公开(公告)号：WO1998024400A3

公开(公告)日：1998-06-11

申请号：PCT/EP1997006764

申请日：1997-12-03

Applicant: BASF AKTIENGESELLSCHAFT ,  SPERLING, Karin ,  POTTHOFF-KARL, Birgit ,  GREINDL, Thomas

Inventor： BASF AKTIENGESELLSCHAFT

IPC: A61K07/48

公开(公告)号：WO9824400A2

公开(公告)日：1998-06-11

申请号：PCT/EP9706764

申请日：1997-12-03

Applicant: BASF AG ,  SPERLING KARIN ,  POTTHOFF KARL BIRGIT ,  GREINDL THOMAS

Inventor： SPERLING KARIN ,  POTTHOFF-KARL BIRGIT ,  GREINDL THOMAS

IPC: A61K8/44 ,  A61Q5/02 ,  A61Q5/06 ,  A61Q5/12 ,  A61Q9/04 ,  A61Q17/04 ,  A61Q19/00 ,  A61Q19/10 ,  C09K15/20 ,  A61K7/00

CPC classification number: C09K15/20 ,  A61K8/44 ,  A61K2800/51 ,  A61Q5/02 ,  A61Q5/06 ,  A61Q5/12 ,  A61Q9/04 ,  A61Q17/04 ,  A61Q19/00 ,  A61Q19/10

Abstract: Disclosed is an active substance composition, specially a cosmetic agent, a light-screening agent or a vitamin composition, containing one or several compounds of formula (I), specially an active substance composition, containing as a compound of formula (I) ethylene diaminosuccinate (EDDS), ethylene diaminoglutamate (EDDG) or (2-hydroxy propylene)-1,3-diaminosuccinate (HPDDS). The invention also relates to the use of bis(dicarboxylic acid) diaminoalkylene derivatives of the above formula (I) as complexing agents for earth alkaline metal ions and heavy metal ions in active substance compositions, specially cosmetic agents, screening agents, vitamin compositions and for stabilizing oxidation-sensitive active substances.

Abstract translation: 描述了一种药物组合物，特别是化妆品，光稳定剂或包含式（I）的一种或多种化合物维生素组合物，特别是含有式（I）的化合物的药物组合物Ethylendiaminosuccinat（EDDS），Ethylendiaminoglutamat（EDDG）或（2- 羟基亚丙基）-1,3- diaminosuccinat（HPDDS）。 本发明还涉及使用上述式（I），作为碱土金属和在活性组合物中的重金属离子，特别是化妆品，防晒剂，维生素组合物的配位剂的双（二羧酸）二氨衍生物和稳定氧化敏感的活性成分。

公开(公告)号：WO1998002482A1

公开(公告)日：1998-01-22

申请号：PCT/EP1997003573

申请日：1997-07-07

Applicant: BASF AKTIENGESELLSCHAFT ,  STEUERLE, Ulrich ,  REUTHER, Wolfgang ,  MEIXNER, Hubert ,  EHLE, Michael ,  GREINDL, Thomas ,  BETZ, Rainer

Inventor： BASF AKTIENGESELLSCHAFT

IPC: C08G73/02

CPC classification number: C08G73/0213 ,  B01D53/02 ,  B01D2257/106 ,  B01J20/26 ,  C02F1/56 ,  C08L71/02 ,  C08L2666/20

Abstract: Method of manufacturing finely divided, water-insoluble polymers of aziridines by polymerization of aziridines, preferably ethylene-imine, in the presence of two or more functional groups containing cross-linking agents in one or more ethers, as well as modified, water-insoluble polymers of aziridines that can be obtained by reacting finely divided, water-insoluble cross-linked polymers of aziridines in an aqueous medium with carbon disulphide or with formaldehyde and a nucleophilic agent from the group comprising alkali-metal cyanides, primary amines, secondary amines, alkali-metal sulphites, and alkali-metal phosphites, and the use of the modified and unmodified finely divided, water-insoluble polymers for immobilizing active ingredients, as absorbents for aldehydes, ketones and acids, for removing heavy-metal ions from liquid effluents, and for removing ozone and/or sour gases from air or inert gases.

