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公开(公告)号:US3645921A
公开(公告)日:1972-02-29
申请号:US3645921D
申请日:1970-04-20
Applicant: ECODYNE CORP
Inventor: SALEM ELI , BUTTERWORTH DONALD J , RYAN LEO F
CPC classification number: B01J49/07
Abstract: THE INVENTION RELATES TO A METHOD FOR CONVERTING STRONGBASE ANION EXCHANGE RESINS FROM THE MONOVALENT ANION FORM TO THE HYDROXIDE FORM. A SOLUTION OF POLYVALENT ANIONS IS FIRST PASSED THROUGH THE RESIN TO DISPLACE THE MONOVALENT ANIONS. A SOLUTION OF ALKALI METAL HYDROXIDE IS THEN PASSED THROUGH THE RESIN TO CONVERT IT TO THE HYDROXIDE FORM, AND TO PRODUCE AN EFFLUENT SOLUTION OF HYDROXIDE IONS AND POLYVALENT ANIONS. THIS EFFLUENT SOLUTION IS THEN NEUTRALIZED WITH AN ACID CONTAINING POLYVALENT ANIONS, AND THE NEUTRALIZED SOLUTION IS PASSED THROUGH A SECOND BATCH OF RESIN IN THE MONOVALENT ANION FORM. IN THE PREFERRED EMBODIMENT, A PORTION OF THE EFFLUENT IS RETAINED WITHOUT NEUTRALIZATION AND IS DELIVERED TO THE SECOND BATCH OF RESIN AFTER THE NEUTRALIZED EFFLUENT TO PERFORM A PORTION OF THE HYDROXIDE REGENERATION.
Abstract translation: 1339788转换阴离子交换树脂ECODYNE CORP 1971年4月19日[1970年4月20日] 26264/71标题C3P [也在B1部分具有季铵活性基团的强碱阴离子交换树脂从一价阴离子形式(氢氧化物除外)转化为 氢氧化物形式通过使多价阴离子的水源通过第一批树脂以用多价阴离子从树脂中取代一价阴离子; 随后将碱金属氢氧化物水溶液通过树脂将树脂转化为氢氧化物形式,并制备含有氢氧根阴离子和多价阴离子的含水流出物溶液; 用含有多价阴离子源的酸中和至少一部分流出物溶液以形成中和的多价阴离子源; 并使中和源以一价阴离子形式通过第二批树脂以从其中置换一价阴离子。 “一价阴离子形式”是指氢氧化物形式以外的树脂形式。 “中和源”仅比排出液更酸性,并且可以是酸性,中性或甚至碱性。 合适的树脂是通过使叔胺与单乙烯基芳族烃和二乙烯基芳族烃的卤代甲基化交联共聚物反应而制备的树脂, 苯乙烯和二乙烯基苯的共聚物与或不与乙基乙烯基苯。 其它合适的树脂是叔胺与卤代烷基化,优选氯甲基化的乙烯基芳族化合物的共聚物的反应产物,例如乙烯基芳族化合物。 苯乙烯或乙烯基茴香醚和少量的聚烯烃化合物,例如, 二乙烯基苯,异戊二烯,丁二烯或三乙烯基苯。 在该实施例中使用氢氧化钠,硫酸钠和硫酸。
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公开(公告)号:US3582504A
公开(公告)日:1971-06-01
申请号:US3582504D
申请日:1970-04-20
Applicant: ECODYNE CORP
Inventor: SALEM ELI , DUFF JOSEPH H
CPC classification number: B01J49/09
Abstract: IN THE REGENERATION OF MIXED-BED ION EXCHANGE RESINS, THE RESINS ARE FIRST SEPARATED IN THE CONVENTIONAL MANNER BY AN UPFLOW OF LIQUID. THE RESINS ARE THEN ISOLATED FROM ONE ANOTHER, AND CONTAMINANT CATION EXCHANGE RESIN IS SEPARATED FROM THE ANION EXHANGE RESIN BY FLOATING THE ANION EXCHANGE RESIN IN AN INTERMEDIATE-DENSITY LIQUID HAVING A DENSITY INTERMEDIATE BETWEEN THE CATION AND ANION EXCHANGE RESINS. THE CONTAMINANT CATION EXCHANGE RESIN SINKS TO THE BOTTOM OF THE VESSEL, PERMITTING THE ANION EXCHANGE RESIN TO BE READILY ISOLATED.
