Abstract:
Methods of making and resultant compositions thereof, which include a gas generant having a coating including an inorganic combustion inhibitor. Such coated gas generants are useful in pyrotechnic compositions and ignition materials, and may be employed, for example, in inflatable restraint systems. The ratio of coated and uncoated gas generant bodies within an airbag inflator may be tailored to provide S-curve inflation performance. Spray application of aqueous mixture including the combustion inhibitor onto the gas generant body provides a rapid way to achieve a thin but robust coating.
Abstract:
Compositions and methods relate to gas generants used in inflatable restraint systems. The gas generant grains include a fuel mixture having at least one fuel and at least one oxidizer, which have a burn rate that is susceptible to pressure sensitivity during combustion. The gas generant composition further includes a plurality of pressure sensitivity modifying glass fiber particles distributed therein to lessen the pressure sensitivity and/or to increase combustion stability of the gas generant. Such gas generants can be formed via spray drying techniques.
Abstract:
Methods and systems of providing a source of hydrogen and oxygen with high volumetric energy density, as well as a power systems useful in non-air breathing engines such as those in, for example, submersible vehicles, is disclosed. A hydride reactor may be utilized in forming hydrogen from a metal hydride and a peroxide reactor may be utilized in forming oxygen from hydrogen peroxide. The high temperature hydrogen and oxygen may be converted to water using a solid oxide fuel cell, which serves as a power source. The power generation system may have an increased energy density in comparison to conventional batteries. Heat produced by exothermic reactions in the hydride reactor and the peroxide reactor may be transferred and utilized in other aspects of the power generation system. High temperature water produced during by the peroxide reactor may be used to fuel the hydride reactor.
Abstract:
Compositions and methods relating to gas generants used in inflatable restraint systems. The gas generant grains formed via spray drying techniques of the present disclosure provide superior performance, including high burn rates and high gas yields. Further, processing of the gas generant grain products can be streamlined. Such gas generants include by way of non-limiting example, guanidine nitrate, basic copper nitrate, and a secondary oxidizer, such as potassium perchlorate.
Abstract:
A fundamental component of COMP B, (i.e)., the trinitrotoluene (TNT) melt-cast, is replaced with one or more mononitro-substituted arenes or dinitro-substituted arenes, such as dinitronanisole, to permit melt casting without presenting the toxicity drawbacks experienced with the use of TNT. Also included in the COMP B replacement formulation are coarse oxidizer particles and thermal stabilizers. Exemplary thermal stabilizers are alkylnitroanilines and arylnitroanilines. The thermal stabilizer combines with the melt-cast binder to lower the overall melting temperature of the melt-cast composition, preferably into a range of from 80 °C to 90 °C, while raising the autoignition temperature of the composition. In one preferred embodiment, the high impact and shock sensitivity commonly associated with melt-cast explosives such as COMP B is mitigated by providing at least a portion of the energetic filler (e.g., RDX) in a fine powder form.
Abstract:
An inflator that includes a quantity of gas generant housed within a chamber. A liquid including at least one of a fuel soluble in the liquid or an oxidizer soluble in the liquid and a piston are housed within another chamber of the inflator. This chamber is sealed. Upon actuation, movement of the piston hydraulically expels the liquid through an opening in the piston such that the liquid contacts the gas formed by combustion of the gas generant and cools the same. The fuel and/or oxidizer in the liquid can react to form additional gas.
Abstract:
A gas generating eject motor (10) includes a case (12) containing an ignitable low temperature gas generant material (24) that does not produce toxic gases upon the combustion thereof. The gas generant material is generally contained with a screen enclosure (26, 30) housed within the case. An igniter (70) is disposed within the gas generant material for selectively igniting the gas generant to thereby generate combustion gases. A nozzle (40) is disposed within an open aft end of the case for focusing and directing the combustion gases generated by the ignited gas generant material. The case is constructed and arranged to be separaly attached to the aft end of a rocket (90) to be launched from a launch platform (80), so that, upon ignition of the gas generant, the combustion gases focused by the nozzle will apply a thrust to the rocket and thereby propel, or eject, the rocket from the launch platform, at which time the combustible propellant of the rocket motor will ignite and the eject motor will be separated from the rocket.
Abstract:
Igniter compositions comprising strontium nitrate, an al/mg alloy and a gas-producing fuel component and methods of processing are provided which produce or result in relatively little particulate material, as compared to typical igniter compositions used in association with vehicle occupant restraint airbag cushions.
Abstract:
Gas generating compositions and methods for their use are provided. Metal complexes are used as gas generating compositions. These complexes are comprised of a metal cation template, a neutral ligand containing hydrogen and nitrogen, sufficient oxidizing anion to balance the charge of the complex, and at least one cool burning organic nitrogen-containing compound. The complexes are formulated such that when the complex combusts, nitrogen gas and water vapor is produced. Specific examples of such complexes include metal nitrite amine, metal nitrate amine, and metal perchlorate amine complexes, as well as hydrazine complexes. A binder and co-oxidizer can be combined with the metal complexes to improve crush strength of the gas generating compositions and to permit efficient combustion of the binder. Such gas generating compositions are adaptable for use in gas generating devices such as automobile air bags.
Abstract:
Compositions and methods relating to gas generants used in inflatable restraint systems. The gas generant grains formed via spray drying techniques of the present disclosure provide superior performance, including high burn rates and high gas yields. Further, processing of the gas generant grain products can be streamlined. Such gas generants include by way of non-limiting example, guanidine nitrate, basic copper nitrate, and a secondary oxidizer, such as potassium perchlorate.