公开(公告)号：WO2009091539A1

公开(公告)日：2009-07-23

申请号：PCT/US2009/000215

申请日：2009-01-14

Applicant: ENVIRONMENTAL ENERGY SERVICES, INC. ,  PASTORE, Mark, R.

Inventor： PASTORE, Mark, R.

IPC: C10L10/04

CPC classification number: F23J7/00 ,  C10L9/10 ,  C10L10/04 ,  C10L2200/0209 ,  C10L2200/0213 ,  C10L2200/0218 ,  C10L2200/0268 ,  C10L2200/029 ,  C10L2290/141 ,  F23B2700/023 ,  F23D1/00 ,  F23K2201/505

Abstract: There is provided a process for operating a coal- fired furnace to generate heat. The process has the steps of a) providing the coal to the furnace and b) combusting the coal in the presence of a first slag- reducing ingredient and a second slag-reducing ingredient in amounts effective to reduce slag formation in the furnace. The first slag-reducing ingredient and the second slag-reducing ingredient are different substances. The first slag-reducing ingredient is selected from the group consisting of magnesium carbonate, magnesium hydroxide, magnesium oxide, magnesium sulfate, and combinations thereof. The second slag-reducing ingredient is selected from the group consisting of copper acetate, copper nitrate, aluminum nitrate, aluminum oxide, aluminum hydroxide, and ammonium phosphate. There is also provided a method for reducing slag formation in a coal-fired furnace.

Abstract translation: 提供了一种操作燃煤炉以产生热量的方法。 该方法具有以下步骤：a）将煤提供给炉，以及b）在有效降低炉中形成炉渣的量下，在第一除渣成分和第二减渣成分的存在下燃烧煤。 第一种减渣成分和第二种减渣成分是不同的物质。 第一种减渣成分选自碳酸镁，氢氧化镁，氧化镁，硫酸镁及其组合。 第二减渣成分选自乙酸铜，硝酸铜，硝酸铝，氧化铝，氢氧化铝和磷酸铵。 还提供了一种在燃煤炉中减少炉渣形成的方法。

公开(公告)号：WO2006006978A1

公开(公告)日：2006-01-19

申请号：PCT/US2005/011881

申请日：2005-05-08

Applicant: NOX II INTERNATIONAL, LTD. ,  COMRIE, Douglas C. ,  VELLELLA, Vincent, A.

Inventor： COMRIE, Douglas C. ,  VELLELLA, Vincent, A.

IPC: C10L5/00

CPC classification number: C10L10/00 ,  B01D53/501 ,  B01D53/508 ,  B01D53/64 ,  B01D2251/304 ,  B01D2251/306 ,  B01D2251/404 ,  B01D2255/2047 ,  B01D2255/20738 ,  B01D2257/302 ,  B01D2257/602 ,  C10L9/10 ,  C10L10/02 ,  C10L10/04 ,  F23J7/00 ,  F23K1/00 ,  F23K2201/505

Abstract: A process for burning coal or other carbonaceous fuels captures sulfur and other undesirable compounds are captured and retained in non-reactive ceramic-like form after the combustion phase. The process involves addition of multiple element alkali powders and/or sorbents preferably containing oxidizing anions such as nitrates and nitrites, preferably based on calcium. In various embodiments, the remediation materials when applied in a complex powder and/or liquid containing multiple elements, result in higher sulfur capture than the materials would otherwise achieve on an individual basis. In a preferred embodiment, the sorbents contain elements that minimize or lower the melting point of the ash. This leads to lowered cohesiveness and toughness of the ash so that less ash builds up on the boiler and better heat transfer is obtained.

