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公开(公告)号：KR101494229B1
公开(公告)日：2015-02-17
申请号：KR1020130049071
申请日：2013-05-01
Applicant: 한국화학연구원
CPC classification number: B01J8/388 , B01J29/40 , B01J29/85 , B01J29/90 , B01J37/0045 , B01J38/14 , B01J38/30 , B01J2208/00548 , B01J2208/00628 , C07C1/20 , Y02P20/52 , Y02P20/584 , Y02P30/42 , C07C11/04 , C07C11/06
Abstract: 본 발명은 중간생성물의 선택도 모니터링을 통한 메탄올로부터 경질올레핀을 제조하는 순환유동층 공정의 효율적 운전에 관한 것으로, 구체적으로 디메틸에테르(DME) 선택도를 모니터링하여 사용된 촉매의 비활성화 정도를 예측하고 촉매 재생을 위한 공기 유량을 조절하여 최적화된 코크 정도를 유지시킴으로써 경질올레핀계 탄화수소의 생산성을 효과적으로 증진할 수 있고, 특히 에틸렌 및 프로필렌에 대한 우수한 선택성을 유지할 수 있는 방법에 관한 것이다.
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公开(公告)号：KR101468374B1
公开(公告)日：2014-12-02
申请号：KR1020120136279
申请日：2012-11-28
Applicant: 한국화학연구원
Abstract: 본발명은아연및 란탄이함침된나노크기결정인제올라이트촉매및 이의제조방법에관한것으로, 상세하게는 10 내지 100 nm 크기인 1차입자, 및 1 내지 10 μm 크기인 2차입자로이루어지되, 상기 2차입자는복수개의상기 1차입자들을포함하여이루어지며, 실리카와알루미나몰비(SiO/AlO)가 50 내지 80인제올라이트; 및상기제올라이트에함침된아연및 란탄을포함하는제올라이트촉매를제공한다. 본발명에따른제올라이트촉매는방향족화합물, 특히 BTX의선택성을높이기위해촉매의활성물질로아연및 란탄이공침된것으로서, 나노크기의결정입자, 아연및 란탄의공침및 적절한산점으로인하여고정층촉매반응기를이용하여에탄올로부터방향족화합물을제조시방향족화합물및 BTX의선택도를크게증가시킬수 있는효과가있다.
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公开(公告)号：KR1020140075214A
公开(公告)日：2014-06-19
申请号：KR1020120143346
申请日：2012-12-11
Applicant: 한국화학연구원
CPC classification number: B01J23/42 , B01J21/18 , B01J35/1061 , B01J37/0201 , B82Y40/00 , C01B3/26
Abstract: The present invention relates to a catalyst for an aqueous phase reforming reaction having a nano-sized mesoporous carbon carrier, a method for producing the same, and a method for producing hydrogen from oxygen-containing hydrocarbon through the aqueous phase reforming reaction using the same. When the catalyst of the present invention is used for the aqueous phase reforming reaction for producing hydrogen from oxygen-containing hydrocarbon, the catalyst has a larger surface area than an existing micro-sized mesoporous carbon carrier so that the degree of dispersion of active metals is increased and the structure of mesopores is developed. Accordingly, the speed of transferring and diffusing material becomes rapid so that the transfer rate, production rate, and production speed of hydrogen gas can be improved.
