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公开(公告)号：JPH02259163A
公开(公告)日：1990-10-19
申请号：JP7808989
申请日：1989-03-31
Applicant: UBE INDUSTRIES
Inventor： YAMAMURA TAKETAMI , ISHIKAWA TOSHIHIRO , SHIBUYA MASAKI
IPC: C08J5/06 , C04B35/80 , D01F9/10 , D06M13/02 , D06M13/50 , D06M13/51 , D06M13/513 , D06M15/17 , D06M15/41 , D06M101/00
Abstract: PURPOSE:To provide the subject fiber having improved adhesivity to matrixes and capable of giving composite materials having excellent mechanical strengths by treating a central layer comprising a specific inorganic fiber containing silicon, carbon and oxygen atoms with a specified surface-treating agent to form a surface layer. CONSTITUTION:The surface of a central layer comprising an inorganic fiber which comprises (A) an amorphous substance comprising Si, C and O atoms, (B) an aggregate comprising amorphous SiO2 and crystalline ultrafine particles having a article size of
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公开(公告)号：JPH02217358A
公开(公告)日：1990-08-30
申请号：JP3609589
申请日：1989-02-17
Applicant: UBE INDUSTRIES
Inventor： YAMAMURA TAKETAMI , KUGIMOTO JUNICHI , ISHIKAWA TOSHIHIRO , SHIOJI YASUHIRO , SHIBUYA MASAKI
Abstract: PURPOSE:To reduce deterioration of title material under high-temperature oxidizing atmosphere and improve abrasion resistance by blending a specific crystalline carbon (and amorphous carbon) with a crystalline carbon kept in non- oriented state and/or amorphous carbon and Si-C-O substance. CONSTITUTION:The powder of (C) a silicon-containing polycyclic aromatic polymer obtained by heating (A) a random copolymer obtained by combining an organosilicone polymer consisting of Si-CH2 unit or Si-CH2 unit and Si-Si unit and having side chain with a petroleum based or coal based pitch and (B) mesophase polycyclic aromatic polymer is molded and burned at 800-3000 deg.C in vacuum or inert gas and as necessary melt or solution of the component C is repeatedly impregnated and burned to provide the title material consisting of a crystalline carbon (and amorphous carbon) led from a polycyclic aromatic compound kept in meriphase state and constituting the component C and crystalline carbon kept in a nonoriented state and led from optically isotropic polycyclic aromatic compound constituting the component C and/or amorphous carbon and Si-C-O substance consisting of an amorphous material composed of Si, C and O and/or crystalline ultrafine granules composed of beta-SiC and amorphous SiOx (0
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公开(公告)号：JPH02127433A
公开(公告)日：1990-05-16
申请号：JP28032588
申请日：1988-11-08
Applicant: UBE INDUSTRIES
Inventor： YAMAMURA TAKETAMI , KUGIMOTO JUNICHI , ISHIKAWA TOSHIHIRO , SHIOJI YASUHIRO , SHIBUYA MASAKI
Abstract: PURPOSE:To obtain the title polymer having excellent mechanical properties and improved oxidation resistance and wetting properties with plastic by subjecting a specific random copolymer to heat reaction and heat melting with a polycyclic aromatic compound within a specific temperature range. CONSTITUTION:(A) A random copolymer bonded through Si-C couple group to carbon of aromatic ring of a polycyclic aromatic compound-containing petroleum based or coal based pitch or heat treated product thereof as at least part of Si of transition metalcontaining organosilicon polymer consisting essentially of Si-CH2 bond unit or the above-mentioned Si-CH2 unit and Si-Si bond unit, having H, lower alkyl group, etc., at side chain of Si and having a atom such as Ti, Zr, etc., bonded directly or through O atom to at least part of Si of main skeleton consisting of the above-mentioned bond unit is subjected to heat reaction and heat melting with (B) a polycyclic aromatic compound consisting of both phase with optically isotropic phase at 200-500 deg.C.