Abstract translation: 燃烧煤或其他含碳燃料的方法捕获硫，并且其它不期望的化合物在燃烧阶段之后被捕获并保持为非反应性陶瓷样形式。 该方法包括加入优选含有氧化性阴离子如硝酸盐和亚硝酸盐的多元素碱性粉末和/或吸附剂，优选基于钙。 在各种实施方案中，当应用于含有多种元素的复合粉末和/或液体中时，补救材料导致比单独以其他方式实现的材料更高的硫捕获。 在优选的实施方案中，吸附剂含有使灰分熔点最小化或降低的元素。 这导致灰分的凝聚力和韧性降低，使得较少的灰分积聚在锅炉上并且获得更好的热传递。

公开(公告)号：WO99011976A1

公开(公告)日：1999-03-11

申请号：PCT/FI1998/000681

申请日：1998-08-31

IPC: C10L9/10 ,  F23K1/02 ,  F23J7/00

CPC classification number: F23K1/02 ,  C10L9/10 ,  F23G2209/262 ,  F23K2201/505

Abstract: A method for preventing the sintering of bed material caused by the alkali metal alloys of low melting points contained in the fuel of a circulating fluidized-bed boiler or a fluidized-bed boiler. In the method, an auxiliary admixed with water is added to the fuel before feeding the fuel into the furnace, the auxiliary reacting with the alkali metal mixtures of low melting points contained in the fuel. The auxiliary is introduced admixed with water either in the form of a clearly aqueous solution or a damp slurry which mixes well with the fuel. There are many ways of determining the amount of auxiliary needed.

Abstract translation: 一种用于防止由循环流化床锅炉或流化床锅炉的燃料中包含的低熔点碱金属合金引起的床料烧结的方法。 在该方法中，在将燃料送入炉内之前，向燃料中加入与水混合的助剂，辅助剂与包含在燃料中的低熔点的碱金属混合物反应。 将辅助剂以明确的水溶液或与该燃料充分混合的潮湿浆液的形式与水混合。 确定所需辅助量的方法有很多种。

公开(公告)号：EP1854868B1

公开(公告)日：2015-04-22

申请号：EP06124971.0

申请日：2006-11-29

Applicant: GENERAL ELECTRIC COMPANY

Inventor： Widmer, Neil Colin ,  Taware, Avanish Vinayak

IPC: C10L10/04 ,  F22B35/00 ,  F23N1/02 ,  F23N5/00 ,  F23J3/00 ,  F23J7/00

CPC classification number: F23N1/022 ,  F22B35/00 ,  F23J3/00 ,  F23J7/00 ,  F23K2201/505 ,  F23N5/003 ,  F23N2037/02 ,  F23N2041/10

公开(公告)号：EP2714245A1

公开(公告)日：2014-04-09

申请号：EP12793161.6

申请日：2012-05-23

Applicant: Babcock and Wilcox Power Generation Group, Inc.

Inventor： GADGIL, Mandar, R. ,  GHORISHI, S., Behrooz

IPC: B01D53/64 ,  B01D53/46

CPC classification number: F23J15/003 ,  B01D53/46 ,  B01D53/64 ,  B01D53/8631 ,  B01D53/8696 ,  B01D53/90 ,  B01D2251/108 ,  B01D2251/304 ,  B01D2251/306 ,  B01D2251/404 ,  B01D2251/60 ,  B01D2255/20738 ,  B01D2257/55 ,  B01D2257/602 ,  B01D2258/0283 ,  F23C2201/101 ,  F23J7/00 ,  F23J15/006 ,  F23J2215/20 ,  F23J2217/101 ,  F23J2217/102 ,  F23J2219/10 ,  F23J2219/40 ,  F23J2219/60 ,  F23K2201/505 ,  F23N5/003

Abstract: The present invention relates generally to the field of emission control equipment for boilers, heaters, kilns, or other flue gas-, or combustion gas-, generating devices (e.g., those located at power plants, processing plants, etc.) and, in particular to a new and useful method and apparatus for reducing or preventing the poisoning and/or contamination of an SCR catalyst. In another embodiment, the method and apparatus of the present invention is designed to protect the SCR catalyst. In still another embodiment, the present invention relates to a method and apparatus for increasing the service life and/or catalytic activity of an SCR catalyst while simultaneously controlling various emissions.

公开(公告)号：EP1765962B1

公开(公告)日：2013-09-18

申请号：EP05734895.5

申请日：2005-05-08

Applicant: Nox II International, Ltd.

Inventor： COMRIE, Douglas C. ,  VELLELLA, Vincent, A.

