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    POLYMERIZATION OF ISOPRENE FROM RENEWABLE RESOURCES
    1.
    发明申请
    POLYMERIZATION OF ISOPRENE FROM RENEWABLE RESOURCES 有权
    可再生能源的异丙苯聚合

    公开(公告)号：US20140080983A1

    公开(公告)日：2014-03-20

    申请号：US13971484

    申请日：2013-08-20

    Applicant: Joseph C. McAuliffe ,  Sergey Paramonov ,  Stephan Rodewald ,  Karl J. Sanford

    Inventor： Joseph C. McAuliffe ,  Sergey Paramonov ,  Stephan Rodewald ,  Karl J. Sanford

    IPC: C08F4/52 ,  C08F4/16

    CPC classification number: C08F4/52 ,  C08F4/16 ,  C08F36/08 ,  C12P5/007 ,  Y02E50/343

    Abstract: This invention relates to compositions and methods for producing polymers of isoprene derived from renewable resources, such as isoprene produced from cultured cells that use renewable carbon sources. A starting isoprene composition, such as a bioisoprene composition, is distinguished from petroleum based isoprene by its purity profile (such as lower levels of certain C5 hydrocarbons other than isoprene, presence of certain compounds associated with the biological process for production) and the relative content of the carbon isotopes. Polymers obtained by polymerization of such starting isoprene composition according to this invention, such as a polyisoprene homopolymer or a copolymer having repeat units that are derived from isoprene, are distinguishable from isoprene containing polymers from petrochemical resources.

    Abstract translation: 本发明涉及用于生产衍生自可再生资源的异戊二烯聚合物的组合物和方法，例如由使用可再生碳源的培养细胞产生的异戊二烯。 起始的异戊二烯组合物，例如生物异戊二烯组合物，其特征在于其石油基异戊二烯的纯度分布（例如除了异戊二烯之外的某些C5烃的较低水平，与生产生物过程相关的某些化合物的存在）以及相对含量 的碳同位素。 通过聚合本发明的这种起始异戊二烯组合物得到的聚合物，例如聚异戊二烯均聚物或具有衍生自异戊二烯的重复单元的共聚物，与来自石化资源的含异戊二烯聚合物是可区分的。

    Polymerization of isoprene from renewable resources
    2.
    发明授权
    Polymerization of isoprene from renewable resources 有权
    从可再生资源聚合异戊二烯

    公开(公告)号：US08546506B2

    公开(公告)日：2013-10-01

    申请号：US12817093

    申请日：2010-06-16

    Applicant: Joseph C. McAuliffe ,  Sergey Paramonov ,  Stephan Rodewald ,  Karl J. Sanford

    Inventor： Joseph C. McAuliffe ,  Sergey Paramonov ,  Stephan Rodewald ,  Karl J. Sanford

    IPC: C08F236/08 ,  C07C11/18 ,  C12P5/02

    CPC classification number: C08F4/52 ,  C08F4/16 ,  C08F36/08 ,  C12P5/007 ,  Y02E50/343

    Abstract: The invention features compositions and methods for producing polymers of isoprene derived from renewable resources such as isoprene produced from cultured cells that use renewable carbon sources. A starting isoprene composition, such as a bioisoprene composition, is distinguished from petroleum based isoprene by the purity profile (such as lower levels of certain C5 hydrocarbons other than isoprene, presence of certain compounds associated with the biological process for production) and the relative content of the carbon isotopes. Polymers obtained by polymerization of such starting isoprene composition according to this invention, such as a polyisoprene homopolymer or a copolymer having repeat units that are derived from isoprene, are distinguishable from isoprene containing polymers from petrochemical resources. The present invention more specifically discloses a polyisoprene polymer which is comprised of repeat units that are derived from isoprene monomer, wherein the polyisoprene polymer has δ13C value of greater than −22‰. This type of polyisoprene can be a cis-1,4-polyisoprene homopolymer rubber. Also provided are methods for verifying that a polyisoprene homopolymer or a copolymer having repeat units that are derived from isoprene contains isoprene that is from a sustainable renewable non-petroleum derived source.

