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    Dyeing, fluorescent brightening and/or printing textile materials
    83.
    发明专利
    Dyeing, fluorescent brightening and/or printing textile materials 未知

    公开(公告)号：GB929053A

    公开(公告)日：1963-06-19

    申请号：GB403162

    申请日：1962-02-02

    Applicant: BASF AG

    Inventor： LUETZEL GERHARD ,  ROHLAND WERNER ,  LUDSTECK DIETER

    IPC: D06L3/12

    Abstract: Processes for dyeing and printing textile materials comprise treating the material, if necessary at elevated temperature, in the presence of a strongly alkaline reacting agent with a dye or fluorescent brightening agent which has one or more reactive hydrogen atoms preferably attached by way of nitrogen, oxygen or sulphur or which is capable of forming such atoms during the process and with an uncoloured non-fluorescent polyfunctional compound which has at least three ethylenimine groups preferably attached by way of carbon or phosphorus, the said ethylenimine groups being optionally substituted by one or more aliphatic radicals, or which is capable of forming such groups during the process. The textile materials may be of natural or regenerated cellulose, polymers or copolymers of acrylonitrile or aromatic polyesters. Specified alkaline agents are sodium and potassium hydroxide, sodium and potassium carbonate and as compounds which are converted into strongly alkaline reacting agents under the conditions of the process sodium and potassium bicarbonate, disodium and trisodium phosphate. Mixtures of any of the above agents may be used. The dyestuffs suitable for the present invention may be substantive or reactive dyes from a very large number of specified series and may be soluble or insoluble in water. The optical brighteners may be of stilbene, benzimidazole, benzoxazole or benzthiazole series. The preferred groupings which contain one or more reactive hydrogen atoms are sulphonic acid amides, HO-alkylene, H2N-alkylene and/or sulphonic acid alkylamide groups, for example H2N-SO2-, HO-CH2CH2-, H2N-CH2-CH2-and/or H3C-NH-SO2- groups. Groupings capable of forming reactive hydrogen atoms during the process are, for example, methylene ether or ester groups which are converted to methylol groups during the process. The water-solubilizing sulphonic acid-amide, -(b -hydroxyethyl) amide and -methylamide groups are suitable for the dyes of the present invention. The said uncoloured polyfunctional compounds may advantageously contain three or more groups of the formula in which X and Y which are the same or different represent a hydrogen atom or an alkyl radical especially an ethyl or methyl group. Suitable compounds have the formulae: Fixation of the dyestuffs may be effected at room temperature but advantageously by steam or dry heat at 40 DEG -150 DEG C. Although the dye, polyfunctional compound and alkali may be applied separately and in any sequence it is preferred to apply them simultaneously. A dye composition containing dyestuff, polyfunctional compound and, if desired, dispersing agents and/or protective colloids and/or usual auxiliaries may be employed. The polyfunctional compounds may be used as aqueous dispersions or as solutions in water-miscible solvents such as dimethylformamide, dimethylacetamide, N-methyl-2-pyrrolidone, glycol ethers, tetrahydrofuran, methanol, ethanol, isopropanol, acetone, formic and acetic acid. The dyebaths and printing pastes may also contain usual additives such as alkylsulphonates, sodium acetate, urea and thickening agents such as oil-in-water emulsions, tragacanth, alginate and methyl cellulose. The dyes may be applied by any usual means, e.g. padding and printing. Examples p of dyeing and printing cotton and rayon staple fabrics are given which dyed fabrics have improved wet and dry crease-resistance. Specifications 520,199, 811,221, 811,222, 827,568, 900,764, 908,301, 916,532, 917,764, 924,258 and U.S.A. Specifications 2,459,771 and 2,520,619 are referred to.

