Oxidising composition for hair treatment

    公开(公告)号:FR2769219A1

    公开(公告)日:1999-04-09

    申请号:FR9712359

    申请日:1997-10-03

    Applicant: OREAL

    Abstract: Cosmetic and/or dermatological composition for treating keratinic fibres comprises a carrier, at least one 2-electron oxidoreductase enzyme, at least one substrate for the enzyme, and at least one basic amino acid. Preferably the enzyme is an animal, microbial or recombinant uricase and is present in an amount of 0.01-20 (preferably 0.1-5) wt.%. The substrate is selected from uric acid and its salts and is present in an amount of 0.01-20 (preferably 0.1-5) wt.%. The amino acid is histidine, lysine, arginine, ornithine or citrulline and is present in an amount of 0.01-20 (preferably 0.05-5) wt.% The composition can contain 0.0005-12 wt.% of an oxidation dye precursor selected from p-phenylenediamines, "double bases", o- or p-aminophenols and heterocyclic bases. The composition can contain 0.0001-10 wt.% of a coupler selected from m-phenylenediamines, m-aminophenols, m-diphenols and heterocyclic couplers. The composition can also contain a direct dye. The carrier is water or a mixture of water and an organic solvent. The composition contains 1-40 (preferably 5-30) wt.% organic solvent. The composition has a pH of 5-11, preferably 6.5-10. Used for bleaching human hair by applying the composition, optionally containing an auxiliary oxidising agent, and then rinsing; for dyeing human hair by applying a composition as above containing an oxidation dye precursor and optionally a coupler; for permanent waving of human hair by applying a reducing composition, putting the hair under tension, optionally rinsing the hair, applying a composition as above, and optionally rinsing the hair.

    REDUCTIVE COMPOSITION CONTAINING BASIC AMINO-ACID AND CATIONIC POLYMER

    公开(公告)号:HU9600193D0

    公开(公告)日:1996-03-28

    申请号:HU9600193

    申请日:1996-01-29

    Applicant: OREAL

    Abstract: A cosmetic compsn. for the first stage of permanent waving of keratinous matter, esp. hair, involving reducing the disulphide bonds of the keratin, contains (a) an agent for reducing the di-sulphide keratin bonds, (b) ornithine, lysine or arginine as alkalising agent, and (c) a cationic polymer contg. prim., sec. or tert. amine gps. or quat. ammonium gps. in the main chain. Pref. the cpds. are sulphites, bisulphites and/or thiols (pref.), esp. cysteine or derivs., cysteamine or derivs., or 3-mercapto- propionic, thiolactic or thioglycolic acid or their ester or salts, opt. associated with a disulphide, and used in amt. of 1-20 (5-15)wt.% of the compsn.; (b) Arginine is pref. opt. with other alkalising agent, e.g. NH4OH, monoethanolamine or a carbonate, esp. to neutralise the acid reducing agents, in amt. of 0.1-18% of the reducing compsn.; (c) The polymer (i) contains piperazinyl units and (hydroxy)- alkylene units, opt. broken by O, S, N or aromatic or heterocyclic rings, and opt. the oxidn. or quaternisation derivs., (ii) is a water-sol. polyaminoamide, opt. cross-linked and/or alkylated, (iii) is a deriv. of a polyaminoamide obtd. by condensn. of polyalkylene polyamines and polycarboxylic acids, followed by alkylation with bifunctional agents.

    75.
    发明专利
    未知

    公开(公告)号:DE69102783T2

    公开(公告)日:1994-12-15

    申请号:DE69102783

    申请日:1991-01-29

    Applicant: OREAL

    Inventor: DE LABBEY ARNAUD

    Abstract: Cosmetic reducing composition for hair. This composition contains as reducing agents for the disulphide bonds of keratin, the combination of an ester of thioglycolic acid and of an N-acyl-(C2-C4)-cysteamine, the pH of the composition being below 8. Use of the composition in a permanent hair deforming method for its waving, its uncurling or straightening.

    76.
    发明专利
    未知

    公开(公告)号:ES2057791T3

    公开(公告)日:1994-10-16

    申请号:ES91400198

    申请日:1991-01-29

    Applicant: OREAL

    Inventor: DE LABBEY ARNAUD

    Abstract: Cosmetic reducing composition for hair. This composition contains as reducing agents for the disulphide bonds of keratin, the combination of an ester of thioglycolic acid and of an N-acyl-(C2-C4)-cysteamine, the pH of the composition being below 8. Use of the composition in a permanent hair deforming method for its waving, its uncurling or straightening.

