Purificn. of brine water using amphoteric ion exchange resin - contg. acrylic!-methacrylic! acid (deriv.) polymer and polymer of styrene! amine deriv., tri:allylamine or propyl-di: allylamine

    公开(公告)号:FR2419756A1

    公开(公告)日:1979-10-12

    申请号:FR7807507

    申请日:1978-03-15

    Abstract: A process for purifying brine using a deionising step is claimed in which the brine water contg. bicarbonate ion and bisulphite ion and having a pH of 0.5-1.5 is treated with an amphoteric ion exchange resin contg. a weak acidic, higher mol material and a weak basic, higher hol material and thereby, the purified brine water is obtd. The weak acidic, higher mol material is chosen from a polymer of ethylenic unsatd. carboxylic acid or its polymer deriv. comprising a polymer of (meth)acrylic acid. The weak basic, higher mol material is chosen from a polymer of aromatic amine or aliphatic amine, comprising a polymer of amine deriv. of styrene, a polymer of triallylamine and a polymer of propyl-diallyl. amine. The process is used for producing a purified water contg. NaCl for industrial use.

    EXTRACTION OF COBALT, COPPER AND NICKEL VALUES FROM AMMONIACAL SOLUTIONS

    公开(公告)号:AU3296478A

    公开(公告)日:1979-08-09

    申请号:AU3296478

    申请日:1978-02-03

    Applicant: AMAX INC

    Abstract: Cobalt, copper and nickel values are separated from ammoniacal aqueous solutions by contacting the solutions with a chelate exchange resin of polymerized ar-vinylbenzylamino dicarboxylic acids whereby the cobalt, copper and nickel values are loaded on the chelate exchange resin, stripping the cobalt, copper and nickel values from the loaded chelate exchange resin by contacting the loaded resin with a mineral acid and restoring the capacity of the chelate exchange resin when it falls below a predetermined value by reacting the degraded chelate exchange resin with an aqueous solution of a halo salt of a carboxylic acid, the aqueous solution being maintained at a pH value greater than about 8.

    73.
    发明专利
    未知

    公开(公告)号:FR2411630A1

    公开(公告)日:1979-07-13

    申请号:FR7835275

    申请日:1978-12-14

    Abstract: Silica can be removed effectively from a mixed bed demineralizer containing an anion exchange resin and a cation exchange resin during regeneration by (1) PASSING FROM ABOUT 30 TO ABOUT 80 VOLUME % OF AN ANION REGENERANT SOLUTION THROUGH ONLY THE ANION EXCHANGE RESIN, (2) PASSING THE REMAINING PORTION OF THE ANION REGENERANT SOLUTION THROUGH BOTH THE ANION EXCHANGE RESIN AND THE CATION EXCHANGE RESIN, AND (3) PASSING A STREAM OF CATION REGENERANT SOLUTION THROUGH THE CATION EXCHANGE RESIN.

    74.
    发明专利
    未知

    公开(公告)号:FR2286675B1

    公开(公告)日:1979-06-22

    申请号:FR7529931

    申请日:1975-09-30

    Abstract: A regenerative base ion exchange process involving the step of passing a liquid upwardly through a bed of particulate solid base ion exchange resin in a chamber of a two-phase reactor to regenerate said resin, wherein the rate of liquid flow is such that the solid resin is compacted and held by the liquid as a compact bed against a barrier located above it and is prevented by the liquid from sinking.

    75.
    发明专利
    未知

    公开(公告)号:FR2408383A1

    公开(公告)日:1979-06-08

    申请号:FR7733795

    申请日:1977-11-09

    Abstract: Electrochemical properties of a cation exchange membrane of a carboxylic acid type fluorinated polymer which is used for an electrolysis of an aqueous solution of an alkali metal chloride is recovered by converting ion exchange groups of -COO)mM; wherein M represents an alkali metal or an alkaline earth metal; and m represents a valence of M; to the corresponding acid or ester groups of -COOR wherein R represents hydrogen or a C1 - C5 alkyl group and heat-treating the fluorinated polymer having the groups of -COOR.

    Regenerating spent anionic and cationic exchange resin mixt. - using a device contg. vertically assembled resin separator, ultrasonic purifier and bottom mixer

    公开(公告)号:DE2842729A1

    公开(公告)日:1979-04-05

    申请号:DE2842729

    申请日:1978-09-30

    Applicant: GEN ELECTRIC

    Abstract: Installation for regenerating a mixt. of spent anionic and cationic exchanger resins contains a resin separator, an ultrasonic resin purifier and a resin mixer, arranged vertically to one another. The resin separator is in the highest position, the purifier is directly below the separator and the mixer is directly below the purifier. A device is provided for conveying the spent resins to the separator, a device for allowing the resins to fall, by gravity, through ultrasonic purifier down to resin mixer; a device for actuating the ultrasonic purifier while the resins fall through it, so as to remove the impurities from resin; a device for charging a liq. carrier, e.g. water, countercurrently to resin, to carry impurities removed from resin to the separator, and also a device for removing the impurities from the resin separator. Plant serves partic. for purifying and chemically regenerating resins used in a condensate treatment system, esp. for a nuclear energy plant. Waste water quantity is reduced, e.g. from 38000 l. to 3800 l. Space is saved. Resins can be regenerated in which ratio cationic : anionic resin varies greatly. The separator can be used as anionic resin regenerator tank and the mixer as cationic resin regenerator tank.

    APPARATUS FOR WRAPPING PROTECTIVE TAPE AROUND A LENGTH OF PIPE

    公开(公告)号:AU497886B2

    公开(公告)日:1979-01-18

    申请号:AU2170377

    申请日:1977-01-27

    Applicant: ECODYNE CORP

    Abstract: A process for scrubbing undissolved impurities from the upper portion of an ion exchange resin filtration bed is disclosed wherein air is introduced in the upper portion of the bed and develops a pressure within the vessel. This pressure subsequently forces rinse water down through the upper portion of the bed and out of the vessel. The gas is introduced into the bed and the water is drained therefrom at a level below the bed's upper surface but above a substantial lower portion of the resin bed. In this manner, lesser quantities of scrubbing fluids are required and the majority of the resin material is left undisturbed to maintain maximum ion exchange capacity.

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