公开(公告)号：WO2010044940A3

公开(公告)日：2010-04-22

申请号：PCT/US2009/051476

申请日：2009-07-23

Applicant: GENERAL ELECTRIC COMPANY ,  CELLA, James, Anthony ,  SHIANG, Joseph, John ,  SHANKLIN, Elliott, West ,  SMIGELSKI, Paul, Michael, Jr.

Inventor： CELLA, James, Anthony ,  SHIANG, Joseph, John ,  SHANKLIN, Elliott, West ,  SMIGELSKI, Paul, Michael, Jr.

IPC: C07C39/42 ,  C07C43/225 ,  C07F5/02 ,  C07D295/088 ,  C09K11/00

Abstract: Polyfluorene polymers and copolymers having substantial amounts (10-100%) of fluorenes coupled at the 2 and 5 positions of fluorene are useful as active layers in OLED devices where triplet energies > 2.10 eV are required.

公开(公告)号：WO2008156928A1

公开(公告)日：2008-12-24

申请号：PCT/US2008/063240

申请日：2008-05-09

Applicant: GENERAL ELECTRIC COMPANY ,  LIU, Jie ,  ZHANG, Yanshi ,  YE, Quing ,  CELLA, James, Anthony

Inventor： LIU, Jie ,  ZHANG, Yanshi ,  YE, Quing ,  CELLA, James, Anthony

IPC: H01L51/00 ,  C08G65/40 ,  C08G65/48 ,  C08G75/02 ,  C08G75/12 ,  C08G75/23 ,  H05B33/14

CPC classification number: H01L51/0035 ,  C08G65/48 ,  C08G75/23 ,  H01L51/0085 ,  H01L51/5016

Abstract: In one aspect, the invention provides a polyarylether having pendant carbazolyl groups. The polymers of the invention are made by the bromination of a polyarylether, which is then reacted with a carbazole moiety. The polymers may have some amount of unsubstituted aromatic groups and some brominated aromatic groups also. These polymers find use in optoelectronic device. Thus, in another aspect, the invention provides optoelectronic device comprising a polyarylether having pendant carbazolyl groups.

Abstract translation: 一方面，本发明提供了具有咔唑基侧基的聚芳醚基。 本发明的聚合物通过聚芳基醚的溴化而制成，然后与咔唑部分反应。 聚合物也可以具有一定量的未取代的芳族基团和一些溴化芳族基团。 这些聚合物可用于光电器件。 因此，在另一方面，本发明提供了包含具有侧链咔唑基的聚芳醚的光电装置。

公开(公告)号：WO2008014037A2

公开(公告)日：2008-01-31

申请号：PCT/US2007068620

申请日：2007-05-10

Applicant: GEN ELECTRIC ,  SHIANG JOSEPH JOHN ,  LITZ KYLE ERIK ,  CELLA JAMES ANTHONY ,  CHICHAK KELLY SCOTT ,  YE QING

Inventor： SHIANG JOSEPH JOHN ,  LITZ KYLE ERIK ,  CELLA JAMES ANTHONY ,  CHICHAK KELLY SCOTT ,  YE QING

IPC: C07F15/00 ,  C09K11/06

CPC classification number: C07F15/0033 ,  H01L51/0035 ,  H01L51/0043 ,  H01L51/0061 ,  H01L51/0085 ,  H01L51/5012 ,  Y02E10/549 ,  Y10S428/917

Abstract: The present invention provides compositions comprising at least one novel organic iridium compound which comprises at least one cyclometallated ligand and at least one ketopyrrole ligand. The organic iridium compositions of the present invention are referred to as Type (1) organic iridium compositions and are constituted such that no ligand of the novel organic iridium compound has a number average molecular weight of 2,000 grams per mole or greater (as measured by gel permeation chromatography). Type (1) organic iridium compositions are referred to herein as comprising "organic iridium complexes". The novel organic iridium compositions are useful in optoelectronic electronic devices such as OLED devices and photovoltaic devices. In one aspect, the invention provides novel organic iridium compositions useful in the preparation of OLED devices exhibiting enhanced color properties and light output efficiencies.