Abstract translation: 1310067离子交换ECODYNE CORP 1971年4月19日[1970年4月20日] 26263/71标题B1J通过将树脂分离成一层阳离子交换树脂和一层阴离子交换树脂与一些阴离子交换树脂再生,排出的阴离子和阳离子交换树脂的混合床 作为污染物存在的阳离子交换树脂,将阴离子交换树脂和污染物树脂转移到污染物分离区,其中使用两种树脂之间密度的氢氧化钠水溶液再生阴离子交换树脂并引起 漂浮和污染树脂下沉。 阳离子交换树脂被再生并转移到具有分离和再生的阴离子交换树脂的保持区,在那里它们在进入服务区之前混合。
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公开(公告)号:US3585127A
公开(公告)日:1971-06-15
申请号:US3585127D
申请日:1969-09-18
Applicant: ECODYNE CORP
Inventor: SALEM ELI
CPC classification number: B01J47/04
Abstract: A METHOD IS PROVIDED FOR THE TREATMENT OF WATER BY ION EXCHANGE WHILE ELIMINATING LEAKAGE. IN CARRYING OUT THE METHOD, WATER IS FIRST PASSED THROUGH A SERVICE LAYER OF ANION AND CATION EXHANGE RESINS IN A SERVICE ZONE IN THE CONVENTIONAL MANNER. SUBSEQUENTLY, THE WATER IS PASSED THROUGH A LEAKAGE BARRIER LAYER OF CATION EXCHANGE RESIN IN THE SERVICE ZONE. PERIODICALLY, THE RESINS IN THE SERVICE ZONE ARE SEPARATED IN A SEPARATION ZONE. THE ANION EXCHANGE RESIN IS THEN REGENERATED IN AN ANION RESIN REGENERATION ZONE, AND THE CATION EXHANGE RESIN IS REGENERATED IN A CATION RESIN REGENERATION ZONE, WHICH PREFERABLY ALSO SERVES AS THE SEPARATION ZONE. A PORTION F THE CATION EXCHANGE RESIN IS THEN TRANSFERRED TO THE SERVICE ZONE TO ESTABLISH A LEAKAGE BARRIER LAYER. THE REMAINDER OF THE CATION EXCHANGE RESIN IS MIXED WITH THE ANION EXCHANGE RESIN, AND THE MIXED RESINS ARE TRANSFERRED TO THE SERVICE ZONE TO ESTABLISH A SERVICE LAYER OF ANION AND CATION EXCHANGE RESINS.
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公开(公告)号:ZA8403467B
公开(公告)日:1985-01-30
申请号:ZA8403467
申请日:1984-05-08
Applicant: ECODYNE CORP
Inventor: SALEM ELI
CPC classification number: G01N27/043 , B01J47/04 , Y10T137/0324
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公开(公告)号:GB2107602A
公开(公告)日:1983-05-05
申请号:GB8230032
申请日:1982-10-21
Applicant: ECODYNE CORP
Inventor: DOWN PETER E , SALEM ELI
IPC: B01J49/00
Abstract: A method for regenerating the exhausted anion and cation exchange resins in a mixed bed demineralizer which utilizes an inert material of a specific density intermediate to the specific densities of the anion and cation resins. The inert resin remains in the regeneration system and is not returned to the service vessel with the regenerated resin.
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公开(公告)号:AU497886B2
公开(公告)日:1979-01-18
申请号:AU2170377
申请日:1977-01-27
Applicant: ECODYNE CORP
Inventor: FLYNN GEORGE C , SALEM ELI
Abstract: A process for scrubbing undissolved impurities from the upper portion of an ion exchange resin filtration bed is disclosed wherein air is introduced in the upper portion of the bed and develops a pressure within the vessel. This pressure subsequently forces rinse water down through the upper portion of the bed and out of the vessel. The gas is introduced into the bed and the water is drained therefrom at a level below the bed's upper surface but above a substantial lower portion of the resin bed. In this manner, lesser quantities of scrubbing fluids are required and the majority of the resin material is left undisturbed to maintain maximum ion exchange capacity.
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公开(公告)号:DE2708315A1
公开(公告)日:1977-09-15
申请号:DE2708315
申请日:1977-02-25
Applicant: ECODYNE CORP
Inventor: FLYNN GEORGE C , SALEM ELI
Abstract: A process for scrubbing undissolved impurities from the upper portion of an ion exchange resin filtration bed is disclosed wherein air is introduced in the upper portion of the bed and develops a pressure within the vessel. This pressure subsequently forces rinse water down through the upper portion of the bed and out of the vessel. The gas is introduced into the bed and the water is drained therefrom at a level below the bed's upper surface but above a substantial lower portion of the resin bed. In this manner, lesser quantities of scrubbing fluids are required and the majority of the resin material is left undisturbed to maintain maximum ion exchange capacity.
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公开(公告)号:AU8888382A
公开(公告)日:1983-05-05
申请号:AU8888382
申请日:1982-09-30
Applicant: ECODYNE CORP
Inventor: DOWN PETER E , SALEM ELI
IPC: B01J49/00
Abstract: A method for regenerating the exhausted anion and cation exchange resins in a mixed bed demineralizer which utilizes an inert material of a specific density intermediate to the specific densities of the anion and cation resins. The inert resin remains in the regeneration system and is not returned to the service vessel with the regenerated resin.
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公开(公告)号:MX4781E
公开(公告)日:1982-09-21
申请号:MX549477
申请日:1977-03-02
Applicant: ECODYNE CORP
Inventor: FLYNN GEORGE C , SALEM ELI
Abstract: A process for scrubbing undissolved impurities from the upper portion of an ion exchange resin filtration bed is disclosed wherein air is introduced in the upper portion of the bed and develops a pressure within the vessel. This pressure subsequently forces rinse water down through the upper portion of the bed and out of the vessel. The gas is introduced into the bed and the water is drained therefrom at a level below the bed's upper surface but above a substantial lower portion of the resin bed. In this manner, lesser quantities of scrubbing fluids are required and the majority of the resin material is left undisturbed to maintain maximum ion exchange capacity.
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公开(公告)号:AU554640B2
公开(公告)日:1986-08-28
申请号:AU8888382
申请日:1982-09-30
Applicant: ECODYNE CORP
Inventor: DOWN PETER E , SALEM ELI
IPC: B01J49/00
Abstract: A method for regenerating the exhausted anion and cation exchange resins in a mixed bed demineralizer which utilizes an inert material of a specific density intermediate to the specific densities of the anion and cation resins. The inert resin remains in the regeneration system and is not returned to the service vessel with the regenerated resin.
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