Abstract translation: 本发明涉及一种具有纳米尺寸介孔碳载体的水相重整反应催化剂，其制备方法，以及通过使用该催化剂的水相重整反应从含氧烃生产氢的方法。 当本发明的催化剂用于从含氧烃生产氢的水相重整反应时，催化剂的表面积比现有的微孔中孔碳载体大，因此活性金属的分散度为 增加了介孔的结构， 因此，转移和扩散材料的速度变快，从而可以提高氢气的转印速度，生产速度和生产速度。
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84.发明公开에탄올로부터 1,3-부타디엔 제조를 위한, 탄탈라계 복합금속산화물이 담지된 성형실리카계 촉매 및 이를 이용한 1,3-부타디엔의 제조방법 有权用于从乙醇生产1,3-丁二烯的二氧化硅催化剂上支持的基于TANTALA的复合金属氧化物及其使用的1,3-丁二烯的生产方法
公开(公告)号：KR1020140047329A
公开(公告)日：2014-04-22
申请号：KR1020120113453
申请日：2012-10-12
Applicant: 한국화학연구원
CPC classification number: B01J23/20 , B01J21/08 , B01J37/0201 , C07C1/20 , C07C11/167
Abstract: The present invention relates to a catalyst for manufacturing 1,3- butadiene supported with a first metal oxide and a second metal oxide in silica, wherein the first metal oxide is a tantalum oxide and the second metal oxide is at least one selected from a group consisting of cerium oxide, nickel oxide, zirconium oxide and manganese oxide; and a manufacturing method for 1,3- butadiene using the same. Specifically, the catalyst of the present invention is practically applicable to a fixed bed reactor by selecting a silica mold carrier having an appropriate size and strength; impregnates tantalum oxide as the first metal oxide and cerium oxide, nickel oxide, zirconium oxide and manganese oxide as the second metal oxide; inhibits an occurrence of deactivation by minimizing the selectivity degradation of 1,3-butadiene as reaction time passes, which significantly improves the life expectancy of the catalyst as compared to an existing silica-based catalyst, thereby capable of being effectively used for the manufacture of 1,3-butadiene. [Reference numerals] (AA) Total transformation rate (%); (BB) Total transformation rate; (CC) Butadiene selectivity; (DD) Reaction time (hour); (EE) Butadiene selectivity (%)
Abstract translation: 本发明涉及用二氧化硅中的第一金属氧化物和第二金属氧化物负载的1,3-丁二烯的催化剂，其中第一金属氧化物是氧化钽，第二金属氧化物是从基团 由氧化铈，氧化镍，氧化锆和氧化锰组成; 以及使用该丁二烯的1,3-丁二烯的制造方法。 具体地，本发明的催化剂通过选择具有适当尺寸和强度的二氧化硅模具载体，实际上适用于固定床反应器; 浸渍作为第一金属氧化物的氧化钽和作为第二金属氧化物的氧化铈，氧化镍，氧化锆和氧化锰; 通过使作为反应时间的1,3-丁二烯的选择性降解最小化来抑制失活的发生，与现有的二氧化硅基催化剂相比，催化剂的预期寿命显着提高，从而能够有效地用于制造 1,3-丁二烯。 （标号）（AA）总转化率（％） （BB）总转化率; （CC）丁二烯选择性; （DD）反应时间（小时）; （EE）丁二烯选择性（％）
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公开(公告)号：KR1020130092711A
公开(公告)日：2013-08-21
申请号：KR1020120014152
申请日：2012-02-13
Applicant: 동양하이테크산업주식회사 , 한국화학연구원
CPC classification number: Y02P20/52 , B01J29/0325 , B01J21/18 , B01J37/0201 , C01B3/326
Abstract: PURPOSE: A catalyst for aqueous phase reforming reaction with a stable structure compared to that of a conventional catalyst and a manufacturing method thereof are provided to significantly increase a conversion ratio and a production rate of hydrogen and to provide hydrogen economically and environment-friendlily. CONSTITUTION: A catalyst for aqueous phase reforming reaction comprises a metal component carried in a mesoporous carbon carrier. The metal component is one selected from the group consisting of metals of VIIB group and VIII group. The mesoporous carbon carrier is manufactured by using a 3-dimensional mesoporous silica molecular sieve of one selected from the group consisting of SBA-1, SBA-6, SBA-16, FDU-5, KIT-6, and MCM-48.
