公开(公告)号：PL310463A1

公开(公告)日：1996-03-18

申请号：PL31046395

申请日：1995-09-14

Applicant: RHONE POULENC CHIMIE

Inventor： DOS SANTOS EMMANUEL ,  METIVIER PASCAL

IPC: B01J27/13 ,  B01J27/188 ,  B01J27/19 ,  B01J31/04 ,  C07B61/00 ,  C07C51/16 ,  C07C51/27 ,  C07C51/285 ,  C07C53/124 ,  C07C55/00 ,  C07C55/16 ,  C07C55/18 ,  C07C69/24 ,  C07C69/347 ,  C07C69/44 ,  C11C3/00 ,  C07C53/126

Abstract: Prepn. of mono- and di-carboxylic acids from unsatd. fatty acids and/or derivs., comprises: (i) oxidising an unsatd. fatty acid, in the form of an acid and/or ester, with hydrogen peroxide in presence of a metal oxide or a carboxylic acid, opt. with a ruthenium catalyst; (ii) reacting the mixt. with nitric acid in presence of a vanadium catalyst, opt. with a co-catalyst; and (iii) recovering the mono- and di-carboxylic acids. The starting material is pref. a fatty acid with at least one double bond, an animal fat or oil, a vegetable oil, an ester of a pptd. fatty acid and is pref. oleic, colza, sunflower and soya oil. The ruthenium catalyst is pref. present in amt. of 1-35 % w.r.t. H2O2. H2O2 may be used with a gp. VIa metal catalyst, esp. a W and/or Mo catalyst in amt. of 1-35 (pref. 3-10) %, w.r.t. H2O2. The vanadium catalyst may be a V halide, a V oxide, a V oxyhalide, a V or vanadyl sulphate, an alkali metal or ammonium vanadate, or V acetylacetonate. The optional V co-catalyst may be based on a Gp. VIIa or VIII metal. A stoichiometric amt. of H2O2 or a 0-50 % excess is used with a carboxylic acid in a hydrogen peroxide : carboxylic acid molar ratio of 10-500 (pref. 10-40) %.

公开(公告)号：AU2620495A

公开(公告)日：1995-12-18

申请号：AU2620495

申请日：1995-05-22

Applicant: RHONE POULENC CHIMIE

Inventor： METIVIER PASCAL ,  PARRON JEAN-CLAUDE

IPC: C08J11/24 ,  C08L75/04

公开(公告)号：ES2062428T3

公开(公告)日：1994-12-16

申请号：ES90400162

申请日：1990-01-22

Applicant: RHONE POULENC CHIMIE

Inventor： DESMURS JEAN-ROGER ,  METIVIER PASCAL ,  PADILLA GENEVIEVE ,  RAJOHARISON HARIVELO

IPC: C07C67/307 ,  C07C69/63 ,  C07C69/65

Abstract: Process for the preparation of an optically active 2-chloropropionate ester of formula: R being an optionally substituted hydrocarbyl residue, from an optically active lactate of formula the said process being characterised in that the said lactate (I) is brought into contact with phosgene and a compound chosen from aliphatic amides, aliphatic lactams and aliphatic ureas. Use of the process for the manufacture of intermediates which are useful in the agrochemical industry.

公开(公告)号：AT103889T

公开(公告)日：1994-04-15

申请号：AT90400162

申请日：1990-01-22

Applicant: RHONE POULENC CHIMIE

Inventor： DESMURS JEAN-ROGER ,  METIVIER PASCAL ,  PADILLA GENEVIEVE ,  RAJOHARISON HARIVELO

IPC: C07C67/307 ,  C07C69/63 ,  C07C69/65

公开(公告)号：DE69002694D1

公开(公告)日：1993-09-16

申请号：DE69002694

申请日：1990-05-29

Applicant: RHONE POULENC CHIMIE

Inventor： METIVIER PASCAL ,  RAJOHARISSON HARVELO

IPC: C07C67/307 ,  C07C67/327 ,  C07C69/63 ,  C07D213/63 ,  C07D307/58 ,  C07D333/32

Abstract: Process for the preparation of optically active 2-chloropropionic acid esters of formula … … COOR1 being a hydrolysable group from an optically active lactate of formula … … with inversion of configuration by bringing the lactate (II) into contact with SOCl2 followed by decomposition of the chlorosulphite formed, the said process being characterised in that at least the decomposition stage is carried out in the presence of ether.

