公开(公告)号：KR20180070582A

公开(公告)日：2018-06-26

申请号：KR20187010612

申请日：2016-10-17

Applicant: SHELL INT RESEARCH

Inventor： VAN MOURIK ARIAN

IPC: C07C1/24 ,  C07C7/00 ,  C07C7/05 ,  C07C7/11 ,  C07C15/46

CPC classification number: C07C7/10 ,  C07C1/24 ,  C07C7/005 ,  C07C7/05 ,  C07C15/46

Abstract: 본발명은, 하기단계들을포함하는, 스타이렌또는치환된스타이렌의제조방법에관한것이다: (a) 1-페닐에탄올또는치환된 1-페닐에탄올을함유하는공급물을적합한탈수촉매의존재하에탈수처리하는단계; (b) 얻어진생성물혼합물을분리처리하고, 이에따라서물 및스타이렌또는치환된스타이렌을함유하는스트림및 중질분을함유하는잔류분획을얻는단계; (c) 물및 스타이렌또는치환된스타이렌을함유하는스트림을염기로처리하는단계; (d) 단계 (c)의처리된스트림을스타이렌또는치환된스타이렌-풍부생성물스트림과스타이렌또는치환된스타이렌-부족폐수스트림으로분리시키는단계; (e) 스타이렌또는치환된스타이렌-부족폐수스트림을스트리핑칼럼에서스팀으로처리하고, 이에따라서처리된폐수스트림과, 스팀및 스타이렌또는치환된스타이렌을포함하는처리된스트림을얻는단계.

公开(公告)号：KR20180042855A

公开(公告)日：2018-04-26

申请号：KR20187004061

申请日：2016-08-16

Applicant: SHELL INT RESEARCH

Inventor： YANSON YURIY ,  LI HONG XIN ,  PETUSHKOV ANTON

IPC: B01J29/44 ,  B01J29/40 ,  B01J35/02 ,  B01J35/10 ,  B01J37/02 ,  C07C4/18 ,  C07C15/04

CPC classification number: B01J29/46 ,  B01J29/042 ,  B01J29/045 ,  B01J29/44 ,  B01J29/48 ,  B01J35/1061 ,  B01J37/0203 ,  B01J2229/20 ,  B01J2229/42 ,  C07C4/18 ,  C07C2521/08 ,  C07C2529/44 ,  C10G35/095 ,  Y02P20/52 ,  C07C15/04 ,  C07C11/04

Abstract: a) 20 내지 70 중량%의내화성산화물결합제; 0.1 내지 1.0 ㎖/g의중간기공용적, 3 내지 100㎚의미결정크기및 20 내지 200의범위의실리카대 알루미나몰비를갖는, 30 내지 80 중량%의 ZSM-5로구성되는캐리어(모든백분율은전체촉매를기준으로함); b) 0.001 내지 5 중량%의양의, 제6족, 제9족및 제10족으로이루어진군으로부터선택된 1종이상의금속; 및 c) 임의로, 전체촉매를기준으로최대 0.5 중량%까지의양의, 제14족으로부터선택된금속을포함하는알킬방향족전환촉매, 및이러한촉매의제조방법.

公开(公告)号：KR840000767B1

公开(公告)日：1984-06-08

申请号：KR790002515

申请日：1979-07-25

Applicant: SHELL INT RESEARCH

Inventor： WEBB SHIRLEY BEATRICE ,  SMITH GRAHAM CLIFFORD ,  HAKEN PIETER TEN

IPC: C07D213/36

Abstract: The title compds. I (X=H, cyano, alkoxy, cyclozlkyloxy, alkylthio, arylthio, alkyl, -NRR'; R=H, alkyl; R'=alkyl, aryl, cycloalkyl, acyl; Y, Z independently=halo, alkyl, alkoxy, nitro; m, n=0-2) were prepd. Thus, nicotine-4'-chloroanilide was treated with SOCl2 to give the imino chloride, which was treated with CuCN to give 60% 4'-chlorophenylimino-C-(cyano)methyl-3-pyridine. At 1kg of the latter compd./ha there was >80% inhibition of plasmopera viticola on vine plants. Other compds. also had plant growth retardant and leaf abscission activity.

公开(公告)号：KR840000055B1

公开(公告)日：1984-01-31

申请号：KR800000028

申请日：1980-01-07

Applicant: SHELL INT RESEARCH

Inventor： BARKER MICHAEL DEREK

IPC: C07D405/12

公开(公告)号：KR820000001B1

公开(公告)日：1982-01-25

申请号：KR760000991

申请日：1976-04-21

Applicant: SHELL INT RESEARCH

Inventor： KIRBY P ,  JORDAN D ,  RAREN C

IPC: A01N25/02 ,  A01N29/04 ,  A01N31/14

Abstract: Weeds which were growing together with rice were inhibited by applying weed killing amount of 2,6-dichlorobenzyl-(2,2-dimethyl-4-ethyl-1,3-dioxorane-4-yl)methyl ether, carrier and surface active agent to the rice culture ground when after germination of rice-seed or after 5-20 days of riceplanting.

公开(公告)号：KR850000432B1

公开(公告)日：1985-04-03

申请号：KR800000928

申请日：1980-03-06

Applicant: SHELL INT RESEARCH

Inventor： HAKEN PIETER TEN ,  WEBB SHIRLEY BEATRICE

IPC: C07D213/74

公开(公告)号：KR840000837B1

公开(公告)日：1984-06-19

申请号：KR800003454

申请日：1980-09-02

Applicant: SHELL INT RESEARCH

Inventor： BADMIN JOHN STEWART ,  KNIGHT ROBERT JOHN ,  PUNPENG VICHIEN

IPC: A01N43/00

公开(公告)号：KR840000533B1

公开(公告)日：1984-04-20

申请号：KR800000042

申请日：1980-01-08

Applicant: SHELL INT RESEARCH

Inventor： BADMIN JOHN S

IPC: A01N57/00

公开(公告)号：KR810001279B1

公开(公告)日：1981-10-10

申请号：KR770000031

申请日：1977-01-10

Applicant: SHELL INT RESEARCH

Inventor： WOOD D ,  ROSINGER H ,  SHELDON R

IPC: C07C45/00

Abstract: Title compds. useful as intermediates for insecticide, were prepd. by reaction of the mixt. of metha-aryloxy-benzyl and-benzal halide. and aq. NH3, HCHO or hexamethylenetetramine followed by hydrolysis at pH 3-6.5 in the presence of CH3COOH or inorganic acid. Thus the mixt. of 3-phenoxybenzyl bromide and 3-phenoxybenzal bromide which were prepd. by reaction of 3-phenoxytoluene with Br2, was mixed with hexa methylenetetramine and H2O. The mixt. was maintanined at 105oC 4hr under refluxing and was hydrolysed with conc. HCl to give metha-phenoxy-benzaldehyde.

公开(公告)号：KR800001504B1

公开(公告)日：1980-12-19

申请号：KR780000976

申请日：1978-04-06

Applicant: SHELL INT RESEARCH

Inventor： RIESSER G

IPC: B01J23/84

Abstract: Hydrocarbons are dehydrogenated with a mixed oxide catalyst which is prepd. by drying and calcing a mixture of Fe2O3 20-95, K2O or K2CO3 3-30, V2O5 0.01-9, MoO3 r WO3 0.01-20, CeO3 0/01-50, CoO 0-50 and Cr2O3 0-30 wt. %. Thus, ethylbenzene is dehydrogenated at 610≦̸C, and 0-374 atm. with catalyst and water vapor to give styrene with selectivity of 93.8.