    Abstract translation: 本发明的特征是用于生产衍生自可再生资源的异戊二烯聚合物的组合物和方法，例如由使用可再生碳源的培养细胞产生的异戊二烯。 起始的异戊二烯组合物如生物异戊二烯组合物通过纯度分布（例如除异戊二烯以外的某些C5烃的较低水平，与生产生物过程相关的某些化合物的存在）以及相对含量 的碳同位素。 通过聚合本发明的这种起始异戊二烯组合物得到的聚合物，例如聚异戊二烯均聚物或具有衍生自异戊二烯的重复单元的共聚物，与来自石化资源的含异戊二烯聚合物是可区分的。 本发明更具体地公开了由衍生自异戊二烯单体的重复单元组成的聚异戊二烯聚合物，其中聚异戊二烯聚合物的δ13C值大于-220 / 00。 这种类型的聚异戊二烯可以是顺式-1,4-聚异戊二烯均聚物橡胶。 还提供了用于验证聚异戊二烯均聚物或具有衍生自异戊二烯的重复单元的共聚物包含来自可持续可再生非石油衍生源的异戊二烯的方法。

    Self-sealing apparatus for chemical reaction vessel
    3.
    发明申请
    Self-sealing apparatus for chemical reaction vessel 审中-公开

    公开(公告)号：US20060021673A1

    公开(公告)日：2006-02-02

    申请号：US10899995

    申请日：2004-07-27

    Applicant: Stephan Rodewald

    Inventor： Stephan Rodewald

    IPC: B65B1/04

    CPC classification number: B65B7/2835 ,  B01J2219/00315 ,  B01J2219/00335 ,  B01J2219/00344 ,  B01J2219/00346 ,  B01L3/50825 ,  B01L2300/042 ,  B01L2300/049 ,  B01L2400/0616 ,  B01L2400/0633 ,  Y10S141/01

    Abstract: According to an aspect of the invention, an apparatus for self-sealing of a reaction vessel, such that the reaction vessel may be repeatedly accessed by a fluid transfer mechanism and subsequently self-sealed, is detailed. The reaction vessel has an access opening, and the apparatus comprises a cap, a ball which is comprised of a magnetizable material (such as a ferrous metal), and a ring magnet. The cap is sized to fit over the reaction vessel access opening, and has an access port. The cap has an internal surface which faces the reaction vessel, and an external surface, which faces away from the reaction vessel. The ball is sized to fit over the cap access port, such that a portion of the ball seats partially in the cap access port on the cap internal surface, thus sealing the cap access port. According to an aspect of the invention, the ball may be comprised of a ferromagnetic material, or a magnetizable material that is preferably magnetized. The ring magnet produces a magnetic field, and is mounted to the cap on the cap external surface. The ring magnet is spaced from the cap such that the magnetic field is sufficient to hold the ball in the cap access port, and to reseat the ball in the cap access port after the reaction vessel is accessed.

    Process for synthesizing functionalized styrene monomer
    4.
    发明授权
    Process for synthesizing functionalized styrene monomer 失效
    官能化苯乙烯单体合成方法

    公开(公告)号：US06803462B2

    公开(公告)日：2004-10-12

    申请号：US10609973

    申请日：2003-06-30

    Applicant: Stephan Rodewald ,  Steven Kristofer Henning ,  Brian Earl Burkhart

    Inventor： Stephan Rodewald ,  Steven Kristofer Henning ,  Brian Earl Burkhart

    IPC: C07D29502

    CPC classification number: C08F236/14

    Abstract: This invention discloses a rubbery polymer which is comprised of repeat units that are derived from (1) at least one conjugated diolefin monomer, and (2) at least one functionalized monomer having of the structural formula: wherein R represents an alkyl group containing from 1 to about 10 carbon atoms or a hydrogen atom, and wherein R1 and R2 can be the same or different and represent hydrogen atoms or a moiety selected from the group consisting of wherein R3 groups can be the same or different and represent alkyl groups containing from 1 to about 10 carbon atoms, aryl groups, allyl groups, and alkyloxy groups of the structural formula —(CH2)y—O—(CH2)z—CH3, wherein Z represents a nitrogen containing heterocyclic compound, wherein R4 represents a member selected from the group consisting of alkyl groups containing from 1 to about 10 carbon atoms, aryl groups, and allyl groups, and wherein n, x, y and z represents integers from 1 to about 10, with the proziso that R1 and R2 can not both be hydrogen atoms.

