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公开(公告)号：KR1020120121141A
公开(公告)日：2012-11-05
申请号：KR1020110038935
申请日：2011-04-26
Applicant: 한국화학연구원
IPC: C07F9/6593 , C08K5/5399 , C08J5/22 , H01M10/056
CPC classification number: C08K5/5399 , C07F9/65815 , H01M10/052 , H01M10/0565
Abstract: PURPOSE: A cyclotriphosphazene-based crosslinking agent for polymer electrolyte and a solid polymer electrolyte composition containing the same are provided to reduce crystallization of ethylene oxide units and to improve ion conductivity. CONSTITUTION: A cyclotriphosphazene-based crosslinking agent is denoted by chemical formula 1. A method for preparing cyclotriphosphazene-based crosslinking agent comprises: a step of alkoxylation of R3 substituent of hexachlorocyclotriphosphazene to prepare compound 4; a step of treating the compound 4 with pyridinium p-toluene sulfonate to prepare compound 5; a step of reacting compound 5 with triethyl amine and methacryloyl chloride to prepare compound 1. A solid polymer electrolyte composition contains 0.1-95 wt% of cyclotriphosphazene-based crosslinking agent of chemical formula 1; 0.1-96.8 wt% of plasticizer of chemical formula 2; 3-40 wt% of litium salt; and 0.1-5 wt% of curing type initiator.
Abstract translation: 目的：提供用于聚合物电解质的环三磷腈系交联剂和含有它们的固体聚合物电解质组合物，以减少环氧乙烷单元的结晶并提高离子传导性。 构成：以化学式1表示环三磷腈系交联剂。制备环三磷腈系交联剂的方法包括：将六氯环三磷腈的R3取代基进行烷氧基化以制备化合物4的步骤; 用对甲苯磺酸吡啶鎓处理化合物4以制备化合物5的步骤; 将化合物5与三乙胺和甲基丙烯酰氯反应以制备化合物1的步骤。固体聚合物电解质组合物含有0.1-95重量％的化学式1的环三磷腈系交联剂; 0.1-96.8重量％的化学式2的增塑剂; 3-40重量％的盐酸盐; 和0.1-5重量％的固化型引发剂。
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82.发明公开
公开(公告)号：KR1020120057158A
公开(公告)日：2012-06-05
申请号：KR1020100118779
申请日：2010-11-26
Applicant: 에스케이이노베이션 주식회사 , 한국화학연구원
IPC: H01M10/0565 , H01M10/0525 , C08K5/1515 , C08K5/5415
CPC classification number: H01M10/0565 , C08K5/1515 , C08K5/5415 , C08K5/549 , H01B1/122 , H01M10/052 , H01M2300/0082 , Y02E60/12
Abstract: PURPOSE: A polymer electrolyte composition is provided to prevent the short circuit of a positive electrode and a negative electrode, and to improve electrochemical stability and ion conductivity at room temperature. CONSTITUTION: A polymer electrolyte composition comprises a siloxane-based epoxy compound in chemical formula 1 as a crosslinking agent. In chemical formula 1, R1-R8 is respectively and independently C1-10 alkyl, n is an integer from 1-10. The polymer electrolyte composition is manufactured by reaction of the siloxane-based epoxy compound, and a nitrogen-containing polymer which is one or more mixtures selected from poly(vinylpyridine-co-styrene), poly(vinylpyridine), poly(vinylpyrrolidinone), polyvinylimidazole, poly(vinylpyridine-acrylate), polypyrrole, polyaniline.
Abstract translation: 目的：提供一种高分子电解质组合物，以防止正极和负极短路，提高室温下的电化学稳定性和离子传导性。 构成：聚合物电解质组合物包含化学式1中的硅氧烷基环氧化合物作为交联剂。 在化学式1中，R 1 -R 8分别为C 1-10烷基，n为1-10的整数。 聚合物电解质组合物是通过硅氧烷类环氧化合物和作为选自聚（乙烯基吡啶 - 共 - 苯乙烯），聚（乙烯基吡啶），聚（乙烯基吡咯烷酮），聚乙烯咪唑的一种或多种混合物的含氮聚合物 ，聚（乙烯基吡啶 - 丙烯酸酯），聚吡咯，聚苯胺。
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公开(公告)号：KR1020120030760A
公开(公告)日：2012-03-29
申请号：KR1020100092482
申请日：2010-09-20
Applicant: 한국화학연구원
Abstract: PURPOSE: An organic semiconductor composition suitable for a soluble process and an organic thin film transistor manufactured thereby are provided to easily control solution viscosity by controlling the content of a binder. CONSTITUTION: A composition includes thiol and olefin. An organic insulating film(3) is manufactured by using photo hardening from the composition. An organic thin film transistor is manufactured by using an organic semiconductor composition as a channel material. The organic semiconductor composition includes the organic semiconductor compound having more than one kind, a binder, and a solvent. The composition for a gate insulating layer is spin-coated on a gate electrode(2) and patterned using a mask. The organic semiconductor composition is printed in an ink jet, a screen or a roll-to-roll method.
