ,  C07C69/78 ,  C07C69/82 ,  C07C69/76 ,  C07C69/84

Abstract: The invention relates to a continuous method for producing aromatic carboxylic acid esters by reacting at least one aromatic carboxylic acid of formula (I) Ar—COOH (I), wherein Ar represents an optionally substituted aryl group with 5 to 50 atoms, with at least one alcohol of formula (II) R2—(OH)n (II), wherein R2 represents an optionally substituted hydrocarbon group with 1 to 100 C atoms and n is an integer from 1 to 10, in the presence of at least one transesterification catalyst in a reaction tube, the longitudinal axis of which extends in the direction of propagation of the microwaves of a monomode microwave applicator, under microwave irradiation to form the ester.

Abstract translation: 本发明涉及通过使至少一种式（I）Ar-COOH（I）的芳族羧酸（其中Ar表示任选取代的具有5至50个原子的芳基）与芳族羧酸酯反应生成芳族羧酸酯的方法， 一种式（II）的醇R 2 - （OH）n（II），其中R 2表示任选取代的具有1至100个C原子的烃基，n是1至10的整数，在至少一种酯交换催化剂 在反应管中，其纵轴在微波辐射下在微波微波施加器的微波的传播方向上延伸以形成酯。

公开(公告)号：US08067635B2

公开(公告)日：2011-11-29

申请号：US12444655

申请日：2007-10-05

Applicant: Matthias Krull ,  Roman Morschhaeuser ,  Alexander Lerch ,  Helmut Ritter ,  Sarah Schmitz

Inventor： Matthias Krull ,  Roman Morschhaeuser ,  Alexander Lerch ,  Helmut Ritter ,  Sarah Schmitz

IPC: C07C231/02

CPC classification number: C07C231/02 ,  Y02P20/582 ,  C07C233/65

Abstract: The invention relates to a method for producing tertiary amides of alkylphenyl carboxylic acids by reacting at least one secondary amine with at least one alkylphenyl carboxylic acid to form an ammonium salt, said ammonium salt being subsequently converted into the tertiary amide by means of microwave radiation.

Abstract translation: 本发明涉及通过使至少一种仲胺与至少一种烷基苯基羧酸反应形成铵盐来生产烷基苯基羧酸叔酰胺的方法，所述铵盐随后通过微波辐射转化成叔酰胺。

公开(公告)号：US20110089021A1

公开(公告)日：2011-04-21

申请号：US12935720

申请日：2009-03-18

Applicant: Matthias Krull ,  Roman Morschhaeuser

Inventor： Matthias Krull ,  Roman Morschhaeuser

IPC: C07C51/06

CPC classification number: C07C231/02 ,  B01J19/126 ,  C07C233/05 ,  C07C233/65 ,  C07C235/06 ,  C07C235/34

Abstract: The invention relates to a method for producing carboxylic acid amides, according to which at least one carboxylic acid of formula (I) R3—COON   (I) wherein R3 is hydrogen or an optionally substituted hydrocarbon radical comprising between 1 and 50 carbon atoms, is reacted with at least one amine of formula (II) HNR1R2   (II) wherein R1 and R2 are independently hydrogen or an optionally substituted hydrocarbon radical comprising between 1 and 100 C atoms, to form an ammonium salt, and said ammonium salt is reacted in the presence of superheated water, under microwave irradiation, to form a carboxylic acid amide.

Abstract translation: 本发明涉及一种制备羧酸酰胺的方法，根据该方法，至少一种式（I）的R 3 -COON（I）羧酸或其中R 3为氢或含有1至50个碳原子的任选取代的烃基的羧酸是 与至少一种式（II）的胺HNR1R2（II）反应，其中R 1和R 2独立地是氢或包含1至100个C原子的任选取代的烃基，以形成铵盐，并且所述铵盐在 在微波照射下存在过热水，形成羧酸酰胺。