    Abstract translation: 本发明公开了一种橡胶状聚合物，其由衍生自（1）至少一种共轭二烯单体的重复单元组成，和（2）至少一种具有以下结构式的官能化单体：其中R表示含有1个 至约10个碳原子或氢原子，并且其中R 1和R 2可以相同或不同，并且表示氢原子或选自下组的部分，其中R3基团可以相同或不同，并且表示 含有1至约10个碳原子的烷基，具有结构式 - （CH 2）y O-（CH 2）z -CH 3的芳基，烯丙基和烷氧基，其中Z表示含氮杂环化合物，其中R 4 >表示选自含有1至约10个碳原子的烷基，芳基和烯丙基的成员，并且其中n，x，y和z表示1至约10的整数，其中R <1>和R 2可以是n 它们都是氢原子。

    Functionalized elastomers
    5.
    发明授权
    Functionalized elastomers 失效
    官能化弹性体

    公开(公告)号：US06790921B1

    公开(公告)日：2004-09-14

    申请号：US10609916

    申请日：2003-06-30

    Applicant: Stephan Rodewald ,  Steven Kristofer Henning ,  Brian Earl Burkhart

    Inventor： Stephan Rodewald ,  Steven Kristofer Henning ,  Brian Earl Burkhart

    IPC: C08F448

    CPC classification number: C08F236/14

    Abstract: This invention discloses a rubbery polymer which is comprised of repeat units that are derived from (1) at least one conjugated diolefin monomer, and (2) at least one functionalized monomer having of the structural formula: wherein R represents an alkyl group containing from 1 to about 10 carbon atoms or a hydrogen atom, and wherein R1 and R2 can be the same or different and represent hydrogen atoms or a moiety of the structural formula: wherein the R3 groups in repeat units and in different repeat units can be the same or different and represent hydrogen atoms or alkyl groups containing from 1 to about 4 carbon atoms, wherein n and x represents integers from 1 to about 10, with the proviso that R1 and R2 can not both be hydrogen atoms.

    Abstract translation: 本发明公开了一种橡胶状聚合物，其由衍生自（1）至少一种共轭二烯单体的重复单元组成，和（2）至少一种具有以下结构式的官能化单体：其中R表示含有1个 至约10个碳原子或氢原子，并且其中R 1和R 2可以相同或不同，并且表示氢原子或结构式的部分：其中R 3基团以重复单元和 不同的重复单元可以相同或不同，表示氢原子或含有1至约4个碳原子的烷基，其中n和x表示1至约10的整数，条件是R 1和R 2 >不能都是氢原子。

    Functionalized elastomers
    6.
    发明授权
    Functionalized elastomers 失效
    官能化弹性体

    公开(公告)号：US06664328B1

    公开(公告)日：2003-12-16

    申请号：US10457881

    申请日：2003-06-10

    Applicant: Stephan Rodewald ,  Steven Kristofer Henning ,  Brian Earl Burkhart

    Inventor： Stephan Rodewald ,  Steven Kristofer Henning ,  Brian Earl Burkhart

    IPC: C08F23610

    CPC classification number: C08F236/14 ,  Y10T152/10495

    Abstract: This invention discloses a rubbery polymer which is comprised of repeat units that are derived from (1) at least one conjugated diolefin monomer, and (2) at least one functionalized monomer having the structural formula: wherein R represents an alkyl group containing from 1 to about 10 carbon atoms or a hydrogen atom, and wherein R1 and R2 can be the same or different and represent hydrogen atoms or a moiety of the structural formula: wherein the R3 groups in repeat units and in different repeat units can be the same or different and represent hydrogen atoms or alkyl groups containing from 1 to about 4 carbon atoms, wherein n and x represents integers from 1 to about 10, with the proviso that R1 and R2 can not both be hydrogen atoms.

