公开(公告)号：WO2005123783A1

公开(公告)日：2005-12-29

申请号：PCT/EP2005/005966

申请日：2005-06-01

Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  VINCENZI, Paolo ,  SPOTO, Rosa

Inventor： VINCENZI, Paolo ,  SPOTO, Rosa

IPC: C08F4/02

CPC classification number: C08F10/00 ,  C08F110/02 ,  Y10T428/2982 ,  C08F4/6543 ,  C08F4/6567 ,  C08F4/6555 ,  C08F2500/12 ,  C08F2500/24 ,  C08F2500/18

Abstract: Process for the preparation of a solid catalyst component for the polymerization of olefins, the process comprising the steps of­: - continuously contacting solid particles of a MgCl 2 .mROH adduct, wherein 0.5 2 .nROH, wherein n is lower than m; - reacting the slurry from step a) with one or more titanium compounds of formula Ti(OR) p X q-p , wherein q=3-4 and p=0-q, X is an halogen and R is an alkyl, cicloalkyl or aryl radical having 1-18 carbon atoms.

Abstract translation: 用于制备用于烯烃聚合的固体催化剂组分的方法，该方法包括以下步骤： - 连续接触MgCl 2 .mOH加合物的固体颗粒，其中0.5 <6.0，R是烷基，环烷基或芳基 具有1-12个碳原子，液相包含一种或多种能够与所述加合物的-OH基反应的化合物，以获得含有MgCl 2·nROH的浆料，其中n低于m; 使来自步骤a）的浆料与一种或多种式Ti（OR）pXq-p的钛化合物反应，其中q = 3-4且p = 0-q，X为卤素，R为烷基，环烷基或芳基 具有1-18个碳原子的基团。

公开(公告)号：WO2004106388A3

公开(公告)日：2005-05-12

申请号：PCT/EP2004005186

申请日：2004-05-07

Applicant: BASELL POLIOLEFINE SPA ,  MORINI GIAMPIERO ,  DALL OCCO TIZIANO ,  PIEMONTESI FABRIZIO ,  SPOTO ROSA ,  VINCENZI PAOLO ,  VITALE GIANNI

Inventor： MORINI GIAMPIERO ,  DALL OCCO TIZIANO ,  PIEMONTESI FABRIZIO ,  SPOTO ROSA ,  VINCENZI PAOLO ,  VITALE GIANNI

IPC: C08F4/636 ,  C08F4/649 ,  C08F4/651 ,  C08F4/654 ,  C08F10/00 ,  C08F210/16

CPC classification number: C08F10/00 ,  C08F210/16 ,  C08F4/6367 ,  C08F4/651 ,  C08F210/08 ,  C08F2500/12 ,  C08F4/6555 ,  C08F4/6492 ,  C08F4/6545 ,  C08F4/6565

Abstract: A process for preparing a catalyst component, comprising a Mg compound a Ti compound and an electron donor compound (ED) selected from alcohol, glycols, esters, ketones, amines, amides, nitriles, alkoxysilanes and aliphatic ethers as essential compounds, comprising two or more steps of reaction involving the use of at least one of said essential compounds as fresh reactant alone or in a mixture in which it constitutes the main component, said process being characterized by the fact that in the last of said one or more reaction steps the essential compound used as a fresh reactant is the ED compound.

Abstract translation: 一种制备催化剂组分的方法，包括Mg化合物，Ti化合物和选自醇，二醇，酯，酮，胺，酰胺，腈，烷氧基硅烷和脂族醚作为必需化合物的电子给体化合物（ED），包括两个或 更多的反应步骤涉及使用至少一种所述必需化合物作为新鲜反应物或其构成主要组分的混合物，所述方法的特征在于在所述一个或多个反应步骤的最后一个步骤中， 用作新鲜反应物的必需化合物是ED化合物。

公开(公告)号：WO2010034664A1

公开(公告)日：2010-04-01

申请号：PCT/EP2009/062056

申请日：2009-09-17

Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  COLLINA, Gianni ,  FAIT, Anna ,  FUSCO, Ofelia ,  MORINI, Giampiero ,  PEDRIALI, Lorella ,  SPOTO, Rosa ,  VINCENZI, Paolo

Inventor： COLLINA, Gianni ,  FAIT, Anna ,  FUSCO, Ofelia ,  MORINI, Giampiero ,  PEDRIALI, Lorella ,  SPOTO, Rosa ,  VINCENZI, Paolo