Abstract translation: 一种用于通过聚合氮丙啶，优选乙烯亚胺，含有至少两个官能团中的至少一种醚存在交联剂和氮丙啶的改性，水不溶性聚合物，其通过的细碎反应可获得的制备氮丙啶的细碎水不溶性聚合物的过程中，不溶于水的，交联 在水性介质中的氮丙啶的聚合物，用二硫化碳或与甲醛和选自碱金属氰化物，伯胺，仲胺，碱金属亚硫酸盐和碱金属亚磷酸盐和使用经修饰的和未修饰的微粒的组成的组中的亲核剂，用于固定活性化合物，作为吸收剂用于水不溶性聚合物 醛，酮和酸，一种从废水中除去重金属离子的和用于除去臭氧和/或从空气或惰性气体的酸性气体。

公开(公告)号：WO1997031037A1

公开(公告)日：1997-08-28

申请号：PCT/EP1997000849

申请日：1997-02-21

Applicant: BASF AKTIENGESELLSCHAFT ,  JULIUS, Manfred ,  ETTL, Roland ,  GÜNTHER, Wolfgang ,  GREINDL, Thomas

Inventor： BASF AKTIENGESELLSCHAFT

IPC: C08F08/32

CPC classification number: C10M149/12 ,  C07C235/88 ,  C07C255/25 ,  C08F8/30 ,  C10L1/143 ,  C10L1/1985 ,  C10L1/22 ,  C10L1/224 ,  C10L1/2286 ,  C10L1/231 ,  C10L1/232 ,  C10L1/233 ,  C10L1/238 ,  C10L1/2383 ,  C10L1/2387 ,  C10L10/06 ,  C10L10/08 ,  C10M133/16 ,  C10M133/52 ,  C10M133/54 ,  C10M2215/04 ,  C10M2215/042 ,  C10M2215/08 ,  C10M2215/082 ,  C10M2215/16 ,  C10M2215/26 ,  C10M2215/28 ,  C10M2217/046 ,  C10M2217/06 ,  C10N2270/02 ,  C08F10/00

Abstract: The invention relates to fuel and lubricant additives of the formula (I) in which n is 0 or 1, Z is straight or branched-chain polyalkyl radical with a mean molecular weight of 150 to 40000, Y is a radical of the formula (IIa) or (IIb) in which R, R and R are the same or different and are selected from among a hydrogen atom, possibly substituted alkyl, alkenyl, alkinyl radicals and possibly substituted cycloalkyl, aryl or arylalkyl radicals, which may have one or more hetero atoms and A is a possibly substituted alkylene imine radical, or if n is 0, one of the radicals Y may be a polyoxy alkyl radical; and a process for their production, fuels and lubricants and additive mixtures containing these compounds.

Abstract translation: 本发明涉及通式（I）其中n是0或1的燃料和润滑油添加剂; Z是直链或具有约150-40000团的数均分子量的支链的聚烷基基团; Y是下式基团（IIa）或（IIb）中，其中R，R <1>和R <2>是相同的或不同的，选自氢原子，任选取代的烷基，烯基，炔基被选择，和任选地 取代的环烷基，芳基或芳烷基，任选地具有一个或多个杂原子，且A为任选取代的亚烷基亚胺基团; 或当n是0，基团中的一个，Y是聚氧化烯基团任选地; 和它们的制备，燃料和润滑剂，过程和与添加剂含有这些化合物的混合物。

公开(公告)号：WO1996004332A1

公开(公告)日：1996-02-15

申请号：PCT/EP1995002891

申请日：1995-07-21

Applicant: BASF AKTIENGESELLSCHAFT ,  GREINDL, Thomas ,  KAPPES, Elisabeth ,  OFTRING, Alfred ,  KUD, Alexander ,  BAUR, Richard ,  KRONER, Matthias

Inventor： BASF AKTIENGESELLSCHAFT

IPC: C08G85/00

CPC classification number: C08G73/10 ,  C08G63/91 ,  C08G69/48 ,  C08G73/02 ,  C08G73/1092 ,  C11D3/3703 ,  C11D3/3719 ,  C11D3/3769

Abstract: A process is disclosed for preparing polymers with hydroxamic acid, hydroxamic acid ether and/or hydrazide groups in the side chain, by reacting (a) polymers which contain ester, amide, imide and/or acetal groups in the main chain and carboxyl, ester, imide, amide and/or anhydride groups and/or halogen as side chain, or a polysuccinimide with (b) hydroxylamine, hydroxylamine alkyl ethers with 1 to 18 C atoms in the alkyl group, N-monoalkylhydroxylamines with 1 to 18 C atoms in the alkyl group and/or in salts of said compounds and/or (c) hydrazine and/or hydrazine salts in an aqueous medium or alcohols at pH values of at least 7. Also disclosed is the use of the thus obtained modified polymers as additives to washing and cleaning agents, as complexing agents for alkaline earth and heavy metal ions, as pigment dispersants and as scale inhibitors.