Abstract translation: 目的：提供一种适用于可溶性工艺的有机半导体组合物及其制造的有机薄膜晶体管，以通过控制粘合剂的含量来容易地控制溶液的粘度。 构成：组合物包括硫醇和烯烃。 通过使用组合物的光硬化制造有机绝缘膜（3）。 通过使用有机半导体组合物作为沟道材料制造有机薄膜晶体管。 有机半导体组合物包括具有多于一种的有机半导体化合物，粘合剂和溶剂。 将栅极绝缘层的组合物旋涂在栅电极（2）上并使用掩模进行图案化。 有机半导体组合物以喷墨，丝网或卷对卷方式印刷。
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公开(公告)号：KR101005811B1
公开(公告)日：2011-01-05
申请号：KR1020080098904
申请日：2008-10-09
Applicant: 한국화학연구원
Abstract: 본 발명은 하기 화학식 1로 표시되는 포스페이트를 갖는 과불소화 다가 아크릴계 화합물 및 이의 제조방법과 이를 함유하는 광중합 조성물에 관한 것이다.
[화학식 1]
[상기 화학식 1에서, R
1 및 R
f 는 명세서에 정의된 바와 같다.]
본 발명에 따른 과불소화 다가 아크릴 화합물 및 광중합 조성물은 자외선 등의 광을 조사함에 의하여 신속히 경화되어 광통신 파장 대에서의 광투명성이 우수하고 복굴절율이 낮으며 열안정성이 우수한 고분자 광경화 필름을 용이하게 제조할 수 있어 광 스위치, 가변 광감쇠기, 광 도파로 등 다양한 광소자의 코어 혹은 클래딩 재료로 사용이 가능한 물질이다.
포스페이트, 과불소화 다가 아크릴, 광투명성, 광중합, 복굴절률, 고분자 필름-
85.发明授权
公开(公告)号：KR100942426B1
公开(公告)日：2010-02-17
申请号：KR1020070102895
申请日：2007-10-12
Applicant: 한국화학연구원
CPC classification number: Y02E60/523 , Y02P70/56
Abstract: 본 발명은 수소이온 전도성 나노복합전해질막, 이의 제조방법 및 이를 이용한 막-전극 접합체에 관한 것으로서, 더욱 상세하게는 수소이온 전도성 무기물을 종래의 전해질 막에 포함시켜 고온에서도 수소이온 전도도의 감소 없이 연료의 크로스오버를 방지할 뿐만 아니라 전해질 막의 치수안정성 열 안정성까지 증가시킴으로써 고온에서도 우수한 성능을 갖고, 환경친화적인 연료전지를 제조할 수 있도록 하였다.
수소이온전도성 무기물, 나노 복합전해질막, 막-전극 어셈블리, 디메틸 에테르 직접연료전지-
Patent Agency Ranking
公开(公告)号：KR100895793B1
公开(公告)日：2009-05-08
申请号：KR1020070072069
申请日：2007-07-19
Applicant: 한국화학연구원
IPC: C07C271/60 , C07C251/66
CPC classification number: G03F7/031
Abstract: An oxime carbamate compound is provided to be usable for a photopolymerization initiator in the ultraviolet irradiation and to control the absorption spectrum of the photopolymerization initiator by introducing an aryl or heteroaryl substituent. An oxime carbamate compound is indicated as the chemical formula 1. In the chemical formula 1, R1 is (C6-C30) aryl or (C6-C30) heteroaryl; R11, R12, R13, R14 and R15 are independently hydrogen, linear or branched, saturated or unsaturated (C1-C12) alkyl, (C3-C8) cycloalkyl, (C1-C12) alkylcarbonyl, and (C6-C30) aryl or tri (C1-C12) alkylsiloxy; m is an integer of 0 or 1; and n is an integer of 1-20.
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87.发明公开
公开(公告)号：KR1020090037544A
公开(公告)日：2009-04-16
申请号：KR1020070102895
申请日：2007-10-12
Applicant: 한국화학연구원
CPC classification number: Y02E60/523 , Y02P70/56
Abstract: A nanocomposite electrolyte membrane is provided to reduce the crossover of fuel causing the degradation of performance of a fuel battery and to increase hydrogen ion conductivity. A nanocomposite electrolyte membrane comprises a hydrogen ionic conductive inorganic material. The hydrogen ionic conductive inorganic material is any one selected from the group consisting of a cage type, ladder type, randaom type, and partial case type polysilsequioxanes.
