NITROGEN POLYMER AND ITS PRODUCTION

    公开(公告)号:JPH1143315A

    公开(公告)日:1999-02-16

    申请号:JP21597897

    申请日:1997-07-25

    Abstract: PROBLEM TO BE SOLVED: To obtain a clean energy by forming a nitrogen polymer by degrading- nitrogen-containing group by applying an energy to a nitrogen-containing compound. SOLUTION: This nitrogen polymer of the formula, Nn [(n) is 4-15] such as N5 and N10 is obtained by irradiating an energy source such as discharge, heat or light, preferably high power pulse ultraviolet rays to an azide compound and a diazo compound containing a nitrogen-containing group such as azide group and diazo group capable of releasing a nitrogen component having high reactivity by degradation to degrade the nitrogen-containing group, and to release the highly reactive nitrogen component such as nitrogen radical, azide cation and azide anion. The nitrogen-containing compound used as the raw material for producing the nitrogen polymer is the one in a solid state at a normal temperature, preferably having >=80 deg.C melting point, and the proportion of the nitrogen in the molecule is >=50 atomic %. The nitrogen-containing compound having >=50 atomic % nitrogen content is exemplified by an azide compound of formula I (nitrogen content is 80 atomic %), formula II (nitrogen content is 78 atomic %) or the formula, AgN3 (nitrogen content is 75 atomic %) and preferably the azide compound comprising two elements of N and C.

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