Abstract translation: 本发明提供包含至少一种新型有机铱化合物的组合物，其包含至少一个环金属化配体和至少一个酮吡咯配体。 本发明的有机铱组合物被称为（1）型有机铱组合物，并且构成为使新型有机铱化合物的配体不具有2,000克/摩尔或更大的数均分子量（如通过凝胶 渗透色谱法）。 类型（1）有机铱组合物在本文中被称为包含“有机铱配合物”。 新颖的有机铱组合物可用于光电子电子器件如OLED器件和光伏器件。 一方面，本发明提供了用于制备显示增强的颜色性质和光输出效率的OLED器件的新型有机铱组合物。

公开(公告)号：WO2007109518A2

公开(公告)日：2007-09-27

申请号：PCT/US2007/064126

申请日：2007-03-16

Applicant: GENERAL ELECTRIC COMPANY ,  CELLA, James, Anthony ,  LEWIS, Larry, Neil

Inventor： CELLA, James, Anthony ,  LEWIS, Larry, Neil

CPC classification number: C08G77/38 ,  C08G61/02 ,  C08G77/42 ,  C09K11/06 ,  C09K2211/1416 ,  H01L51/0039 ,  H01L51/0094 ,  H01L51/5012 ,  H05B33/14

Abstract: Optoelectronic devices include a polymer composition derived from reaction between a hydrosiloxane and a polyfluorene comprising structural units of formula (I) wherein R 1 and R 2 are independently alkyl, substituted alkyl, alkenyl, alkynyl, substituted alkenyl, substituted alkynyl, alkyloxy, substituted alkoxy, alkenoxy, alkynoxy, substituted alkenoxy, substituted alkynoxy, or a combination thereof; Ar 1 and Ar 2 are independently aryl or substituted aryl; m and n are independently 0 or 1 ; and at least one of R 1 and R 2 is alkenyl, alkynyl, substituted alkenyl, or substituted alkynyl.

Abstract translation: 光电子器件包括衍生自包含式（I）的结构单元的氢硅氧烷和聚芴之间的反应的聚合物组合物，其中R 1和R 2独立地是烷基，取代的烷基， 烯基，炔基，取代的烯基，取代的炔基，烷氧基，取代的烷氧基，烯氧基，炔氧基，取代的烯氧基，取代的炔氧基或其组合; Ar 1和Ar 2独立地是芳基或取代的芳基; m和n独立地为0或1; 并且R 1和R 2中的至少一个是烯基，炔基，取代的烯基或取代的炔基。

公开(公告)号：WO2005118682A1

公开(公告)日：2005-12-15

申请号：PCT/US2004/015848

申请日：2004-05-20

Applicant: GENERAL ELECTRIC COMPANY ,  RUBINSZTAJN, Slawomir ,  CELLA, James Anthony

Inventor： RUBINSZTAJN, Slawomir ,  CELLA, James Anthony

IPC: C08G77/08

CPC classification number: C08G77/08

Abstract: A new silicone condensation reaction, the condensation between an alkoxy silane or siloxane and an organo- hydrosilane or siloxane and catalysts therefore is described and claimed.

Abstract translation: 因此，新的有机硅缩合反应，烷氧基硅烷或硅氧烷与有机氢硅烷或硅氧烷之间的缩合以及催化剂被描述和要求保护。

公开(公告)号：WO2004060962A1

公开(公告)日：2004-07-22

申请号：PCT/US2003/039139

申请日：2003-12-10

Applicant: GENERAL ELECTRIC COMPANY ,  MCCLOSKEY, Patrick, Joseph ,  LENS, Jan, Pleun ,  CELLA, James, Anthony ,  KAMPS, Jan, Henk ,  LONGLEY, Kathryn, Lynn ,  RAMESH, Narayan ,  REILLY, Warren, William ,  SMIGELSKI, Paul, Michael, Jr. ,  WISNUDEL, Marc, Brian

Inventor： MCCLOSKEY, Patrick, Joseph ,  LENS, Jan, Pleun ,  CELLA, James, Anthony ,  KAMPS, Jan, Henk ,  LONGLEY, Kathryn, Lynn ,  RAMESH, Narayan ,  REILLY, Warren, William ,  SMIGELSKI, Paul, Michael, Jr. ,  WISNUDEL, Marc, Brian

IPC: C08G64/00

CPC classification number: C08G63/64 ,  C08G64/04 ,  C08G64/14 ,  C08G64/307 ,  C08L23/00 ,  C08L67/00 ,  C08L69/00 ,  C08L69/005 ,  C08L2666/18 ,  C08L2666/06

Abstract: Polycarbonates containing low or undetectable levels of Fries rearrangement products and comprising repeat units derived from one or more of resorcinol, hydroquinone, methylhydroquinone, bisphenol A, and 4,4’-biphenol have been prepared by the melt reacti on of one or more of the aforementioned dihydroxy aromatic compounds with an ester-substituted diaryl carbonate such as bis-methyl salicyl carbonate. Low, or in many instances undetectable, levels of Fries rearrangement products are found in the product polycarbonates obtained as the combined result of a highly effective catalyst system which suppresses the Fries reaction and the use of lower melt polymerization temperatures relative to temperatures required for the analogous polymerization reactions using diphenyl carbonate.

