公开(公告)号：DE102004042949A1

公开(公告)日：2006-03-09

申请号：DE102004042949

申请日：2004-09-02

Applicant: BASF AG

Inventor： SCHEIDEL JENS ,  JUNGKAMP TIM ,  BAUMANN ROBERT ,  LUYKEN HERMANN ,  BARTSCH MICHAEL ,  HADERLEIN GERD ,  PFAB PETER ,  SIEGEL WOLFGANG ,  BASLER PETER

IPC: C07C253/08 ,  C07C253/30 ,  C07C253/34 ,  C07C255/07

Abstract: Producing 3-pentenonitrile comprises isomerizing a 2-methyl-3-butenonitrile feed stream in the presence of a dissolved or dispersed catalyst, distilling the product stream to separate an overhead stream (2) from a catalyst-containing bottoms stream, distilling stream (2) to obtain an overhead stream enriched in (Z)-2-methyl-2-butenonitrile and a bottoms stream (5), and distilling stream (5) to produce a bottoms stream containing 3-pentenonitrile and an overhead stream containing 2-methyl-3-butenonitrile.

公开(公告)号：DE102004004671A1

公开(公告)日：2005-08-18

申请号：DE102004004671

申请日：2004-01-29

Applicant: BASF AG

Inventor： JUNGKAMP TIM ,  BAUMANN ROBERT ,  BARTSCH MICHAEL ,  HADERLEIN GERD ,  LUYKEN HERMANN ,  SCHEIDEL JENS

IPC: C07C253/10 ,  C07C255/07 ,  C07C253/30 ,  C07C253/34

Abstract: Producing 3-pentenonitrile comprises isomerizing a 2-methyl-3-butenonitrile feed stream in the presence of a dissolved or dispersed catalyst, distilling the product stream to separate an overhead stream (2) from a catalyst-containing bottoms stream, distilling stream (2) to obtain an overhead stream enriched in (Z)-2-methyl-2-butenonitrile and a bottoms stream (5), and distilling stream (5) to produce a bottoms stream containing 3-pentenonitrile and an overhead stream containing 2-methyl-3-butenonitrile.

公开(公告)号：CA2560096A1

公开(公告)日：2005-08-11

申请号：CA2560096

申请日：2005-01-26

Applicant: BASF AG

Inventor： BAUMANN ROBERT ,  LUYKEN HERMANN ,  HADERLEIN GERD ,  KUNSMANN-KEITEL DAGMAR PASCALE ,  BARTSCH MICHAEL ,  JUNGKAMP TIM ,  SCHEIDEL JENS

IPC: C07C253/10 ,  C07C255/07

Abstract: A process is described for preparing 3-pentenenitrile by hydrocyanating 1,3-butadiene with hydrogen cyanide over at least one catalyst, wherein the 1,3-butadiene and/or hydrogen cyanide is contacted with at least one microporous solid before the reaction.