IPC: C10L9/10 ,  B01D53/50 ,  F23K1/00 ,  B01D53/64

CPC classification number: C10L10/00 ,  B01D53/501 ,  B01D53/508 ,  B01D53/64 ,  B01D2251/304 ,  B01D2251/306 ,  B01D2251/404 ,  B01D2255/2047 ,  B01D2255/20738 ,  B01D2257/302 ,  B01D2257/602 ,  C10L9/10 ,  C10L10/02 ,  C10L10/04 ,  F23J7/00 ,  F23K1/00 ,  F23K2201/505

Abstract: A process for burning coal or other carbonaceous fuels captures sulfur and other undesirable compounds are captured and retained in non-reactive ceramic-like form after the combustion phase. The process involves addition of multiple element alkali powders and/or sorbents preferably containing oxidizing anions such as nitrates and nitrites, preferably based on calcium. In various embodiments, the remediation materials when applied in a complex powder and/or liquid containing multiple elements, result in higher sulfur capture than the materials would otherwise achieve on an individual basis. In a preferred embodiment, the sorbents contain elements that minimize or lower the melting point of the ash. This leads to lowered cohesiveness and toughness of the ash so that less ash builds up on the boiler and better heat transfer is obtained.

公开(公告)号：EP2624938A1

公开(公告)日：2013-08-14

申请号：EP11770638.2

申请日：2011-10-05

Applicant: Albemarle Corporation

Inventor： NALEPA, Christopher, J.

IPC: B01D53/64 ,  B01D53/83 ,  C10L9/10

CPC classification number: B01D53/64 ,  B01D2251/108 ,  B01D2257/602 ,  B01D2258/0283 ,  C10L9/10 ,  F23J7/00 ,  F23J2215/60 ,  F23K1/00 ,  F23K2201/505

Abstract: Processes and systems are provided for using bromine and/or bromide-containing organic compound to reduce mercury emissions during coal combustion.

公开(公告)号：EP2253885A2

公开(公告)日：2010-11-24

申请号：EP09252195.4

申请日：2009-09-16

Applicant: Pellet Technology LLC

Inventor： Zeeck, James R.

IPC: F23K1/00 ,  F23K1/02 ,  F23K3/00

CPC classification number: F23K1/00 ,  C10L5/44 ,  F23K1/02 ,  F23K3/00 ,  F23K2201/10 ,  F23K2201/20 ,  F23K2201/30 ,  F23K2201/50 ,  F23K2201/505 ,  F23K2203/103 ,  F23K2203/201 ,  Y02E50/10 ,  Y02E50/30

Abstract: A process is provided using non-food or limited-feed agricultural residue and energy crops for energy production, such as ethanol or electricity generation. The agricultural plant material is harvested and baled. The bales are transported to the processing site for storage or immediate processing. The bale strings are first removed, and then the broken bales are shredded. The shredded plant material is then ground to a small size. The ground material is then pelletized to produce densified pellets of the agricultural plant material. The pellets are cooled and then stored or transported to an end user.

Abstract translation: 提供了一种使用非食物或有限饲料农业残留物和能源作物进行能源生产的过程，如乙醇或发电。 农业植物材料被收获并且被打包。 大包被运送到加工现场进行储存或立即处理。 捆包绳首先被移除，然后破碎的捆被切碎。 粉碎的植物材料然后研磨成小尺寸。 然后将研磨的材料造粒，以生产农业植物材料的致密颗粒。 颗粒冷却后储存或运输至最终用户。

公开(公告)号：EP1993700A2

公开(公告)日：2008-11-26

申请号：EP07718228.5

申请日：2007-01-17

Applicant: Comrie, Douglas C.

Inventor： Comrie, Douglas C.

