Abstract:
A powder coating composition comprises a component (A) containing carboxylic acid or anhydride functionality and a component (B) containing hydroxy functionality. The components (A) and (B) are both solids at temperatures up to 50.degree. C. and at least one of them is a synthetic resin having a glass transition temperature in the range 0.degree. to 120.degree. C. The carboxylic acid or anhydride-functional component (A) is a compound or polymer containing at least two cyclic carboxylic anhydride groups per molecule or is a compound containing a moiety of the formula: ##STR1## where X is a hydrogen atom or an alkyl group, or a cyclic anhydride thereof. The hydroxy-functional component (B) contains at least two hydroxy groups per molecule and contains at least one amine group in its molecule to catalyze the reaction of the carboxylic acid or anhydride groups of component (A) with the hydroxy groups of component (B). The composition is prepared by mixing the ingredients, extruding them at a temperature above the glass transition temperature of at least one of the components but below the fusion temperature, and comminuting the extrudate. The composition is applied to substrates and heated to cause fusion and reaction of the ingredients to cure the coating layer formed.
Abstract:
A resinous composition for coating use which is excellent in weather resistance and in low temperature curing properties, comprising a resin having resinous acid value based on carboxyl groups derived from its constituting tetrachlorophthalic acid of 2 to 8, a resinous acid value based on sulfonic acid groups derived from its constituting sulfophthalic acid of 0.5 to 5, and a functional group capable of reacting with a crosslinking agent to be compounded with the resin. The present resin is useful, in the combination form with a crosslinking agent, as a resinous vehicle of a coating composition which is excellent in curing properties, weather resistance, pigment dispersibility and storage stability and is specifically useful as an intermediate or top coat paint for automobile bodies or the like.
Abstract:
A resinous composition for coating use comprising a resin having a resinous acid value derived from polycarboxylic acid whose titration midpoint potential in non-aqueous potentiometric titration is more than -300 mV under the state capable of developing resinous acid value of 2 to 50 and having a functional group reactive with a crosslinking agent, and preparation thereof.The composition is useful for the preparation of coating composition having improved curing property.
Abstract:
In an aqueous coating composition comprising an aqueous medium having dispersed therein an unsaturated polycarboxylic acid resin neutralized with a base and a resol-type phenolic resin, an improvement characterized in that said composition further contains a copper compound dispersed in the aqueous medium in an amount of 0.0005 to 5% by weight in terms of copper metal, based on said polycarboxylic acid resin.
Abstract:
Provided herein are aqueous dispersions. The aqueous dispersions can comprise a first copolymer derived from one or more ethylenically unsaturated monomers, and a second carboxy-functional copolymer derived from one or more carboxylic acid-containing monomers. The aqueous dispersions can be used to prepare low- or zero-VOC aqueous coating compositions that possess desirable properties, including good block resistance and scrub resistance. Coatings and coating formulations comprising the aqueous dispersion, as well as methods of making and using the same are also provided.