Abstract translation: 目的：提供一种与常规催化剂相比具有稳定结构的水相重整反应催化剂及其制备方法，以显着提高氢气的转化率和生产率，从而在经济和环保方面提供氢气。 构成：用于水相重整反应的催化剂包括载于介孔碳载体中的金属组分。 金属成分选自VIIB族和VIII族金属。 通过使用选自SBA-1，SBA-6，SBA-16，FDU-5，KIT-6和MCM-48的一种3维介孔二氧化硅分子筛制造介孔碳载体。
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Patent Agency Ranking86.发明公开
公开(公告)号：KR1020120133751A
公开(公告)日：2012-12-11
申请号：KR1020110052570
申请日：2011-06-01
Applicant: 동양하이테크산업주식회사 , 한국화학연구원
CPC classification number: Y02P20/52 , C01B32/05 , B01J23/42 , B01J23/8986 , C01B3/40
Abstract: PURPOSE: A carbon supported metal catalyst with a three dimensional bimodal mesoporous structure and an aqueous phase reforming method of oxygenated compounds using the same are provided to directly form carbon with a bimodal porous structure without a separate template material. CONSTITUTION: An aqueous phase reforming method of oxygenated compounds using a carbon supported metal catalyst with a three dimensional bimodal mesoporous structure includes the following steps: a carbon precursor is impregnated into silica; the impregnated product is dried and carbonated to prepare a silica/carbon complex; and the silica is removed from the silica/carbon complex. The silica is one or more selected from silica gel with mesopores, silica nanoparticles, silica beads, aluminum anodic oxide, and alumino silicagel. [Reference numerals] (AA) Adsorption; (BB) Desorption; (CC) Adsorption amount; (DD) Relative pressure
Abstract translation: 目的：提供具有三维双峰介孔结构的碳负载金属催化剂和使用其的含氧化合物的水相重整方法，以直接形成具有双峰多孔结构的碳，而没有单独的模板材料。 构成：使用具有三维双峰介孔结构的碳负载金属催化剂的含氧化合物的水相重整方法包括以下步骤：将碳前体浸渍到二氧化硅中; 将浸渍的产物干燥并碳酸化以制备二氧化硅/碳络合物; 并且二氧化硅从二氧化硅/碳络合物中除去。 二氧化硅是选自具有介孔的硅胶，二氧化硅纳米颗粒，二氧化硅珠，铝阳极氧化物和铝硅胶中的一种或多种。 （附图标记）（AA）吸附; （BB）解吸; （CC）吸附量; （DD）相对压力
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公开(公告)号：KR1020120074766A
公开(公告)日：2012-07-06
申请号：KR1020100136704
申请日：2010-12-28
Applicant: 한국화학연구원 , 현대엔지니어링 주식회사
Abstract: PURPOSE: A titanium-SAPO-34 crystalline catalyst, a method for preparing the same, and a method for manufacturing light olefin using the same are provided to improve the productivity of the light olefin by improving the crystallinity and the hydrothermal stability of the catalyst. CONSTITUTION: A tetraethyl aluminohydroxide(TEAlOH) solution containing an organic templating agent and an alumina precursor is prepared. Phosphoric acid and water are mixed with the TEAlOH solution to obtain synthetic gel. A silica precursor and a titanium precursor are added in the synthetic gel, and a mixing operation is implemented. The mixed synthetic gel is aged and hydrothermal synthesized to obtain Ti-SAPO-34 gel. Non-reacted precursors are eliminated, and a drying operation is implemented. The Ti-SAPO-34 is plasticized.
Abstract translation: 目的：提供钛 - SAPO-34结晶催化剂，其制备方法和使用其制备轻质烯烃的方法，以通过提高催化剂的结晶度和水热稳定性来提高轻质烯烃的生产率。 构成：制备含有有机模板剂和氧化铝前体的四乙基氢氧化铝（TEAlOH）溶液。 将磷酸和水与TEAlOH溶液混合以获得合成凝胶。 在合成凝胶中加入二氧化硅前体和钛前体，进行混合操作。 混合合成凝胶进行老化和水热合成，得到Ti-SAPO-34凝胶。 消除未反应的前体，并进行干燥操作。 Ti-SAPO-34被塑化。
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公开(公告)号：KR1020120022261A
公开(公告)日：2012-03-12
申请号：KR1020100085670
申请日：2010-09-01
IPC: C07C305/10 , C10L3/06 , C07C7/20 , C07C5/00
Abstract: PURPOSE: A disulfate-based promoter for natural gas hydrate(NGH) is provided to increase dewatering efficiency, storage ability, and production rate of natural gas hydrate. CONSTITUTION: A disulfate-based promoter for natural gas hydrate(NGH) is anionic multi-chain type disulfate based surfactant and marked as chemical formula 1. In the chemical formula 1, R1 and R2 can be same or different, and are selected from an alkyl group which is saturated or unsaturated and C1-30 straight-chain or branched-chain. M is selected from alkali metal in the chemical formula 1. The alkyl group can be substituted for fluorine atom or aromatic ring. The promoter additionally includes another promoter which is selected from anionic, cationic, and non-ionic surfactant having an ability of promoting hydrate generation.