    New phthalocyanine dyes
    86.
    发明专利
    New phthalocyanine dyes 未知

    公开(公告)号：GB919179A

    公开(公告)日：1963-02-20

    申请号：GB3522660

    申请日：1960-10-14

    Applicant: BASF AG

    Inventor： TARTTER ARNOLD ,  ROHLAND WERNER ,  LUDSTECK DIETER ,  SCHROEDEL RUDOLF

    IPC: C09B47/26 ,  C09B62/016 ,  C09B62/457 ,  D06P1/38

    Abstract: 1-Amino-4-chloro- or -bromo-butine-(2), 1-amino - 4 - chlorobutene - (2), 1-amino-3 : 4-dichlorobutene-(2) and 1-amino-2 : 3-dimethyl-4-bromobutene-(2) hydrochlorides are made by treating methanolic hydrogen chloride the reaction product of the appropriate dihalobutene or butine with hexamethylene tetramine. The hydrochlorides of 1-(4-aminophenoxy)-3 : 4-dichlorobutene-(2), 1-(4-aminophenoxy)-4-chlorobutine - (2), 1-aminobenzene-3-sulphonic acid-(3 : 4-dichlorobuten-(2)-ylamide) and of 1-aminobenzene-4-sulphonamide substituted in the amide group by 3 : 4-dichlorobuten-(2)-yl, 4-chlorobuten-(2)-yl and 4-chlorobutin-(2)-yl radicals are made by hydrolysis of the corresponding acetylamino compounds. 2-(4-chlorobutin - (2) - ylamino - (1))-4 : 6-dichloro-1 : 3 : 5-triazine is made by reacting cyanuric chloride with 1-amino-4-chlorobutine. Benzene-1-sulphonic acid-(4-chlorobutin-(2)-ylamide)-3- and -4-carboxylic acid chlorides are made from the corresponding carboxylic acids prepared by reacting the corresponding benzoic acid sulphochloride with 1-amino-4- chlorobutine-(2). Specification 827,569 is referred to.ALSO:The invention comprises dyes of the formula:-(HO3S)n-(-Pc-)-(A-E-F)m where Pc is the radical of a metal-free or metalliferous phthalocyanine, or of a chlorphthalocyanine, phenylphahalocyanine, phenylmercaptophthalocyanine or phenylsulphonylphthalocyanine containing 1 to 4 chloro, phenyl, phenylmercapto or phenylsulphonyl radicals in the molecule and wherein the metal of the metalliferous derivatives is not lost by treatment with concentrated sulphuric acid at room temperature, A is one of the radicals -SO2-NH- E is -CH2C=C-CH2 or CH2-C=C-CH2-, R1 and R2 are each hydrogen, chlorine, bromine or methyl, X is hydrogen or sulphonic acid, F is chlorine or bromine or one of the radicals -O-SO3H, Q is a chlorine or bromine ion, n is 0-4 and m is 1-4. The dyes are made by reacting a phthalocyanine amine of the formula:-(HO3S)n-(Pc)-(D)m with m mols of a compound Y-E-Z where Pc, E, n and m are as above, Z is chlorine, bromine or -OSO3H, D is -NH2, -CH2NH2, or and Y is chlorine or bromine or when D is Y may also be or or by reacting a phthalocyanine sulphonchloride of the formula (Pc)-(SO2T)m + n with m mols of H2N-G-E-Z and hydrolysing the remaining sulphonchloride groups, where Pc, E, Z, m and n are as above, T is chlorine or bromine and G is a covalent linkage or or or by reacting a derivative of the formula (HO3S)n-(Pc)-(L-T)m with m mols of H2N-E-Z where Pc, T, E, Z, m and n are as above and L is or When Z in the above products is chlorine or bromine they may optionally be reacted with pyridine or tetramethylthiourea. Examples are given. The dyes dye and print textile materials of wool, silk, synthetic linear polyamides and leather, and dye and print natural or regenerated cellulose textile materials in conjunction with an alkali and heat treatment. Specification 827,569 is referred to.

    New monoazo dyestuffs derived from urea or thiourea and the production of the same
    89.
    发明专利
    New monoazo dyestuffs derived from urea or thiourea and the production of the same 未知

    公开(公告)号：GB876496A

    公开(公告)日：1961-09-06

    申请号：GB118359

    申请日：1959-01-13

    Applicant: BASF AG

    Inventor： ROHLAND WERNER ,  STOECKL ERICH

    IPC: C09B43/14 ,  C09B43/155 ,  C09B62/53

    Abstract: The invention comprises dyes of formula:- where X is the residue of a water-soluble monoazo dye, A is O or S, D is an arylene residue which may be substituted, E is an alkylene radical of 2-4 C atoms and Z is Hlg. The dyes are made by treating an aminoarylsulphonic acid halogen-alkylamide and an appropriate amino azo dye with phosgene, thiophosgene or a chloroformic acid ester. Alternatively the dyes may be made by conventional diazotization and coupling processes. Indicated aminoaryl sulphonic acid halogen alkylamides are aniline, aminodiphenyl and naphthylamine sulphonic acid chlor- or brom-alkylamides which may be substituted in the aryl nucleus with such substituents as alkyl, aryl, aralkyl, hydroxy, alkoxy, aroxy, sulphonic acid, sulphonamide, sulphohalogenalkylamide, nitro and halogen groups. Specified reactants from which the diazo residue is derived include 1, 4-diaminobenzene- 3-sulphonic acid and 1, 4-diamino-3-nitro-benzene. Coupling component residues are derived from amino-phenol and -naphthols and aminophenyl-methylpyrazolones and their sulphonic acids, sulphones and sulphonamides. The new dyes may be used on wool or linear polyamides but are particularly effective on natural or regenerated cellulose, especially when used in conjunction with an acid-binding agent. Numerous examples are provided of the preparation of the dyes and their use in dyeing cotton in red and yellow shades the diazo components used including 1-naphthylamine, 2-naphthylamine- 5-sulphonic acid, 1-acetamino-3-aniline- 4-sulphonic acid and 4-aminobenzoic acid. Specification 868,745 is referred to.

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