Abstract:
A process is described for the separation of C 5 hydrocarbons present, in a quantity ranging from 0.2 to 20 % by weight, in streams prevalently containing C 4 products used for the production of high-octane hydrocarbon compounds, by the selective dimerization of isobutene, characterized in that the dimerization reaction is carried out in the presence of linear and branched alcohols and alkyl ethers in a quantity which is such as to have a molar ratio alcohols/alkyl ethers/isobutene in the feeding higher than 0.01.
Abstract translation:描述了用于分离存在的C 5 -C 5烃的方法,其量为0.2至20重量%,流体中普遍含有用于生产的C 4 S 3产物 的高辛烷烃化合物,通过选择性二聚异丁烯,其特征在于二聚反应在直链和支链醇和烷基醚的存在下进行,其量可以使醇/烷基醚的摩尔比 /异丁烯在饲料中高于0.01。
Abstract:
Process for the conversion of heavy feedstocks selected from heavy crude oils, distillation residues, heavy oils coming from catalytic treatment, thermal tars, oil sand bitumens, various kinds of coals and other high-boiling feedstocks of a hydrocarbon origin known as black oils, by the combined use of the following three process units: hydroconversion with catalysts in slurry phase (HT), distillation or flash (D), deasphalting (SDA), comprising the following steps: . mixing at least part of the heavy feedstock and/or at least most of the stream containing asphaltenes obtained in the deasphalting unit with a suitable hydrogenation catalyst and sending the mixture obtained to a hydrotreatment reactor (HT) into which hydrogen or a mixture of hydrogen and H2S is charged; . sending the stream containing the hydrotreatment reaction product and the catalyst in dispersed phase to one or more distillation or flash steps (D) whereby the different fractions coming from the hydrotreatment reaction are separated; . recycling at least part of the distillation residue (tar) or liquid leaving the flash unit, containing the catalyst in dispersed phase, rich in metal sulfides produced by demetallation of the feedstock and possibly coke, to the deasphalting zone (SDA) in the presence of solvents, optionally also fed with at least a fraction of the heavy feedstock, obtaining two streams, one consisting of deasphalted oil (DAO) and the other containing asphaltenes, characterized in that a fraction of the stream containing as phaltenes, coming from the deasphalting section (SDA), called flushing stream, is sent to a treatment section with a suitable solvent for the separation of the product into a solid fraction and a liquid fraction from which said solvent can be subsequently removed.
Abstract:
Process for the catalytic dehydrogenation of alkylaromatic hydrocarbons optionally mixed with ethane which comprises: A) dehydrogenating the hydrocarbon stream, optionally mixed with an inert gas, in a fluid bed reactor in the presence of a catalytic composition based on gallium and manganese supported on alumina modified with silica, at a temperature ranging from 400 to 700°C, at a total pressure ranging from 0.1 to 3 ata and with a GHSV (Gas Hourly Space Velocity) ranging from 50 to 10,000 h ; and B) regenerating and heating the catalyst, by means of the catalytic oxidation of a fuel, in a fluid bed regenerator at a temperature higher than 400°C.
Abstract:
An enhanced process is described for the synthesis of urea from ammonia and carbon dioxide, at a high pressure and temperature, with the formation of ammonium carbamate as intermediate, which includes a high pressure synthesis section, comprising at least one separation step by decomposition-stripping with ammonia of the non-converted ammonium carbamate, carried out in a vertical apparatus, commonly called stripper, characterized in that said step also comprises a feeding, in the lower part of said stripper, of a stream of CO 2 , heated to a temperature ranging from 130 to 230°C, in a quantity of 1 to 15% by weight with respect to the total weight of the fresh CO 2 fed to the process, containing a passivating agent in such a quantity that its equivalent content of O 2 in moles varies from 0.05% to 0.80% with respect to the moles of CO 2 of said stream.
Abstract:
Reactor-regenerator device, comprising at least one reactor for catalytic dehydrogenation reactions of hydrocarbons and at least one regenerator of the catalyst o the "fast riser" type wherein the regenerator-riser is a substantially tubular apparatus for chemical reactions which comprise a gaseous phase in close contact with a solid phase, wherein gas phase and solid particles move upwards in cocurrent flow.
Abstract:
The present invention relates to the use of a silicon-based porous catalytic system for oligomerising light olefins said porous silicon-based catalytic system having an average pore diameter of between about 1 nm and about 5 nm and an acidity level of between about 150 µmol/g and about 650 µmol/g, and prepared from at least one hydrolysable silicon-based compound, or other source of silicon, and at least one non-ionic surface active agent.The invention also relates to a process for oligomerising light olefins using said silicon-based porous catalytic system, and to certain silicon-based porous catalytic systems.
Abstract:
The present invention relates to the use of a silicon-based porous catalytic system for oligomerising light olefins said porous silicon-based catalytic system having an average pore diameter of between about 1 nm and about 5 nm and an acidity level of between about 150 µmol/g and about 650 µmol/g, and prepared from at least one hydrolysable silicon-based compound, or other source of silicon, and at least one non-ionic surface active agent.The invention also relates to a process for oligomerising light olefins using said silicon-based porous catalytic system, and to certain silicon-based porous catalytic systems.
Abstract:
A process is disclosed for improving the oxidative resistance of amorphous carbon or graphite articles. The process comprises applying a solution of water; an oxide or hydroxide of a group 2 metal; a member of the group consisting of nitric acid; sodium nitrite and sodium carbonate; and boric acid or sodium tetraborate.
Abstract:
New complexes of saline type, which are represented by the formula: (Me Lm L''n Aa) Xx WHEREIN, Me represents Rh, Ir, Ru, Pd or Pt; L, L'' represent primary or secondary olefin, linear, branched or cyclic, having from 2 to 12 carbon atoms, and may be substituted by functional unsaturated compounds such as unsaturated nitriles; A is a neutral ligand such as a nitrile, phosphine, phosphite, arsine or stibine; X is an anion such as BF4 , PF6 , ClO4 or NO3 ; m + n equals 1, 2 or 3; a is 0, 1, 2 or 3; and x is 1 or 2, are useful as catalysts in olefin reactions such as the hydrogenation of olefins at 50*-80* C., in the oligomerization or dimerization or codimerization of olefins and in the hydration of olefins by reaction with water in alcohol solvents.