公开(公告)号：WO2006002673A1

公开(公告)日：2006-01-12

申请号：PCT/EP2004/007197

申请日：2004-06-30

Applicant: PIRELLI PNEUMATICI S.P.A. ,  PAVAN, Federico ,  AGRESTI, Simone

Inventor： PAVAN, Federico ,  AGRESTI, Simone

IPC: C23C14/56

CPC classification number: C23C14/562 ,  C23C14/027 ,  C23C14/225 ,  C23C14/548

Abstract: The present invention relates to a method for producing a coated metal wire for reinforcing an elastomeric material, as well as to such a coated metal wire. Preferably, the wire comprises a metal core (6) and a coating layer made of made of a metal alloy material, such as for example brass. The method of the invention comprises the steps of conveying the metal core along a predetermined path in a substantially continuous manner, the predetermined path being positioned in proximity of at least one cathode (1, 2) made of a metal alloy material having a first composition, and of sputtering the at least one cathode (1, 2) onto the metal core (6) being conveyed along the predetermined path to obtain the coating layer, at least one portion of the predetermined path lying outside of a volume defined by a generatrix substantially perpendicular to a contour line of the at least one cathode (1, 2), so that the coating layer formed when the metal core is conveyed in correspondence of the at least one portion of said predetermined path has a second composition different from the first composition. In this way, the reactivity of the coated wire can be advantageously varied as a function of the reactivity of the wire elastomeric material, so as to allow to produce a metal wire coated with brass (or with another metal alloy) suitable for elastomeric materials having different compositions.

Abstract translation: 本发明涉及一种用于制造用于增强弹性体材料的涂覆金属丝以及这种涂覆的金属丝的方法。 优选地，线包括金属芯（6）和由金属合金材料（例如黄铜）制成的涂层。 本发明的方法包括以基本上连续的方式沿着预定路径输送金属芯的步骤，该预定路径被定位在由具有第一组成的金属合金材料制成的至少一个阴极（1,2）附近 ，并且将所述至少一个阴极（1,2）溅射到沿着所述预定路径输送的所述金属芯（6）上以获得所述涂层，所述预定路径的至少一部分位于由母线 基本上垂直于所述至少一个阴极（1,2）的轮廓线，使得当所述金属芯相对于所述预定路径的所述至少一部分被输送时形成的所述涂层具有不同于所述第一 组成。 以这种方式，涂覆的丝线的反应性可以有利地根据线弹性体材料的反应性而变化，从而允许生产涂覆有黄铜（或与另一种金属合金）的金属线，该金属线适合于具有 不同的成分。

公开(公告)号：WO2005095078A1

公开(公告)日：2005-10-13

申请号：PCT/EP2004/003621

申请日：2004-03-31

Applicant: PIRELLI PNEUMATICI S.P.A. ,  PAVAN, Federico ,  AGRESTI, Simone

Inventor： PAVAN, Federico ,  AGRESTI, Simone

IPC: B29B15/00

CPC classification number: C23C4/18 ,  C23C14/165 ,  C23C14/562 ,  C23C14/5806 ,  C23C14/5886 ,  C23C14/5893 ,  C23C26/00

Abstract: The present invention relates to a process for manufacturing a metal wire comprising a steel core and a metal coating layer in a radially outer position with respect to said steel core. The metal coating layer comprises an alloy of at least two metal components. The process comprises the steps of coating the steel core by depositing onto the steel core separate layers of the two metal components, each layer having a thickness not higher than 50 nm, and drawing the coated core to form the alloy of said at least two metal components. Preferably, the deposition step is carried out by means of a plasma deposition technique.