公开(公告)号：DE69418149D1

公开(公告)日：1999-06-02

申请号：DE69418149

申请日：1994-11-04

Applicant: RHONE POULENC CHIMIE

Inventor： GACON-CAMOZ ANTOINETTE ,  METIVIER PASCAL

IPC: C07C201/16

公开(公告)号：AU699062B2

公开(公告)日：1998-11-19

申请号：AU3038795

申请日：1995-08-31

Applicant: RHONE POULENC CHIMIE

Inventor： SANTOS EMMANUEL DOS ,  METIVIER PASCAL

IPC: B01J27/13 ,  B01J27/188 ,  B01J27/19 ,  B01J31/04 ,  C07B61/00 ,  C07C51/16 ,  C07C51/27 ,  C07C51/285 ,  C07C53/124 ,  C07C55/00 ,  C07C55/16 ,  C07C55/18 ,  C07C69/24 ,  C07C69/347 ,  C07C69/44 ,  C11C3/00 ,  C07C55/02 ,  C07C55/14 ,  C07C55/20 ,  C07C55/21

Abstract: Prepn. of mono- and di-carboxylic acids from unsatd. fatty acids and/or derivs., comprises: (i) oxidising an unsatd. fatty acid, in the form of an acid and/or ester, with hydrogen peroxide in presence of a metal oxide or a carboxylic acid, opt. with a ruthenium catalyst; (ii) reacting the mixt. with nitric acid in presence of a vanadium catalyst, opt. with a co-catalyst; and (iii) recovering the mono- and di-carboxylic acids. The starting material is pref. a fatty acid with at least one double bond, an animal fat or oil, a vegetable oil, an ester of a pptd. fatty acid and is pref. oleic, colza, sunflower and soya oil. The ruthenium catalyst is pref. present in amt. of 1-35 % w.r.t. H2O2. H2O2 may be used with a gp. VIa metal catalyst, esp. a W and/or Mo catalyst in amt. of 1-35 (pref. 3-10) %, w.r.t. H2O2. The vanadium catalyst may be a V halide, a V oxide, a V oxyhalide, a V or vanadyl sulphate, an alkali metal or ammonium vanadate, or V acetylacetonate. The optional V co-catalyst may be based on a Gp. VIIa or VIII metal. A stoichiometric amt. of H2O2 or a 0-50 % excess is used with a carboxylic acid in a hydrogen peroxide : carboxylic acid molar ratio of 10-500 (pref. 10-40) %.

公开(公告)号：FR2750986B1

公开(公告)日：1998-10-16

申请号：FR9608725

申请日：1996-07-12

Applicant: RHONE POULENC CHIMIE

Inventor： METIVIER PASCAL

IPC: B01J31/02 ,  C07B43/02 ,  C07B61/00 ,  C07C201/00 ,  C07C201/10 ,  C07C205/22 ,  C07C205/44 ,  C07C205/45 ,  C07C205/60 ,  C07C207/04 ,  C07C227/04 ,  C07C227/06 ,  C07C229/64 ,  C07C201/08

公开(公告)号：AU3697597A

公开(公告)日：1998-02-09

申请号：AU3697597

申请日：1997-07-11

Applicant: RHONE POULENC CHIMIE

Inventor： METIVIER PASCAL

IPC: B01J31/02 ,  C07B43/02 ,  C07B61/00 ,  C07C201/00 ,  C07C201/10 ,  C07C205/22 ,  C07C205/44 ,  C07C205/45 ,  C07C205/60 ,  C07C207/04 ,  C07C227/04 ,  C07C227/06 ,  C07C229/64

公开(公告)号：DE69031404D1

公开(公告)日：1997-10-16

申请号：DE69031404

申请日：1990-04-23

Applicant: RHONE POULENC CHIMIE

Inventor： MAS JEAN-MANUEL ,  METIVIER PASCAL

IPC: A01N37/02 ,  C07B39/00 ,  C07C17/16 ,  C07C19/075 ,  C07C21/14 ,  C07C21/22 ,  C07C22/00 ,  C07C29/62 ,  C07C45/63 ,  C07C67/307 ,  C07C69/63 ,  C07C315/04 ,  C07C317/04 ,  C07D309/04