IPC: B01D45/00 ,  B01D46/00

CPC classification number: F23J7/00 ,  B01D53/83 ,  B01D2253/104 ,  B01D2253/106 ,  B01D2257/602 ,  F23J15/003 ,  F23J2215/60 ,  F23K1/00 ,  F23K2201/505 ,  G06Q10/30 ,  G06Q40/12 ,  Y02P90/90 ,  Y02W90/20 ,  Y10T436/12

Abstract: Methods involve adding sorbent components, such as calcium oxide, alumina, and silica, as well as optional halogens as part of environmental control. Use of the sorbents leads to significant reductions in sulfur and mercury emissions that otherwise would result from burning coal. Use of the sorbents leads to production of waste coal ash that, while higher in mercury, is nevertheless usable as a commercial product because the mercury in the ash is non-leaching and because the coal ash has a higher cementitious nature by virtue of the increased content of the sorbent components in the ash. Thus, the methods involve adding powders having qualities that lead to the production of a cementitious coal ash while at the same time reducing emissions from a coal burning facility.

Abstract translation: 方法包括添加吸附剂组分，如氧化钙，氧化铝和二氧化硅，以及可选的卤素作为环境控制的一部分。 吸附剂的使用导致硫和汞排放量的显着减少，否则会由于燃烧煤炭而降低。 吸附剂的使用导致产生废煤灰，尽管汞含量较高，但仍然可用作商业产品，因为灰中的汞不浸出，并且由于煤灰由于提高了的胶结性质 灰分中吸附剂组分的含量。 因此，这些方法涉及添加具有导致产生水泥煤灰质量的粉末，同时减少来自燃煤设施的排放。

公开(公告)号：EP0915175A1

公开(公告)日：1999-05-12

申请号：EP97905443.4

申请日：1997-03-05

Applicant: KAO CORPORATION

Inventor： ONO, Reiji, Kobe Steel Ltd. ,  NAKAYA, Takashi, Kobe Steel Ltd. ,  KIMURA, Yoshio, Kobe Steel Ltd. ,  KAMIJO, Tsunao, Kobe Steel Ltd. ,  MIYAMOTO, Kenichi, Kao Corporation ,  MATOBA, Takashi, Kao Corporation ,  OHASHI, Hidemi, Kao Corporation ,  ICHIMOTO, Takehiko, Kao Corporation

IPC: C21B5/00 ,  F23K3/00

CPC classification number: C21B5/003 ,  F23K1/00 ,  F23K3/00 ,  F23K3/02 ,  F23K2201/505

Abstract: The use of pulverized coal as the fuel to be injected into a metallurgical or combustion furnace becomes possible enabled by improving the transportability thereof. Further, a pulverized coal is provided, which is inhibited from bridging or channelling in a hopper, or piping choking.
A water-soluble inorganic salt having a polar group is made to adhere to pulverized coal which is prepared from raw coal having an average HGI of 30 or above and which is in a dry state at the injection port of a metallurgical or combustion furnace, the inorganic salt being selected from among BaCl 2 , CaCl 2 , Ca(NO 2 ) 2 , Ca(NO 3 ) 2 , Ca(ClO) 2 , K 2 CO 3 , KCl, MgCl 2 , MgSO 4 , NH 4 BF 4 , NH 4 Cl, (NH 4 ) 2 SO 4 , Na 2 CO 3 , NaCl, NaClO 3 , NaNO 2 , NaNO 3 , NaOH, Na 2 S 2 O 3 , NaS 2 O 5 , HNO 3 , H 2 SO 4 , H 2 CO 3 , and HCl.

Abstract translation: 通过提高其输送性，可以实现将粉煤作为喷射到冶金炉或燃烧炉中的燃料的使用。 此外，提供了一种粉碎煤，其被阻止在料斗中桥接或引导，或管道阻塞。 将具有极性基团的水溶性无机盐与由平均HGI为30以上且在冶金或燃烧炉的注入口处于干燥状态的原煤制成的粉煤附着， 无机盐选自BaCl 2，CaCl 2，Ca（NO 2）2，Ca（NO 3）2，Ca（ClO）2，K 2 CO 3，KCl，MgCl 2，MgSO 4，NH 4 BF 4，NH 4 Cl，（NH 4）2 SO 4，Na 2 CO 3，NaCl， ，NaNO 2，NaNO 3，NaOH，Na 2 S 2 O 3，Na 2 O 5，HNO 3，H 2 SO 4，H 2 CO 3和HCl。