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1.发明申请
公开(公告)号：WO2004070862A3
公开(公告)日：2004-08-19
申请号：PCT/IT2004/000038
申请日：2004-02-04
Applicant: ENEA - Ente per le nuevo Tecnologie, l'Energia e l'Ambiente , UNIVERSITÀ DEGLI STUDI DI ROMA "LA SAPIENZA" , CNR CONSIGLIO NAZIONALE DELLE RICERCHE , BELLITTO, Carlo , PROSINI, Pier, Paolo , BAUER, Elvira, Maria , PASQUALI, Mauro , RIGHINI, Guido
Inventor： BELLITTO, Carlo , PROSINI, Pier, Paolo , BAUER, Elvira, Maria , PASQUALI, Mauro , RIGHINI, Guido
IPC: H01M4/58
Abstract: The invention relates to a method for the production of a crystal material with formula LIMPO4, where "M" is a transition metal, the method providing the steps of grinding and mixing at the solid state an organic phosphonate of a transition metal with a lithium salt and causing them to react together by pyrolysis at the solid state and high temperature by one or more heating cycles. It is thus obtained a micrometric size crystal material already containing carbon without the latter should be added thereafter. According to the invention, carbon forms inside the material during its pyrolysis directly to the surface of the lithium iron phosphate particles, interacting with the latter and ensuring an optimum electron drain.
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2.发明申请METHOD FOR SYNTHESIZING A CATHODIC MATERIAL BASED ON LITHIUM IRONPHOSPHATE, INTRINSICALLY CONTAINING CARBON 审中-公开合成含基于碳酸铁的阴极材料，本质上含有碳的方法
公开(公告)号：WO2004070862A8
公开(公告)日：2004-10-21
申请号：PCT/IT2004000038
申请日：2004-02-04
Applicant: ENEA ENTE NUOVE TEC , UNIV ROMA , CONSIGLIO NAZIONALE RICERCHE , BELLITTO CARLO , PROSINI PIER PAOLO , BAUER ELVIRA MARIA , PASQUALI MAURO , RIGHINI GUIDO
Inventor： BELLITTO CARLO , PROSINI PIER PAOLO , BAUER ELVIRA MARIA , PASQUALI MAURO , RIGHINI GUIDO
CPC classification number: H01M4/5825 , C01B25/45 , H01M4/0435 , H01M4/136 , H01M4/621 , H01M4/625
Abstract: The invention relates to a method for the production of a crystal material with formula LIMPO4, where "M" is a transition metal, the method providing the steps of grinding and mixing at the solid state an organic phosphonate of a transition metal with a lithium salt and causing them to react together by pyrolysis at the solid state and high temperature by one or more heating cycles. It is thus obtained a micrometric size crystal material already containing carbon without the latter should be added thereafter. According to the invention, carbon forms inside the material during its pyrolysis directly to the surface of the lithium iron phosphate particles, interacting with the latter and ensuring an optimum electron drain.
Abstract translation: 本发明涉及一种生产具有式LIMPO4的晶体材料的方法，其中“M”为过渡金属，该方法提供在固态下研磨和混合过渡金属与锂盐的有机膦酸酯的步骤 并使它们在固态和高温下通过一次或多次加热循环热解而一起反应。 因此，此后应该添加已经含有碳但没有碳的微米尺寸晶体材料。 根据本发明，在热解过程中材料内部的碳直接形成到磷酸铁锂颗粒的表面上，与后者相互作用并确保最佳的电子消耗。
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3.发明申请
公开(公告)号：WO2004070862A2
公开(公告)日：2004-08-19
申请号：PCT/IT2004000038
申请日：2004-02-04
Applicant: ENEA ENTE NUOVE TEC , UNIV ROMA , CONSIGLIO NAZIONALE RICERCHE , BELLITTO CARLO , PROSINI PIER PAOLO , BAUER ELVIRA MARIA , PASQUALI MAURO , RIGHINI GUIDO
Inventor： BELLITTO CARLO , PROSINI PIER PAOLO , BAUER ELVIRA MARIA , PASQUALI MAURO , RIGHINI GUIDO
CPC classification number: H01M4/5825 , C01B25/45 , H01M4/0435 , H01M4/136 , H01M4/621 , H01M4/625
Abstract: The invention relates to a method for the production of a crystal material with formula LIMPO4, where "M" is a transition metal, the method providing the steps of grinding and mixing at the solid state an organic phosphonate of a transition metal with a lithium salt and causing them to react together by pyrolysis at the solid state and high temperature by one or more heating cycles. It is thus obtained a micrometric size crystal material already containing carbon without the latter should be added thereafter. According to the invention, carbon forms inside the material during its pyrolysis directly to the surface of the lithium iron phosphate particles, interacting with the latter and ensuring an optimum electron drain.
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4.发明申请GALLIUM DOPED LITHIUM MANGANESE OXIDE SPINELS (LiGaxMn2-xO4) AS ACTIVE CATHODE MATERIAL FOR LITHIUM OR LITHIUM-ION RECHARGEABLE BATTERIES WITH IMPROVED CYCLING PERFORMANCE 审中-公开作为活性阴极材料，用于具有改进的循环性能的锂离子或锂离子可充电电池的硅酸锂氧化锰氧化物（LiGaxMn2-xO4）
公开(公告)号：WO1997037394A1
公开(公告)日：1997-10-09
申请号：PCT/IT1997000048
申请日：1997-03-05
Applicant: CONSIGLIO NAZIONALE DELLE RICERCHE , PISTOIA, Gianfranco , BELLITTO, Carlo , ANTONINI, Alessandra
Inventor： CONSIGLIO NAZIONALE DELLE RICERCHE
IPC: H01M04/50
CPC classification number: H01M4/505 , C01G45/1242 , C01P2002/32 , C01P2002/54 , C01P2006/40 , H01M4/131 , H01M10/052 , Y02T10/7011
Abstract: A lithium or lithium-ion rechargeable battery with improved cycling performance, with nominal voltage of 4 V, comprising an anode made of lithium optionally alloyed with other metals, or an anode made of an electrically conductive material wherein lithium is intercalated in ionic form, a non-aqueous electrolyte and a cathode based on a modified manganese spinel, characterised in that said spinel is modified by the substitution of a portion of manganese with an equal amount of gallium, according to the formula: LiGaxMn2-xO4 (wherein 0
Abstract translation: 具有改进的循环性能的锂或锂离子可再充电电池，额定电压为4V，包括由任选与其它金属合金化的锂制成的阳极或由导电材料制成的阳极，其中锂以离子形式插入， 非水电解质和基于改性锰尖晶石的阴极，其特征在于所述尖晶石通过用等量的镓取代一部分锰而被修饰，根据下式：LiGaxMn2-xO4（其中0
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