Abstract translation: 含有低或不可检测水平的弗里斯重排产物并且包含衍生自间苯二酚，氢醌，甲基氢醌，双酚A和4,4'-联苯酚中的一种或多种的重复单元的聚碳酸酯已经通过熔融反应在一种或多种 上述具有酯取代的二芳基碳酸酯的二羟基芳族化合物，例如碳酸双甲基水杨酸酯。 低产量或在许多情况下，不可检测的是，在由高效催化剂体系获得的产品聚碳酸酯中发现了油炸产品重排产物的水平，该催化剂体系抑制了Fries反应，并且相对于类似物所需的温度使用较低的熔体聚合温度 使用碳酸二苯酯进行聚合反应。

公开(公告)号：WO2010123692A1

公开(公告)日：2010-10-28

申请号：PCT/US2010/030390

申请日：2010-04-08

Applicant: GENERAL ELECTRIC COMPANY ,  KONICA MINOLTA HOLDINGS, INC. ,  YE, Qing ,  LIU, Jie ,  CELLA, James, Anthony ,  KATOH, Eisaku

Inventor： YE, Qing ,  LIU, Jie ,  CELLA, James, Anthony ,  KATOH, Eisaku

IPC: C09K11/06 ,  H05B33/14

CPC classification number: H05B33/14 ,  C09K11/06 ,  C09K2211/1022 ,  C09K2211/1029 ,  C09K2211/1033

Abstract: An optoelectronic device comprises a cathode; an electron-transporting layer comprising a compound of formula I; formula I a light emitting-layer, and an anode; wherein R1 and R2 are independently at each occurrence, hydrogen, a C rC2U aliphatic radical a CyC2U aromatic radical or a d~ C-JO cycloaliphatic radical; R3 is H or alky]; a and b are, independently at each occurrence 0, or an integer ranging from 1 to 3; n is 2 or 3; and Ar is an aryl.

Abstract translation: 光电器件包括阴极; 包含式I化合物的电子传输层; 式I为发光层和阳极; 其中R 1和R 2在每次出现时独立地为氢，C 1 -C 20脂族基团，CyC 2 U芳族基团或d〜C-JO脂环族基团; R3为H或烷基]; a和b各自独立地为0或1至3的整数; n为2或3; 并且Ar是芳基。

公开(公告)号：WO2010065515A1

公开(公告)日：2010-06-10

申请号：PCT/US2009/066215

申请日：2009-12-01

Applicant: GENERAL ELECTRIC COMPANY ,  KONICA MINOLTA HOLDINGS, INC. ,  YE, Qing ,  CELLA, James, Anthony ,  KATOH, Eisaku ,  LIU, Jie

Inventor： YE, Qing ,  CELLA, James, Anthony ,  KATOH, Eisaku ,  LIU, Jie

IPC: C08F12/26 ,  C08F12/28

CPC classification number: C08F12/26 ,  C08F12/32 ,  C08F112/14 ,  H01L51/0003 ,  H01L51/004 ,  H01L51/0042 ,  H01L51/5012

Abstract: The invention relates to polymers useful in optoelectronic devices and comprising structural unit of formula (I), wherein R 1 and R 2 are independently at each occurrence, hydrogen, a C 1 -C 20 aliphatic radical, a C 3 -C 20 aromatic radical, or a C 3 -C 20 cycloaliphatic radical; R 3 is H or alkyl; a and b are, independently at each occurrence 0, or an integer ranging from 1 to 3; and Ar is a direct bond or aryl.