Abstract translation: 本发明涉及一种用于制造金属线的方法，所述金属线包括相对于所述钢芯在径向外侧位置的钢芯和金属涂层。 金属涂层包括至少两种金属组分的合金。 该方法包括以下步骤：通过在两个金属组分的钢芯分离层上沉积钢芯，每个层的厚度不高于50nm，并且拉伸涂覆的芯以形成所述至少两种金属的合金 组件。 优选地，沉积步骤通过等离子体沉积技术进行。

公开(公告)号：WO2004057053A3

公开(公告)日：2004-08-05

申请号：PCT/EP0314810

申请日：2003-12-22

Applicant: PIRELLI ,  PAVAN FEDERICO ,  AGRESTI SIMONE ,  CAVALLOTTI PIETRO LUIGI ,  NOBILI LUCA

Inventor： PAVAN FEDERICO ,  AGRESTI SIMONE ,  CAVALLOTTI PIETRO LUIGI ,  NOBILI LUCA

IPC: B21C37/04 ,  B29C70/68 ,  C23C14/02 ,  C23C14/16 ,  C23C14/56 ,  C23C14/58 ,  C23C16/54

CPC classification number: B21C37/042 ,  C23C14/021 ,  C23C14/165 ,  C23C14/562 ,  C23C14/5886 ,  C23C16/545 ,  D07B1/0666 ,  D07B2205/3089 ,  D07B2801/18

Abstract: A method for producing a metal wire for reinforcing an elastomeric material as well as a metal wire and a metal cord for reinforcing such an elastomeric material are described. The metal wire comprises a metal core having a predetermined initial diameter and a metal coating layer. The method comprises the steps of: a) submitting the core to at least one surface treatment for predisposing the surface of the core to being coated with the coating layer; b) thermally treating the core; c) depositing the metal coating layer to a predetermined initial thickness on the core by means of a plasma deposition technique; and d) drawing the coated core until the core has a final diameter smaller than said predetermined initial diameter and the metal coating layer has a final thickness smaller than said predetermined initial thickness. Advantageously, it is possible to obtain a wire coated in a uniform and homogeneous manner, including a core having a smooth surface suitable for the deposition of the coating layer and a structure suitable for the cold deformation involved in the drawing step.

Abstract translation: 描述了用于制造用于增强弹性体材料的金属线以及用于增强这种弹性体材料的金属线和金属线的方法。 金属线包括具有预定初始直径的金属芯和金属涂层。 该方法包括以下步骤：a）将芯提供给至少一种表面处理，以使芯的表面易于被涂层涂覆; b）热处理芯; c）借助于等离子体沉积技术将所述金属涂层沉积到所述芯上的预定初始厚度; 以及d）拉制涂覆的芯，直到芯具有小于所述预定初始直径的最终直径，并且金属涂层具有小于所述预定初始厚度的最终厚度。 有利的是，可以获得以均匀和均匀的方式涂覆的线材，包括具有适于沉积涂层的光滑表面的芯和适用于拉伸步骤中涉及的冷变形的结构。

公开(公告)号：WO2012085651A8

公开(公告)日：2013-07-18

申请号：PCT/IB2011003144

申请日：2011-12-21

Applicant: PIRELLI ,  AGRESTI SIMONE ,  CIANCIOSI FEDERICO ,  PIERALLI ANDREA

Inventor： AGRESTI SIMONE ,  CIANCIOSI FEDERICO ,  PIERALLI ANDREA

IPC: C21D9/52 ,  B21C37/04 ,  C21D9/573 ,  C21D9/64

CPC classification number: C21D9/5732 ,  B21C37/04 ,  C21D9/525 ,  C21D9/64

Abstract: The process for manufacturing a steel wire comprises: providing a steel wire; austenitizing said steel wire; patenting said steel wire; drawing said steel wire. The patenting of said steel wire comprises: slow cooling said steel wire to a first predetermined temperature; quick cooling the steel wire to a second predetermined temperature; keeping said steel wire at said second predetermined temperature. During the slow cooling, the steel wire substantially keeps its austenite structure unaltered; with the subsequent quick cooling, the steel wire is taken to the best conditions in order to start the phase change in which the austenite structure is transformed into a pearlite structure.