公开(公告)号：CA2553028A1

公开(公告)日：2005-08-11

申请号：CA2553028

申请日：2005-01-27

Applicant: BASF AG

Inventor： JUNGKAMP TIM ,  BAUMANN ROBERT ,  BARTSCH MICHAEL ,  LUYKEN HERMANN ,  HADERLEIN GERD ,  SCHEIDEL JENS

IPC: C07C253/10 ,  C07C255/04

Abstract: The invention relates to a method for producing adipodinitrile and methylglutar nitrile, said method being characterised by the following steps : (a) an educt flow containing pentenenitriles is reacted with hydrogen cyanid e in the presence of at least one catalyst and at least one promoter to obtain a reaction flow containing pentenenitriles, the at least one catalyst, catalys t breakdown products, the at least one promoter, adipodinitrile and methylglut ar nitrile; (b) the reaction flow is distilled to obtain a bottom product flow (3) that is depleted of pentenenitriles and contains the at least one catalyst, catalyst breakdown products, the at least one promoter, adipodinitrile and methylglutar nitrile, and a top product flow (4) enriched in pentenenitriles; (c) the flow (3) is extracted by an extraction means contained in flow (5) to obtain a top product flow (6) that is enriched with extraction means and contains the catalyst, and a bottom product flow (7) th at is depleted of extraction means and contains catalyst breakdown products, th e at least one promoter, pentenenitriles, adipodinitrile and methylglutar nitrile; (d) the flow (6) is distilled to obtain a bottom product flow (8) containing the catalyst, and a top product flow (9) containing the extractio n means; (e) the flow (7) is distilled to obtain a bottom product flow (10) containing catalyst breakdown products, the at least one promoter, pentene nitriles, adipodinitrile and methylglutarnitrile, and a top product flow (11 ) containing the extraction means; (f) the flow (10) is distilled to obtain a bottom product flow (12) containing catalyst breakdown products, the at leas t one promoter, pentenenitriles, adipodinitrile and methylglutarnitrile, and a top product flow (13) containing pentenenitriles; (g) the flow (12) is distilled to obtain a bottom product flow (14) containing catalyst breakdown products and the at least one promoter, and a top product flow (15) containi ng adipodinitrile and methylglutar nitrile; and (h) the flow (15) is distilled to obtain a bottom product flow (16) containing adipodinitrile, and a top produ ct flow (17) containing methylglutarnitrile.

公开(公告)号：DE10350999A1

公开(公告)日：2005-06-02

申请号：DE10350999

申请日：2003-10-30

Applicant: BASF AG

Inventor： BARTSCH MICHAEL ,  BAUMANN ROBERT ,  HADERLEIN GERD ,  FLORES MIGUEL ,  JUNGKAMP TIM ,  LUYKEN HERMANN ,  SCHEIDEL JENS ,  SIEGEL WOLFGANG

IPC: B01J31/18 ,  B01J31/24 ,  C07C253/10 ,  C07C253/30 ,  C07C255/07 ,  C07C255/09 ,  C07F9/12 ,  C07F9/48 ,  C07F9/50 ,  C07F9/6574 ,  C07F9/46 ,  C07F15/04 ,  C07C253/08 ,  C07C255/06 ,  C07C255/04

Abstract: The invention relates to phosphinite phosphites I of formula 1, 2, 3, 4, 5 or 6 and mixtures thereof, wherein R1, R2, R4 independently represent an alkyl or alkylene group with 1 to 8 carbon atoms, provided that at least one of the groups R1, R2, R4 is different from H; R5 to R22 independently represent H, an alkyl or alkylene group with 1 to 8 carbon atoms; R3 is H, methyl or ethyl; X is F, Cl or CF3, if n=1 or 2 and X is H, if n=0.

公开(公告)号：DE10351002A1

公开(公告)日：2005-05-25

申请号：DE10351002

申请日：2003-10-30

Applicant: BASF AG

Inventor： HADERLEIN GERD ,  BAUMANN ROBERT ,  BARTSCH MICHAEL ,  JUNGKAMP TIM ,  LUYKEN HERMANN ,  SCHEIDEL JENS ,  SCHAEFER HEINZ ,  SIEGEL WOLFGANG

IPC: B01J31/18 ,  C01G53/08 ,  C07F15/04 ,  B01J31/24 ,  C07B43/08 ,  C07B37/08 ,  C07C253/10 ,  C07C253/30 ,  C07C5/22

Abstract: A process is described for preparing a nickel(0)-phosphorus ligand complex containing at least one nickel(0)central atom and at least one phosphorus ligand, which comprises reducing a nickel(II) halide dried by azeotropic distillation in the presence of at least one phosphorus ligand.