    77.
    发明专利
    未知

    公开(公告)号:FR2685201B1

    公开(公告)日:1994-03-18

    申请号:FR9116019

    申请日:1991-12-23

    Applicant: OREAL

    Abstract: PCT No. PCT/FR92/01223 Sec. 371 Date Aug. 19, 1994 Sec. 102(e) Date Aug. 19, 1994 PCT Filed Dec. 22, 1992 PCT Pub. No. WO93/12763 PCT Pub. Date Jul. 8, 1993Use of 4-[2-oxo-3-bornylidene)methyl]-phenyltrimethylammonium methyl sulphate to preserve the hair's mechanical properties, and especially its elasticity, from the ravages caused by the successive action of permanent hair shaping and light. The compound is for use in a quantity of between 0.05 and 15% by weight, in an aqueous reducing or setting composition or a composition employed in between these two steps, to achieve permanent hair shaping.

    78.
    发明专利
    未知

    公开(公告)号:DE68902985T2

    公开(公告)日:1993-02-04

    申请号:DE68902985

    申请日:1989-12-05

    Applicant: OREAL

    Abstract: Process for dyeing keratinous fibres, comprising the step of applying to these fibres at least one composition A containing, in a medium appropriate for dyeing, at least one mono- or di-hydroxyindole the application of the composition A being preceded or followed by the application of a composition B containing, in a medium appropriate for dyeing, at least one quinone derivative chosen from ortho- or para-benzoquinones, monoimines or diimines of ortho- or para-benzoquinones, 1,2- or 1,4-naphthoquinones, sulphonimides of ortho- or para-benzoquinones, alpha , omega -alkylene-bis-1,4-benzoquinones, or 1,2- or 1,4-naphthoquinone-monoimines or -diimines; the mono- or di-hydroxyindoles and the quinone derivatives being chosen such that the oxidation-reduction potential difference DELTA E between the oxidation-reduction potential Ei of the mono- or di-hydroxyindoles, determined at pH 7 in a phosphate medium on a vitreous carbon electrode by voltametry, and the oxidation-reduction potential Eq of the quinone derivative determined at pH 7 in a phosphate medium by polarography on a mercury electrode and relative to a saturated calomel electrode is such that DELTA E=Ei-Eq

    PROCEDE DE TEINTURE DE FIBRES KERATINIQUES AVEC UN HYDROXYINDOLE, ASSOCIE A UN DERIVE QUINONIQUE ET NOUVELLES 1,4-BENZOQUINONES

    公开(公告)号:CA2004742A1

    公开(公告)日:1990-06-06

    申请号:CA2004742

    申请日:1989-12-06

    Applicant: OREAL

    Abstract: L'invention concerne un procédé de teinture des fibres kératiniques caractérisé par le fait que l'on applique sur ces fibres au moins une composition (A) contenant dans un milieu approprié pour la teinture au moins un mono- ou dihydroxyindole, l'application de la composition (A) étant précédée ou suivie par l'application d'une composition (B) contenant, dans un milieu approprié pour la teinture, au moins un dérivé quinonique choisi dans le groupe constitué par les ortho et para-benzoquinones, les ortho- ou parabenzoquinones monoimines ou diimines, les 1,2 et 1,4 naphtoquinones, les ortho- et para-benzoquinones sulfonimides, les .alpha.,.omega. -alkylène bis-1,4-benzoquinones, les 1,2- ou 1,4- naphtoquinones monoimines et diimines, et les mono- et dihydroxyindoles, le dérivé quinonique étant choisi de façon à ce que la différence de potentiel d'oxydoréduction .DELTA.E entre le potentiel d'oxydoreduction Ei du mono- ou dihydroxyindole déterminé à pH 7 en milieu phosphate sur électrode de carbone vitreux par voltamétrie, et le potentiel d'oxydoréduction Eq du dérivé quinonique déterminé à pH 7 en milieu phosphate par polarographie sur électrode de mercure par rapport à l'électrode au calomel saturé soit telle que .DELTA.E = Ei-Eq ? 320 mV. Grâce à ce procédé, il est particulièrement facile de teindre les cheveux naturels dans des tons très divers, des nuances claires aux nuances foncées.

    PROCEDE D'EVALUATION DE L'ETAT IONIQUE DES CHEVEUX

    公开(公告)号:CA1118669A

    公开(公告)日:1982-02-23

    申请号:CA331662

    申请日:1979-07-12

    Applicant: OREAL

    Abstract: ha présente invention concerne un procédé d'évaluation de l'état ionique (-), l'état ionique (+) et l'état ionique neutre de la surface de fibres kératiniques et notamment de cheveux humains. L'état ionique neutre est défini comme étant l'état d'un cheveu naturel n'ayant subi aucun traitement susceptible de modifier sa charge ionique. Ce procédé est caractérise en ce que l'on prélève au moins un échantillon de cheveux à partir d'un volume de cheveux à étudier et en ce que l'on fait agir sur l'échantillon prélevé, une solution à pH acide contenant au moins un colorant acide ou basique en une quantité suffisamment faible pour qu'en cas de réaction positive, l'adsorption du colorant concerne sur le cheveu provoque une variation sensible de la coloration de la solution, et qu'ensuite, on apprécie s'il y a eu variation ou non de la coloration de la solution.

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