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公开(公告)号：JPH01242738A
公开(公告)日：1989-09-27
申请号：JP6959188
申请日：1988-03-25
Applicant: UBE INDUSTRIES
Inventor： NAGASAWA TOSHIO , YAMAMURA TAKETAMI , ISHIKAWA TOSHIHIRO , SHIBUYA MASAKI
Abstract: PURPOSE:To prevent the leaning of fibrous bundles in a matrix and to improve the mechanical characteristics of a composite material by regulating either the warp or the woof to inorganic reinforcing fiber and providing the other with the compsn. same as that of the metal as the matrix. CONSTITUTION:In the reinforcing fibrous textile, either the warp or the woof is the bundles of inorganic reinforcing fiber and the other is the metallic wire having the compsn. same as that of the metal as the matrix. As the inorganic reinforcing fiber, the fiber composed of ceramics such as carbide, nitride, boride and oxide or of carbon can be used. The reinforcing fibrous textile is compounded with the matrix metal having the compsn. same as that of the metallic wire into the fiber reinforcing metallic composite material. In the obtd. composite material, the metallic wire is integrated into the matrix metal, by which there occurs a state where the inorganic reinforcing fiber is drawn and arranged toward one direction. In this way, since there is no winding caused by the crossing of each fiber bundle, the composite material having high bending strength, tensile strength, etc., can be obtd.
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公开(公告)号：JPH01208372A
公开(公告)日：1989-08-22
申请号：JP2983588
申请日：1988-02-10
Applicant: SHINAGAWA REFRACTORIES CO , UBE INDUSTRIES
Inventor： ICHIKAWA KENJI , TSUKAMOTO NOBORU , IIDA EIJI , YAMAMURA TAKEOMI , ISHIKAWA TOSHIHIRO , SHIBUYA MASAKI
IPC: C04B35/80
Abstract: PURPOSE:To improve fracture toughness, compressive strength, etc., by kneading specific reinforcing surface-treated inorganic fibers with ceramic powder and calcining the resultant mixture. CONSTITUTION:Inorganic fibers consisting of (a) an amorphous substance consisting of Si, MC (M is Ti or Zr) and O, (b) beta-SiC, MC, a solid solution of the beta-SiC with MC and/or respective crystalline fine particles of MC1-x (x is 0-1) and an aggregate of amorphous SiO2 and MO2 or a mixed system of the components (a) with (b) are coated with a solution of at least component selected from polytitanocarbosilanes or polyzirconocarbosilanes, silane coupling agents, phenolic resins having 500-20000 average molecular weight and petroleum pitch in an organic solvent and dried to afford reinforcing surface-treated inorganic fibers (A) having a surface layer of 0.1-50mum thickness. The resultant component (A) is then kneaded with ceramic powder or an organic substance capable of providing ceramic by heating to be a matrix (B) and the obtained mixture is press formed under 50-5000kg/cm pressure and calcined at 600-2400 deg.C.
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Patent Agency Ranking
公开(公告)号：JPS6464398A
公开(公告)日：1989-03-10
申请号：JP22023487
申请日：1987-09-04
Applicant: UBE INDUSTRIES
Inventor： YAMAMURA TAKETAMI , ISHIKAWA TOSHIHIRO , SHIBUYA MASAKI
Abstract: PURPOSE:To enhance strength by constituting an electromagnetic-waves transmitting material which is constituted of an amorphous inorganic fiber composed of silicon, carbon, oxygen and titanium or zirconium in specific ranges of percentage by weight, which has a specific resistivity value and which can transmit a specific range of microwaves selectively and by constituting a composite substance reinforced with the material. CONSTITUTION:An electromagnetic-waves transmitting material is constituted of an inorganic fiber composed substantially of Si, C, Ti or Zr, and O, and it has a resistivity of 15 -10 OMEGA.cm. The inorganic fiber contains 26-58wt.% Si, 25-62wt.% C, 0.5-30wt.% Ti or Zr, and 2-31wt.% O. The amorphous inorganic fiber constituting the electromagnetic-waves transmitting material transmits microwaves in a range of 500MHz-3000GHz selectively and its matrix is strengthened. If necessary, the electromagnetic-waves transmitting material can be used as a composite substance which uses a plastic or a ceramic as a matrix.