Abstract translation: 过程为，Hydroxamsäureether-和/或酰肼基团，通过在聚合物主链的酯，酰胺，酰亚胺和/或缩醛基团作为侧链和羧基的（a）的聚合物的反应制备含异羟肟酸在侧链聚合物 ，酯，酰亚胺，酰胺和/或酸酐和/或卤素，或聚琥珀酰亚胺与（b）具有在烷基中1至18个碳原子的羟胺，羟胺烷基醚，N-Monoalkylhydroxylaminen 1〜18 C- 烷基中的原子和/或盐所述化合物和/或（c）的肼和/或在水介质或在7的pH值醇类肼盐，并使用由此获得的改性聚合物作为添加剂洗涤剂和 洗涤剂，如络合为碱土金属和重金属离子剂，作为分散剂用于颜料和作为阻垢剂。

公开(公告)号：WO1997040088A1

公开(公告)日：1997-10-30

申请号：PCT/EP1997002062

申请日：1997-04-23

Applicant: BASF AKTIENGESELLSCHAFT ,  STEUERLE, Ulrich ,  REUTHER, Wolfgang ,  MEIXNER, Hubert ,  EHLE, Michael ,  GREINDL, Thomas ,  BETZ, Rainer

Inventor： BASF AKTIENGESELLSCHAFT

IPC: C08G73/02

CPC classification number: C08G73/0213 ,  B01J20/267 ,  C02F1/56 ,  C08G73/022 ,  Y10S210/912

Abstract: A process is disclosed for producing finely divided, water-insoluble aziridine polymers by polymerisation of aziridines, preferably ethylene imine, in the presence of cross-linking agents which contain at least two functional groups in at least one ether. Also disclosed are modified, water-insoluble aziridine polymers obtained by reacting finely divided, water-insoluble, cross-linked aziridine polymers in an aqueous medium with carbon bisulphide or formaldehyde and a nucleophilic agent from the group of the alkaline metal cyanides, primary amines, secondary amines, alkaline metal sulphites and alkaline metal phosphites. The invention also relates to the use of the modified and non-modified, finely divided, water-insoluble polymers for immobilising active substances, as absorbing agent for aldehydes, ketones and acids and for removing heavy metal ions from waste water.

Abstract translation: 一种用于通过聚合氮丙啶，优选乙烯亚胺，含有至少两个官能团中的至少一种醚存在交联剂和氮丙啶的改性，水不溶性聚合物，其通过的细碎反应可获得的制备氮丙啶的细碎水不溶性聚合物的过程中，不溶于水的，交联 在水性介质中的氮丙啶的聚合物，用二硫化碳或与甲醛和选自碱金属氰化物，伯胺，仲胺，碱金属亚硫酸盐和碱金属亚磷酸盐和使用经修饰的和未修饰的微粒的组成的组中的亲核剂，用于固定活性化合物，作为吸收剂用于水不溶性聚合物 醛，酮和酸，以及用于从废水中去除重金属离子。

公开(公告)号：WO1997019159A1

公开(公告)日：1997-05-29

申请号：PCT/EP1996004817

申请日：1996-11-05

Applicant: BASF AKTIENGESELLSCHAFT ,  POTTHOFF-KARL, Birgit ,  EHLE, Beate ,  FUNHOFF, Angelika ,  KIESSLING, Dieter ,  BAUR, Richard ,  GREINDL, Thomas

Inventor： BASF AKTIENGESELLSCHAFT

IPC: C11D03/33

CPC classification number: C11D1/94 ,  C11D1/10 ,  C11D1/146 ,  C11D1/22 ,  C11D1/29 ,  C11D1/72 ,  C11D1/88 ,  C11D3/06 ,  C11D3/08 ,  C11D3/10 ,  C11D3/128 ,  C11D3/33

Abstract: Proposed is a solid washing-agent formulation for textiles, the formulation containing: (A) 1 to 60 % by wt. of inorganic builders made from crystalline or amorphous aluminosilicates, crystalline or amorphous silicates, carbonates and/or phosphates, (B) 0.1 to 25 % by wt. of one or more glycine-N,N-diacetic acid derivatives (I), in which R is an organic group and M is hydrogen or a cation, used as organic co-builders, (C) 1 to 40 % by wt. of anionic surfactants and (D) 0.5 to 30 % by wt. of non-ionic surfactants.