IPC: C08F4/651 ,  C08F4/649 ,  C08F10/00

CPC classification number: C08F10/02 ,  B01J31/0201 ,  B01J31/0235 ,  B01J31/0272 ,  B01J31/143 ,  B01J31/2208 ,  B01J31/26 ,  B01J31/38 ,  C08F10/06 ,  C08F210/16 ,  C08F4/6492 ,  C08F4/651 ,  C08F2/34 ,  C08F210/06 ,  C08F2500/18 ,  C08F2500/12 ,  C08F2500/17

Abstract: Prepolymerized catalyst component for the polymerization of olefins CH 2 =CHR, wherein R is hydrogen or a C 1 -C 12 hydrocarbyl group, comprising a solid catalyst component characterized by comprising Mg, Ti halogen and an electron donor (ID) selected from the alkyl esters of aromatic dicarboxylic acids in such an amount that the molar ratio ID/Mg ranges from 0.025 to 0.07 and the Mg/Ti molar ratio is higher than 13, said prepolymerized catalyst component containing an amount of ethylene pre-polymer up to 5Og per g of said solid catalyst component.

Abstract translation: 用于烯烃聚合的预聚合催化剂组分CH 2 = CHR，其中R是氢或C 1 -C 12烃基，其包含固体催化剂组分，其特征在于包含Mg，Ti卤素和选自芳族的烷基酯的电子给体（ID） 二羧酸的量使得ID / Mg的摩尔比为0.025至0.07，Mg / Ti摩尔比高于13，所述预聚催化剂组分含有一定量的乙烯预聚物，最高至50g / g所述固体 催化剂组分。

公开(公告)号：WO2006056562A1

公开(公告)日：2006-06-01

申请号：PCT/EP2005/056115

申请日：2005-11-21

Applicant: Basell Poliolefine Italia s.r.l. ,  VINCENZI, Paolo ,  SPOTO, Rosa ,  BADALOCCHI, Matteo

Inventor： VINCENZI, Paolo ,  SPOTO, Rosa ,  BADALOCCHI, Matteo

IPC: C22B34/12 ,  C01G23/02 ,  B01D1/06

CPC classification number: B01D1/223 ,  C01G23/022 ,  C22B34/1231 ,  Y02P10/23

Abstract: A method for continuously recovering titanium tetrachloride TiCl4 from a waste liquid comprising TiCl 4 and by-products, wherein said waste liquid is subjected, as a flowing liquid film, to an evaporation step for a residence time of less than minutes at a temperature higher than 90 ° C.

Abstract translation: 一种从包含TiCl 4和副产物的废液中连续回收四氯化钛TiCl 4的方法，其中所述废液作为流动液膜经历蒸发步骤，停留时间较短 在高于90℃的温度下分钟。

公开(公告)号：WO2004106388A2

公开(公告)日：2004-12-09

申请号：PCT/EP2004/005186

申请日：2004-05-07

Applicant: BASELL POLIOLEFINE ITALIA S.P.A. ,  MORINI, Giampiero ,  DALL'OCCO, Tiziano ,  PIEMONTESI, Fabrizio ,  SPOTO, Rosa ,  VINCENZI, Paolo ,  VITALE, Gianni

Inventor： MORINI, Giampiero ,  DALL'OCCO, Tiziano ,  PIEMONTESI, Fabrizio ,  SPOTO, Rosa ,  VINCENZI, Paolo ,  VITALE, Gianni

IPC: C08F4/651

CPC classification number: C08F10/00 ,  C08F210/16 ,  C08F4/6367 ,  C08F4/651 ,  C08F210/08 ,  C08F2500/12 ,  C08F4/6555 ,  C08F4/6492 ,  C08F4/6545 ,  C08F4/6565

Abstract: A process for preparing a catalyst component, comprising a Mg compound a Ti compound and an electron donor compound (ED) selected from alcohol, glycols, esters, ketones, amines, amides, nitriles, alkoxysilanes and aliphatic ethers as essential compounds, comprising two or more steps of reaction involving the use of at least one of said essential compounds as fresh reactant alone or in a mixture in which it constitutes the main component, said process being characterized by the fact that in the last of said one or more reaction steps the essential compound used as a fresh reactant is the ED compound.

Abstract translation: 一种制备催化剂组分的方法，包括Mg化合物，Ti化合物和选自醇，二醇，酯，酮，胺，酰胺，腈，烷氧基硅烷和脂族醚作为必需化合物的电子给体化合物（ED），包括两个或 更多的反应步骤涉及使用至少一种所述必需化合物作为新鲜反应物或其构成主要组分的混合物，所述方法的特征在于在所述一个或多个反应步骤的最后一个步骤中， 用作新鲜反应物的必需化合物是ED化合物。