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公开(公告)号：JPS63120168A
公开(公告)日：1988-05-24
申请号：JP26365286
申请日：1986-11-07
Applicant: UBE INDUSTRIES
Inventor： YAMAMURA TAKETAMI , ISHIKAWA TOSHIHIRO , SHIBUYA MASAKI
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公开(公告)号：JPS62297426A
公开(公告)日：1987-12-24
申请号：JP13929886
申请日：1986-06-17
Applicant: UBE INDUSTRIES , TOYOTA CENTRAL RES & DEV
Inventor： YAMADA SENICHI , TOWATA SHINICHI , YAMAMURA TAKETAMI , ISHIKAWA TOSHIHIRO , SHIBUYA MASAKI
IPC: C22C47/08 , C22C21/00 , C22C47/00 , C22C47/12 , C22C49/00 , C22C49/04 , C22C49/06 , D01F9/10 , D06M11/00 , D06M11/77 , D06M23/08 , D06M23/10 , D06M101/00
Abstract: PURPOSE:To provide the titled reinforced metallic composite having improved mechanical characteristics such as anisotropy, residual stress and wear resistance by reinforcing the metal with continuous inorg. fibers consisting of Si, Ti, or Zr, C and O and short fibers, etc., of a heat resistant material interposed among said fibers. CONSTITUTION:The continuous inorg. fibers which consist of an amorphous material composed of Si, M (M is Ti or Zr), C and O or solid soln. such as beta-SiC or MC and/or respective ultrafine crystalline particles and aggregate, etc., of amorphous SiO2 and MO2 and contain Si, M, C and O are prepd. Said continuous inorg. fibers and a fibrous body consisting of the short fibers, whiskers or powder of the heat resistant material such as SiC, SiN or alumina interposed among the spaces of said inorg. fibers or the woven fabric thereof are then disposed in the cavity of a casting mold. The melt of a base material metal such as Al alloy or MC alloy is poured in this state into the cavity and is then cooled to solidify. The inorg. fiber-reinforced metal (FRM) composite is thus obtd.
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公开(公告)号：JPS62297425A
公开(公告)日：1987-12-24
申请号：JP13929686
申请日：1986-06-17
Applicant: UBE INDUSTRIES , TOYOTA CENTRAL RES & DEV
Inventor： YAMADA SENICHI , TOWATA SHINICHI , YAMAMURA TAKETAMI , ISHIKAWA TOSHIHIRO , SHIBUYA MASAKI
IPC: C22C47/08 , C22C21/00 , C22C47/00 , C22C49/00 , C22C49/06 , D01F9/10 , D06M11/00 , D06M11/83 , D06M101/00
Abstract: PURPOSE:To provide a fiber-reinforced metal which has overall excellent mechanical characteristics by consisting the same of continuous inorg. fibers consisting of Si, Ti or Zr, C and O and an Al alloy base material contg. a prescribed ratio of Ni and incorporating the needle-like phase of said alloy into said Al base material. CONSTITUTION:The continuous inorg. fibers which consist of an amorphous material substantially composed of Si, M, C and O, or solid soln. such as beta-SiC, MC (M is Ti or Zr) and/or respective ultrafine crystalline particles and aggregate, etc., consisting of amorphous SiO2 and MO2 and consist of Si, Ti, or Zr, C and O are prepd. Such continuous inorg. fibers and the Al alloy member contg. 0.5-6wt% Ni are combined by a casting method, more particularly high-pressure casting method and are solidified in a short period. The combined material is cooled from the direction orthogonal with the continuous fibers in the stage of such solidification, by which the fine needle-like crystalline material is crystallized in entanglement with said fibers in the direction perpendicular to the fibers among the continuous fibers, by which the excellent inter- layer shearing strength is imparted. As a result, the fiber-reinforced metal (FRM) having high strength is obtd.
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公开(公告)号：JPS62267329A
公开(公告)日：1987-11-20
申请号：JP11047186
申请日：1986-05-15
Applicant: UBE INDUSTRIES
Inventor： YAMAMURA TAKETAMI , ISHIKAWA TOSHIHIRO , SHIBUYA MASAKI
Abstract: PURPOSE:To obtain the titled composite material having excellent mechanical properties and transparency, by reinforcing a plastic material with an inorganic fiber having a core layer and a skin layer and composed of a specific inorganic substance containing Si, Ti, Zr, O and C. CONSTITUTION:The objective composite material is reinforced with an inorganic fiber composed of (A) a core layer consisting of an inorganic substance containing Si, Ti, Zr, C and O and composed of (i) an amorphous substance composed of Si, M (M is Ti or Zr), C and O or (ii) an agglomerate of crystalline ultra-fine particles of beta-SiC, MC, a solid solution of beta-SiC and MC and/or MC having particle diameter of
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