Abstract translation: 一种固体织物洗涤剂制剂，其包含（A）1〜60的助洗剂基于结晶或无定形铝硅酸盐，结晶或无定形硅酸盐，碳酸盐和/或磷酸盐重量的无机％; （B）0.1〜25重量％的一种或多种甘氨酸-N，（I）其中R是有机基，M是氢或阳离子，如有机增洁剂的式N-二乙酸衍生物; （C）1〜40重量％的阴离子表面活性剂和（D）0.5〜30重量％的非离子表面活性剂。

公开(公告)号：WO1995030681A1

公开(公告)日：1995-11-16

申请号：PCT/EP1995001648

申请日：1995-05-02

Applicant: BASF AKTIENGESELLSCHAFT ,  MÜLLER, Reinhard ,  GREINDL, Thomas ,  OFTRING, Alfred ,  SCHERR, Günter ,  GESSNER, Thomas ,  TRIESELT, Wolfgang ,  POTTHOFF-KARL, Birgit ,  WEHLAGE, Thomas

Inventor： BASF AKTIENGESELLSCHAFT

IPC: C07F13/00

CPC classification number: B01J31/1815 ,  B01J31/1658 ,  B01J31/1805 ,  B01J31/2239 ,  B01J31/2243 ,  B01J2531/0216 ,  B01J2531/025 ,  B01J2531/16 ,  B01J2531/26 ,  B01J2531/72 ,  B01J2531/845 ,  C07F1/005 ,  C07F3/003 ,  C07F13/005 ,  C07F15/065 ,  C11D3/3932 ,  D06L4/12

Abstract: Single or multi-nuclear metal complexes [LnMmXp] Y, in which M is manganese in the oxidation number (II, III, IV, V and/or VI), copper in the oxidation number (I and/or II), cobalt in the oxidation number (II and/or III) or zinc in the oxidation number (II), X is a co-ordination or bridge group, Y is a counter-ion in the corresponding stoichiometric quantity for compensating a charge z, in which z may be positive, zero or negative as the charge of the metal complex, n and m are mutually independently whole numbers from 1 to 8, p is a whole number from 0 to 32 and L is certain nitrogen and/or oxygen atoms as co-ordination centres-containing organic molecules as ligands. The metal complexes (I) are suitable as bleaching and oxidation catalysts, especially in washing and cleaning agents and in textile and paper bleaching.

Abstract translation: 单或多核金属络合物（I）[LnMmXp] Y其中M是锰氧化态（II，III，IV，V和/或VI），铜在氧化态（I）和/或（II ），钴处于氧化态（II）和/或（III）或在氧化态（II）锌，X表示配位或桥连基，Y是在相应的化学计量量的抗衡离子以平衡现有电荷z，其中 Z可以是正作为电荷的金属络合物，零或负的，n和m独立地为整数1-8，p表示从0到32和L某些含氮和/或氧原子作为配位中心的整数 有机分子是作为配体。 金属配合物（I）适合作为漂白和氧化催化剂，尤其是在洗涤剂和清洁产品和在纺织和造纸漂白。

公开(公告)号：WO9910314A3

公开(公告)日：1999-07-01

申请号：PCT/EP9805220

申请日：1998-08-17

Applicant: BASF AG ,  RAHM RAINER ,  GREINDL THOMAS ,  OFTRING ALFRED ,  OETTER GUENTER ,  DETERING JUERGEN ,  BRAUN GEROLD