Abstract translation: 本发明涉及可用于光电子器件的聚合物，其包含式（I）的结构单元，其中R 1和R 2在每次出现时独立地为氢，C 1 -C 20脂族基，C 3 -C 20芳族基或C 3 -C 20 脂环族基团 R3是H或烷基; a和b各自独立地为0或1至3的整数; 并且Ar是直接键或芳基。

公开(公告)号：WO2008076569A1

公开(公告)日：2008-06-26

申请号：PCT/US2007/084912

申请日：2007-11-16

Applicant: GENERAL ELECTRIC COMPANY ,  YE, Qing ,  LIU, Jie ,  CELLA, James, Anthony ,  LITZ, Kyle, Erik ,  SHIANG, Joseph, John

Inventor： YE, Qing ,  LIU, Jie ,  CELLA, James, Anthony ,  LITZ, Kyle, Erik ,  SHIANG, Joseph, John

IPC: C07D209/88 ,  C08G63/19 ,  C08G75/20 ,  H01L27/32

CPC classification number: C07D209/88 ,  C08G63/6854 ,  C08G64/12 ,  C08G73/1046 ,  C08G73/1085 ,  H01L51/0035 ,  H01L51/0037 ,  H01L51/0072 ,  H01L51/0085 ,  H01L51/5012 ,  Y10T428/31507 ,  Y10T428/31721 ,  Y10T428/31786

Abstract: The invention relates to compounds of formula I wherein R 1 , R 2 , and R 4 are independently at each occurrence a C 1 -C 20 aliphatic radical, a C 3 - C 20 aromatic radical, or a C 3 -C 20 cycloaliphatic radical; R 3 and R 5 are independently at each occurrence hydrogen, a C 1 -C 20 aliphatic radical, a C 3 -C 20 aromatic radical, or a C 3 -C 20 cycloaliphatic radical; and a, b and d are independently 0 or an integer ranging from 1 to 3. The invention further relates to polymers derived from compounds of formula I. The polymers may be polyesters, polyethers, polycarbonates, polyestercarbonates, polyetherketones, or polyethersulfones. Compounds and polymers of the invention find use in light emitting devices.

Abstract translation: 本发明涉及式I化合物，其中R 1，R 2，R 4和R 4各自独立地为C 1 C 20 -C 20脂肪族基团，C 3 -C 20芳族基团或C 3 H 3 -C 20脂环族基团; R 3和R 5在每次出现时独立地为氢，C 1 -C 20脂族基团， C 3 -C 20芳族基团或C 3 -C 20脂环族基团; C 3 -C 20芳族基团或C 3 -C 20 -C 20脂环族基团; 并且a，b和d独立地为0或1至3的整数。本发明还涉及衍生自式I化合物的聚合物。聚合物可以是聚酯，聚醚，聚碳酸酯，聚酯碳酸酯，聚醚酮或聚醚砜。 本发明的化合物和聚合物可用于发光器件中。

公开(公告)号：WO2007109518A3

公开(公告)日：2008-01-24

申请号：PCT/US2007064126

申请日：2007-03-16

Applicant: GEN ELECTRIC ,  CELLA JAMES ANTHONY ,  LEWIS LARRY NEIL

Inventor： CELLA JAMES ANTHONY ,  LEWIS LARRY NEIL

IPC: C07C25/18 ,  C07C25/24 ,  C08G61/10 ,  C08G77/04

CPC classification number: C08G77/38 ,  C08G61/02 ,  C08G77/42 ,  C09K11/06 ,  C09K2211/1416 ,  H01L51/0039 ,  H01L51/0094 ,  H01L51/5012 ,  H05B33/14

Abstract: Optoelectronic devices include a polymer composition derived from reaction between a hydrosiloxane and a polyfluorene comprising structural units of formula (I) wherein R 1 and R 2 are independently alkyl, substituted alkyl, alkenyl, alkynyl, substituted alkenyl, substituted alkynyl, alkyloxy, substituted alkoxy, alkenoxy, alkynoxy, substituted alkenoxy, substituted alkynoxy, or a combination thereof; Ar 1 and Ar 2 are independently aryl or substituted aryl; m and n are independently 0 or 1 ; and at least one of R 1 and R 2 is alkenyl, alkynyl, substituted alkenyl, or substituted alkynyl.

Abstract translation: 光电子器件包括衍生自包含式（I）的结构单元的氢硅氧烷和聚芴之间的反应的聚合物组合物，其中R 1和R 2独立地是烷基，取代的烷基， 烯基，炔基，取代的烯基，取代的炔基，烷氧基，取代的烷氧基，烯氧基，炔氧基，取代的烯氧基，取代的炔氧基或其组合; Ar 1和Ar 2独立地是芳基或取代的芳基; m和n独立地为0或1; 并且R 1和R 2中的至少一个是烯基，炔基，取代的烯基或取代的炔基。