Abstract translation: 提供纳米复合电解质膜以减少燃料的交叉，导致燃料电池的性能下降并提高氢离子传导性。 纳米复合电解质膜包括氢离子导电无机材料。 氢离子导电无机材料是选自笼型，梯型，兰德型和部分壳型聚硅氧烷的任意一种。
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公开(公告)号：KR1020090008811A
公开(公告)日：2009-01-22
申请号：KR1020070072069
申请日：2007-07-19
Applicant: 한국화학연구원
IPC: C07C271/60 , C07C251/66
CPC classification number: G03F7/031
Abstract: An oxime carbamate compound is provided to be usable for a photopolymerization initiator in the ultraviolet irradiation and to control the absorption spectrum of the photopolymerization initiator by introducing an aryl or heteroaryl substituent. An oxime carbamate compound is indicated as the chemical formula 1. In the chemical formula 1, R1 is (C6-C30) aryl or (C6-C30) heteroaryl; R11, R12, R13, R14 and R15 are independently hydrogen, linear or branched, saturated or unsaturated (C1-C12) alkyl, (C3-C8) cycloalkyl, (C1-C12) alkylcarbonyl, and (C6-C30) aryl or tri (C1-C12) alkylsiloxy; m is an integer of 0 or 1; and n is an integer of 1-20.
Abstract translation: 提供肟氨基甲酸酯化合物可用于紫外线照射中的光聚合引发剂，并通过引入芳基或杂芳基取代基来控制光聚合引发剂的吸收光谱。 肟基氨基甲酸酯化合物表示为化学式1.在化学式1中，R 1为（C 6 -C 30）芳基或（C 6 -C 30）杂芳基; R11，R12，R13，R14和R15独立地为氢，直链或支链，饱和或不饱和的（C1-C12）烷基，（C3-C8）环烷基，（C1-C12）烷基羰基和（C6-C30）芳基或三 （C1-C12）烷基甲硅烷氧基; m为0或1的整数; n为1-20的整数。
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公开(公告)号：KR100873986B1
公开(公告)日：2008-12-17
申请号：KR1020070055442
申请日：2007-06-07
Applicant: 한국화학연구원
Abstract: An unsaturated carboxylate compound containing phosphorus, and a polymerizable composition containing the compound are provided to improve heat resistance, transparency and refractive index. An unsaturated carboxylate compound containing phosphorus is represented by the formula 1, wherein R11 is a divalent organic group; X11, X12 and X13 are independently O, S, -C(=O)O- or -(CH2)nX14-; X14 are independently O or S; m is an integer of 1-3; R12 are independently a substituent containing a phosphorus atom; R13 are independently an alpha,beta-unsaturated carboxylate residue; and R14 are independently H or a methyl group.
Abstract translation: 提供含磷的不饱和羧酸酯化合物和含有该化合物的可聚合组合物以提高耐热性，透明度和折射率。 含磷的不饱和羧酸酯化合物由式1表示，其中R 11是二价有机基团; X11，X12和X13独立地为O，S，-C（= O）O-或 - （CH2）nX14-; X14独立地是O或S; m是1-3的整数; R12独立地为含有磷原子的取代基; R13独立地为α，β-不饱和羧酸酯残基; 和R 14独立地为H或甲基。
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公开(公告)号：KR1020080107550A
公开(公告)日：2008-12-11
申请号：KR1020070055442
申请日：2007-06-07
Applicant: 한국화학연구원
CPC classification number: C07F9/53 , C08K5/5397
Abstract: An unsaturated carboxylate compound containing phosphorus, and a polymerizable composition containing the compound are provided to improve heat resistance, transparency and refractive index. An unsaturated carboxylate compound containing phosphorus is represented by the formula 1, wherein R11 is a divalent organic group; X11, X12 and X13 are independently O, S, -C(=O)O- or -(CH2)nX14-; X14 are independently O or S; m is an integer of 1-3; R12 are independently a substituent containing a phosphorus atom; R13 are independently an alpha,beta-unsaturated carboxylate residue; and R14 are independently H or a methyl group.
Abstract translation: 提供含磷的不饱和羧酸酯化合物和含有该化合物的可聚合组合物以改善耐热性，透明度和折射率。 含磷的不饱和羧酸酯化合物由式1表示，其中R 11是二价有机基团; X 11，X 12和X 13独立地为O，S，-C（= O）O-或 - （CH 2）n X 14 - ; X 14独立地为O或S; m为1-3的整数; R 12独立地为含有磷原子的取代基; R 13独立地为α，β-不饱和羧酸酯残基; R 14独立地为H或甲基。
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