Inventor： RAHM RAINER ,  GREINDL THOMAS ,  OFTRING ALFRED ,  OETTER GUENTER ,  DETERING JUERGEN ,  BRAUN GEROLD

IPC: C07C229/08 ,  C07C229/16 ,  C07C253/00 ,  C07C255/25 ,  C07D233/72 ,  C07D233/74

CPC classification number: C07C229/08 ,  C07C229/16 ,  C07C253/00 ,  C07C255/25

Abstract: The invention relates to a method for producing compounds of general formula (IIb), wherein R represents C6-C30 alkyl or C6-C30 alkenyl which can also support up to 5 hydroxyl groups, formyl groups, C1-C4 alkoxy groups, phenoxy groups or C1-C4 alkoxycarbonyl groups as substituents and which can be interrupted by up to 5 non-adjacent oxygen atoms, or alkoxylate groupings of formula -(CH2)k-O-(A O)m-(A O)n - Y, wherein A and A represent 1,2 alkylene groups with 2 to 4 C-atoms, Y represents hydrogen, C1-C12 alkyl, phenyl, or C1-C4 alkoxycarbonyl, k represents the number 1, 2 or 3 and m and n each represent numbers from 0 to 50, the sum of m and n being at least 4, independently of each other. According to the inventive method, iminodiacetonitrile is reacted with aldehydes of general formula R-CHO and HCN or alkali cyanides. The method is carried out a) without using an organic solvent and in the presence of a Lewis or Bronsted acid, or b) with or without an organic solvent and in the presence of an emulsifier, or c) with or without an organic solvent and at a pressure of 1 to 40 bar.

Abstract translation: 在对通式（IIb）的化合物的制备方法，其中R是C6至C30的烷基或C6至C30链烯基，其还携带作为取代基的最多5个羟基，甲酰基，C1至C4烷氧基，苯氧基或C1 - 承载一个至C4烷氧基羰基和可被最多5个不相邻的氧原子，或下式的烷氧基化物基团被中断 - （CH 2）CO（A <1> O）间 - （甲<2> O）N - ÿ 是，表示其中A <1>和A <2>独立地表示1,2-亚烷基基团的碳原子数为2〜4，Y是氢，C 1至C 12表示烷基，苯基或C1-C4烷氧羰基并且k 数字1，2或3，且m和n各自为从0到50，其中m的+ n之和必须至少是4，亚氨基二乙腈与通式R-CHO的醛和HCN或碱金属氰化物反应，则 方法a），而不使用有机溶剂的和在路易斯存在 或布朗斯台德酸，或者b））的使用或不使用有机溶剂的和在1至40巴，使用或不使用有机溶剂的和在乳化剂，或c的存在的范围内的压力下进行。

公开(公告)号：WO1997040087A1

公开(公告)日：1997-10-30

申请号：PCT/EP1997002061

申请日：1997-04-23

Applicant: BASF AKTIENGESELLSCHAFT ,  GREINDL, Thomas ,  OFTRING, Alfred ,  BRAUN, Gerold ,  RAHM, Rainer ,  SCHNEIDER, Jürgen ,  SCHERR, Günter ,  SCHUHMACHER, Rudolf ,  LORENCAK, Primoz ,  MEIXNER, Hubert

Inventor： BASF AKTIENGESELLSCHAFT

IPC: C08G73/02

CPC classification number: C08G73/0213 ,  C07C227/02 ,  D21C5/027 ,  D21C9/1042 ,  D21H17/54 ,  Y02W30/648

Abstract: A process is disclosed for preparing water-soluble, carboxyalkylated, amino group-containing polymers by reacting water-soluble, amino group-containing polymers with at least one aldehyde and one alkaline cyanide or with a cyanhydrin from an aldehyde and an alkaline cyanide in an aqueous solution at temperatures from 60 to 110 DEG C. Also disclosed is the use of the carboxyalkylated polymers which contain amino groups and of the N-oxides derived therefrom as auxiliary agents for the production of paper, as additives of washing and cleaning agents and as complexing agents during wood pulp bleaching, cellulose bleaching, cellulose production and de-inking of used printed paper.

Abstract translation: 一种用于通过水溶性反应制备水溶性羧基烷基化的，含氨基的聚合物的方法，具有至少一种醛和碱金属氰化物或醛的氰醇，并在温度水溶液中的碱金属氰化物为60〜110℃，使用的聚合物含有氨基的羧基烷基化 含氨基的聚合物，以及衍生的N-氧化物，如生产纸加工助剂，作为添加剂洗涤剂和清洗剂和如在木浆漂白络合剂，纸浆漂白，纸浆生产和印刷废纸的脱墨。