Abstract translation: 制造钢丝的方法包括：提供钢丝; 所述钢丝奥氏体化; 钢丝专利; 画钢丝。 所述钢线的专利权包括：将所述钢丝缓慢冷却至第一预定温度; 将钢丝快速冷却至第二预定温度; 将所述钢丝保持在所述第二预定温度。 在缓慢冷却过程中，钢丝基本上保持其奥氏体结构不变; 随后快速冷却，钢丝线被采取到最佳状态，以开始奥氏体结构转变成珠光体组织的相变。

公开(公告)号：WO2012085651A1

公开(公告)日：2012-06-28

申请号：PCT/IB2011/003144

申请日：2011-12-21

Applicant: PIRELLI TYRE S.P.A. ,  AGRESTI, Simone ,  CIANCIOSI, Federico ,  PIERALLI, Andrea

Inventor： AGRESTI, Simone ,  CIANCIOSI, Federico ,  PIERALLI, Andrea

IPC: C21D9/52 ,  C21D9/573 ,  C21D9/64 ,  B21C37/04

CPC classification number: C21D9/5732 ,  B21C37/04 ,  C21D9/525 ,  C21D9/64

Abstract: The process for manufacturing a steel wire comprises: providing a steel wire; austenitizing said steel wire; patenting said steel wire; drawing said steel wire. The patenting of said steel wire comprises: slow cooling said steel wire to a first predetermined temperature; quick cooling the steel wire to a second predetermined temperature; keeping said steel wire at said second predetermined temperature. During the slow cooling, the steel wire substantially keeps its austenite structure unaltered; with the subsequent quick cooling, the steel wire is taken to the best conditions in order to start the phase change in which the austenite structure is transformed into a pearlite structure.

Abstract translation: 制造钢丝的方法包括：提供钢丝; 所述钢丝奥氏体化; 钢丝专利; 画钢丝。 所述钢线的专利权包括：将所述钢丝缓慢冷却至第一预定温度; 将钢丝快速冷却至第二预定温度; 将所述钢丝保持在所述第二预定温度。 在缓慢冷却过程中，钢丝基本上保持其奥氏体结构不变; 随后快速冷却，钢丝线被采取到最佳状态，以开始奥氏体结构转变成珠光体组织的相变。

公开(公告)号：WO2004113584A1

公开(公告)日：2004-12-29

申请号：PCT/IT2002/000823

申请日：2002-12-23

Applicant: PIRELLI PNEUMATICI S.P.A. ,  PAVAN, Federico ,  AGRESTI, Simone ,  CAVALLOTTI, Pietro, Luigi ,  NOBILI, Luca

Inventor： PAVAN, Federico ,  AGRESTI, Simone ,  CAVALLOTTI, Pietro, Luigi ,  NOBILI, Luca

IPC: C23C14/56

CPC classification number: B21C37/042 ,  C23C14/021 ,  C23C14/165 ,  C23C14/562 ,  C23C14/5886 ,  C23C16/545 ,  D07B1/0666 ,  D07B2205/3089 ,  D07B2801/18

Abstract: A method for producing a metal wire intended to reinforce elastomeric materials, of the type comprising a core and a metal coating layer, as well as a metal wire and a metal cord intended to reinforce such materials are described. The method comprising the following steps of: a) conveying a metal core having a predetermined initial diameter along a predetermined conveying direction; b) depositing a metal coating layer having a predetermined initial thickness on said metal core by means of a plasma deposition technique; and c) drawing the core thus coated until a wire comprising a core having a final diameter smaller than said predetermined initial diameter and a metal coating layer having a final thickness smaller than said predetermined initial thickness is obtained. Advantageously, it is possible to obtain a wire coated in a uniform and homogeneous manner, in which the variations of amount of metal deposited and the concentration gradients of the components of metal alloys are minimized both in the axial direction and in the radial direction.

Abstract translation: 描述了一种用于生产用于加强包括芯和金属涂层的类型的弹性材料的金属线的方法，以及用于加强这种材料的金属线和金属线。 该方法包括以下步骤：a）沿预定输送方向输送具有预定初始直径的金属芯; b）通过等离子体沉积技术在所述金属芯上沉积具有预定初始厚度的金属涂层; 以及c）绘制如此涂覆的芯直到包含最终直径小于所述预定初始直径的芯的金属丝和最终厚度小于所述预定初始厚度的金属涂层。 有利地，可以获得以均匀均匀的方式涂覆的线，其中金属合金的量的变化和金属合金的组分的浓度梯度在轴向方向和径向方向都最小化。