Abstract translation: 目的：提供天然气水合物（NGH）的二硫酸盐促进剂，以提高天然气水合物的脱水效率，储存能力和生产率。 构成：天然气水合物（NGH）的二硫酸盐基促进剂是阴离子多链型二硫酸盐基表面活性剂，并标记为化学式1.在化学式1中，R 1和R 2可以相同或不同，并且选自 饱和或不饱和的直链或支链的直链或支链的直链或支链烷基。 M选自化学式1中的碱金属。烷基可以被氟原子或芳环取代。 启动子另外包括另外一种启动子，其选自具有促进水合物产生能力的阴离子，阳离子和非离子表面活性剂。
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公开(公告)号：KR1020110138026A
公开(公告)日：2011-12-26
申请号：KR1020100058102
申请日：2010-06-18
Applicant: 한국화학연구원 , 에스케이이노베이션 주식회사
CPC classification number: B01J31/069 , B01J21/08 , B01J37/02
Abstract: PURPOSE: A polymer-silica composite catalyst for selective oxidative desulfurization and a method for manufacturing the same are provided to reduce the precipitation of byproducts generated from the selective oxidative desulfurization. CONSTITUTION: A transition metal is carried in a silica carrier. The surface of the silica carrier carrying the transition metal is silylated based on vinyl organic silane. The copolymer of a styrene-based monomer and a cross-linking agent is surface-polymerized with the surface of the catalyst. The silica is silica bead, silica molecule, silica nano-particle, silica crystal, silica gel, or mesoporous silica of 2-50nm pore size and 150-1000m^2/g specific surface area. The transition metal is one selected from titanium, vanadium, molybdenum, and tungsten.
Abstract translation: 目的：提供一种用于选择性氧化脱硫的聚合物 - 二氧化硅复合催化剂及其制造方法，以减少由选择性氧化脱硫产生的副产物的析出。 构成：二氧化硅载体中载有过渡金属。 承载过渡金属的二氧化硅载体的表面基于乙烯基有机硅烷甲硅烷基化。 苯乙烯类单体与交联剂的共聚物与催化剂的表面进行表面聚合。 二氧化硅是二氧化硅珠，二氧化硅分子，二氧化硅纳米颗粒，二氧化硅结晶，硅胶或孔径为2-50nm，介孔比例为150-1000m ^ 2 / g的介孔二氧化硅。 过渡金属是选自钛，钒，钼和钨的一种。
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90.发明授权
公开(公告)号：KR101087165B1
公开(公告)日：2011-11-25
申请号：KR1020090066010
申请日：2009-07-20
IPC: B01J23/745 , B01J37/03 , C10G11/02 , C10G2/00
Abstract: 본 발명은 피셔-트롭쉬 합성반응에 사용되는 철계 촉매의 제조방법 및 이를 이용한 액체탄화수소의 제조방법에 관한 것으로, 더욱 상세하게는 질산철구수화물(Fe(NO
3 )·9H
2 O), 질산구리(Cu(NO
3 )
2· 3H
2 O) 및 질산알루미늄(Al(NO
3 )·9H
2 O)의 수용액과 수산화암모늄(NH
4 OH) 수용액의 혼합용액에 증류수를 교반하면서 적하시킨 후 공침시키는 단계(단계 1); 상기 단계 1에서 제조된 반응용액을 건조시켜 분말을 얻는 단계(단계 2); 상기 단계 2에서 얻은 분말을 증류수 슬러리 상에서 분산시킨 후 탄산칼륨(K
2 CO
3 )를 함침시키는 단계(단계 3); 및 상기 단계 3에서 제조된 혼합물을 건조시킨 후 400 - 750 ℃에서 7 - 12 시간 동안 소성시키는 단계(단계 4)를 포함하는 액체탄화수소를 제조하기 위한 피셔-트롭쉬 합성반응에 사용되는 철계 촉매의 제조방법 및 상기 철계 촉매를 이용한 액체탄화수소의 제조방법을 제공한다.
피셔-트롭쉬 합성반응, 철계 촉매, 공침, 소성, 액체탄화수소
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