公开(公告)号：CA2544051A1

公开(公告)日：2005-05-12

申请号：CA2544051

申请日：2004-10-28

Applicant: BASF AG

Inventor： HADERLEIN GERD ,  BAUMANN ROBERT ,  BARTSCH MICHAEL ,  LUYKEN HERMANN ,  SIEGEL WOLFGANG ,  SCHAEFER HEINZ ,  SCHEIDEL JENS ,  JUNGKAMP TIM

IPC: C07F15/04 ,  B01J31/16 ,  B01J31/18 ,  C01G53/00 ,  C01G53/08

Abstract: A process is described for preparing a nickel(0)-phosphorus ligand complex containing at least one nickel(0)central atom and at least one phosphorus ligand, which comprises reducing a nickel(II) halide dried by azeotropic distillation in the presence of at least one phosphorus ligand.

公开(公告)号：DE10323803A1

公开(公告)日：2004-11-11

申请号：DE10323803

申请日：2003-04-22

Applicant: BASF AG

Inventor： BARTSCH MICHAEL ,  BAUMANN ROBERT ,  HADERLEIN GERD ,  FLORES MIGUEL ,  JUNGKAMP TIM ,  LUYKEN HERMANN ,  SCHEIDEL JENS ,  SIEGEL WOLFGANG ,  KUNSMANN-KEITEL DAGMAR PASCALE

IPC: C07C253/30 ,  C07C255/07

Abstract: A process for isomerizing cis-2-pentenenitrile to trans-3-pentenenitrile in the presence of aluminum oxide as a catalyst, wherein the aluminum oxide has a BET surface area of at least 50 m 2 /g.

公开(公告)号：CA2520571A1

公开(公告)日：2004-10-14

申请号：CA2520571

申请日：2004-03-24

Applicant: BASF AG

Inventor： JUNGKAMP TIM ,  FLORES MIGUEL ANGEL ,  LUYKEN HERMANN ,  SCHEIDEL JENS ,  MOLNAR FERENC ,  BAUMANN ROBERT ,  HADERLEIN GERD ,  BARTSCH MICHAEL ,  SIEGEL WOLFGANG

IPC: B01J23/755 ,  B01J31/02 ,  B01J31/14 ,  B01J31/18 ,  C07C253/10 ,  C07C255/04 ,  B01J27/14 ,  B01J27/18

Abstract: A system suitable for use as a catalyst for the hydrocyanation of olefinical ly unsaturated compounds, containing a) Ni(0), b) Ni(0) as a ligand complex- fixing compound containing trivalent phosphorus, c) a Lewis acid and d) a compound of formula MRn wherein M = AI or Ti, R= identical or different monovalent alkoxyl radicals, wherein several alkoxy radicals can be interbridged, also in the case where M = AI, R = identical or different alky l radicals wherein several alkyl radicals can be interbridged or one or severa l alkyl radicals can be bridged by one or several of the above-mentioned alkox y radicals, n = valency of M. The invention also relates to methods for the hydrocyanation of an olefinically unsaturationed compound in the presence of said system.

公开(公告)号：BR0212965A

公开(公告)日：2004-10-13

申请号：BR0212965

申请日：2002-10-04

Applicant: BASF AG

Inventor： BARTSCH MICHAEL ,  BAUMANN ROBERT ,  KUNSMANN-KEITEL DAGMAR PASCALE ,  HADERLEIN GERD ,  JUNGKAMP TIM ,  ALMAYER MARCO ,  SIEGEL WOLFGANG ,  MOLNAR FERENC

IPC: B01J31/22 ,  B01J31/18 ,  C07B61/00 ,  C07C253/10 ,  C07C253/30 ,  C07C255/04 ,  C07C255/07 ,  C07F9/48

Abstract: The invention relates to phosphinites I of formulae (1) or (2), in which R1, R2, R5, R6, R7, R8, R9 independently represent hydrogen, an alkyl or alkylene group having 1 to 8 carbon atoms or an alkoxy group having 1 to 8 carbon atoms; R3 is H or methyl; R4 is i-propyl or t-butyl; X is F, Cl or CF 3 and n is 1 or 2.