公开(公告)号：WO2004057053A2

公开(公告)日：2004-07-08

申请号：PCT/EP2003/014810

申请日：2003-12-22

Applicant: PIRELLI PNEUMATICI S.P.A. ,  PAVAN, Federico ,  AGRESTI, Simone ,  CAVALLOTTI, Pietro, Luigi ,  NOBILI, Luca

Inventor： PAVAN, Federico ,  AGRESTI, Simone ,  CAVALLOTTI, Pietro, Luigi ,  NOBILI, Luca

IPC: C23C14/56

CPC classification number: B21C37/042 ,  C23C14/021 ,  C23C14/165 ,  C23C14/562 ,  C23C14/5886 ,  C23C16/545 ,  D07B1/0666 ,  D07B2205/3089 ,  D07B2801/18

Abstract: A method for producing a metal wire for reinforcing an elastomeric material as well as a metal wire and a metal cord for reinforcing such an elastomeric material are described. The metal wire comprises a metal core having a predetermined initial diameter and a metal coating layer. The method comprises the steps of: a) submitting the core to at least one surface treatment for predisposing the surface of the core to being coated with the coating layer; b) thermally treating the core; c) depositing the metal coating layer to a predetermined initial thickness on the core by means of a plasma deposition technique; and d) drawing the coated core until the core has a final diameter smaller than said predetermined initial diameter and the metal coating layer has a final thickness smaller than said predetermined initial thickness. Advantageously, it is possible to obtain a wire coated in a uniform and homogeneous manner, including a core having a smooth surface suitable for the deposition of the coating layer and a structure suitable for the cold deformation involved in the drawing step.

Abstract translation: 描述了用于增强弹性体材料的金属丝的制造方法以及用于加强这种弹性体材料的金属线和金属线。 金属线包括具有预定初始直径的金属芯和金属涂层。 该方法包括以下步骤：a）将芯体提交至少一个表面处理以使芯的表面易于涂覆涂层; b）热处理芯; c）通过等离子体沉积技术将金属涂层沉积在芯上预定的初始厚度; 以及d）拉制所述涂覆的芯，直到所述芯具有小于所述预定初始直径的最终直径，并且所述金属涂层的最终厚度小于所述预定初始厚度。 有利地，可以获得以均匀均匀的方式涂覆的线，包括具有适于沉积涂层的光滑表面的芯和适于牵引步骤中涉及的冷变形的结构。

公开(公告)号：WO2008148407A1

公开(公告)日：2008-12-11

申请号：PCT/EP2007/004973

申请日：2007-06-05

Applicant: PIRELLI TYRE S.P.A. ,  AGRESTI, Simone ,  PAVAN, Federico

Inventor： AGRESTI, Simone ,  PAVAN, Federico

IPC: B60C9/00 ,  D07B1/06

CPC classification number: B60C9/0007 ,  B29D30/48 ,  B29D2030/483 ,  B60C15/06 ,  D07B1/0666 ,  D07B2201/2006 ,  D07B2201/2009 ,  D07B2201/2011 ,  D07B2201/2013 ,  D07B2205/3025 ,  D07B2205/3064 ,  D07B2205/3071 ,  D07B2205/3075 ,  D07B2205/3085 ,  D07B2205/3089 ,  D07B2801/18

Abstract: Tire (100) comprising at least one structural element including at least one metal cord comprising a plurality of elementary metal wires stranded together, each elementary metal wire being coated with at least one first metal coating layer, said metal cord being coated with at least one second metal coating layer, wherein said at least one second metal coating layer has a nominal thickness higher than or equal to 30 nm, preferably of from 50 nm to 120 nm, more preferably of from 70 nm to 100 nm.

Abstract translation: 轮胎（100）包括至少一个结构元件，所述至少一个结构元件包括至少一个金属线，所述至少一个金属线包括多个基本金属线，所述多个金属线绞合在一起，每个基本金属线被涂覆有至少一个第一金属涂层， 第二金属涂层，其中所述至少一个第二金属涂层具有高于或等于30nm，优选为50nm至120nm，更优选为70nm至100nm的标称厚度。

公开(公告)号：WO2005095668A8

公开(公告)日：2006-04-13

申请号：PCT/EP2004003623

申请日：2004-03-31

Applicant: PIRELLI ,  PAVAN FEDERICO ,  AGRESTI SIMONE

Inventor： PAVAN FEDERICO ,  AGRESTI SIMONE

IPC: C23C14/35 ,  C23C14/56

CPC classification number: H01J37/3405 ,  C23C14/352 ,  C23C14/562

Abstract: The present invention relates to a method and an apparatus for producing a steel wire for reinforcing an elastomeric material. The steel wire comprises a metal core (5) and a coating layer made of a metal alloy material having a composition including at least one first metal component and at least one second metal component. According to the invention, the method comprises the steps of: a) conveying the steel core (5) along a predetermined path in a substantially continuous manner; b) co-sputtering at least one first powered cathode (1; 1',1") made of said first metal component and at least one second powered cathode (2; 2',2") made of said second metal component onto the steel core being moved along said predetermined path to obtain a coating layer made of a metal alloy material of a first composition; and c) adjusting the power provided to at least one of said first (1; 1',1") and second cathode (2; 2',2") to obtain a coating layer made of a metal alloy material of a second composition.

Abstract translation: 本发明涉及一种用于生产用于增强弹性材料的钢丝的方法和装置。 所述钢丝包括金属芯（5）和由具有至少一种第一金属成分和至少一种第二金属成分的组成的金属合金材料制成的涂层。 根据本发明，该方法包括以下步骤：a）以大致连续的方式沿预定路径输送钢芯（5）; b）共同溅射由所述第一金属部件制成的至少一个第一有源阴极（1; 1'，1“）和由所述第二金属部件制成的至少一个第二有源阴极（2; 2'，2”） 钢芯沿着所述预定路径移动以获得由第一组合物的金属合金材料制成的涂层; 以及c）调整提供给所述第一（1，1'，1“）和第二阴极（2; 2'，2”）中的至少一个的功率，以获得由第二组成的金属合金材料制成的涂层 。

公开(公告)号：WO2005095668A1

公开(公告)日：2005-10-13

申请号：PCT/EP2004/003623

申请日：2004-03-31

Applicant: PIRELLI PNEUMATICI S.P.A. ,  PAVAN, Federico ,  AGRESTI, Simone

Inventor： PAVAN, Federico ,  AGRESTI, Simone

IPC: C23C14/56

CPC classification number: H01J37/3405 ,  C23C14/352 ,  C23C14/562

Abstract: The present invention relates to a method and an apparatus for producing a steel wire for reinforcing an elastomeric material. The steel wire comprises a metal core (5) and a coating layer made of a metal alloy material having a composition including at least one first metal component and at least one second metal component. According to the invention, the method comprises the steps of: a) conveying the steel core (5) along a predetermined path in a substantially continuous manner; b) co-sputtering at least one first powered cathode (1; 1',1") made of said first metal component and at least one second powered cathode (2; 2',2") made of said second metal component onto the steel core being moved along said predetermined path to obtain a coating layer made of a metal alloy material of a first composition; and c) adjusting the power provided to at least one of said first (1; 1',1") and second cathode (2; 2',2") to obtain a coating layer made of a metal alloy material of a second composition.

Abstract translation: 本发明涉及一种用于生产用于增强弹性材料的钢丝的方法和装置。 所述钢丝包括金属芯（5）和由具有至少一种第一金属成分和至少一种第二金属成分的组成的金属合金材料制成的涂层。 根据本发明，该方法包括以下步骤：a）以大致连续的方式沿预定路径输送钢芯（5）; b）共同溅射由所述第一金属部件制成的至少一个第一有源阴极（1; 1'，1“）和由所述第二金属部件制成的至少一个第二有源阴极（2; 2'，2”） 钢芯沿着所述预定路径移动以获得由第一组合物的金属合金材料制成的涂层; 以及c）调整提供给所述第一（1，1'，1“）和第二阴极（2; 2'，2”）中的至少一个的功率，以获得由第二组成的金属合金材料制成的涂层 。