    Abstract translation: 本发明公开了一种橡胶状聚合物，其由衍生自（1）至少一种共轭二烯单体的重复单元组成，和（2）至少一种具有以下结构式的官能化单体：其中R表示含有1至 约10个碳原子或氢原子，并且其中R 1和R 2可以相同或不同，表示氢原子或结构式的部分：其中R 3基团以重复单元和 不同的重复单元可以相同或不同，表示含有1至约4个碳原子的氢原子或烷基，其中n和x表示1至约10的整数，条件是R 1和R 2均为 不能都是氢原子。

    COPOLYMERS OF CONJUGATED TRIENE MONOMERS FOR IMPROVED FILLER INTERACTION
    10.
    发明申请
    COPOLYMERS OF CONJUGATED TRIENE MONOMERS FOR IMPROVED FILLER INTERACTION 有权
    用于改进填料相互作用的共聚三烯单体共聚物

    公开(公告)号：US20120048446A1

    公开(公告)日：2012-03-01

    申请号：US13079907

    申请日：2011-04-05

    Applicant: Gabor Kaszas ,  Stephan Rodewald ,  Joseph John Kulig

    Inventor： Gabor Kaszas ,  Stephan Rodewald ,  Joseph John Kulig

    IPC: B60C1/00 ,  C08F8/42 ,  C08F8/00 ,  C08F236/22

    CPC classification number: C08C19/28 ,  B60C1/0016 ,  C08C19/22 ,  C08C19/25 ,  C08F8/30 ,  C08F8/42 ,  C08F236/06 ,  C08F236/08 ,  C08F236/10 ,  C08F236/22 ,  C08G77/00 ,  C08K3/04 ,  C08K3/045 ,  C08K5/5419 ,  C08L19/006 ,  C08L21/00 ,  C08L9/00 ,  C08L2666/08 ,  C08F220/06 ,  C08F210/10 ,  C08F4/48

    Abstract: The present invention achieves increased filler interaction by incorporating a small amount (a few units per chain of rubbery polymer) of a conjugated triene monomer, such as alloocimene, randomly throughout the polymer chain of a rubbery polymer or at the chain ends of the rubbery polymer. The incorporation of the conjugated triene monomer leads to the formation of a polymer containing highly reactive conjugated diene units. These conjugated diene units can chemically react with carbon black leading to superior reinforcement. Alternatively, these conjugated diene units can be used for functionalization of the polymer with silica interactive/reactive groups using Diels Alder reactions. This functionalization of the rubbery polymer can conveniently be conducted in a mixer, such as a Banbury mixer, a mill mixer, or the like. The present invention more specifically discloses a rubbery polymer having repeat units which are comprised of (1) an olefin monomer selected from the group consisting of conjugated diolefin monomers and monoolefin monomers and (2) a conjugated triene monomer. The subject invention further reveals a rubbery composition which is comprised of the reaction product of (I) a rubbery polymer having repeat units which are comprised of (1) an olefin monomer selected from the group consisting of conjugated diolefin monomers and monoolefin monomers and (2) a conjugated triene monomer and (II) a dienophile and/or dienophile which is functionalized with a group which is capable of reacting with a filler selected from the group consisting of carbon black, silica, starch, and cellulose.

    Abstract translation: 本发明通过在橡胶状聚合物的整个聚合物链中或在橡胶状聚合物的链末端随机引入少量（每个链的橡胶状聚合物链）的共轭三烯单体如异环烯烃来实现增加的填料相互作用 。 共轭三烯单体的引入导致形成含高活性共轭二烯单元的聚合物。 这些共轭二烯单元可以与炭黑发生化学反应，从而实现优异的增强。 或者，这些共轭二烯单元可用于使用Diels Alder反应用二氧化硅相互作用/反应性基团对聚合物进行官能化。 橡胶状聚合物的这种功能化可以方便地在混合器中进行，例如班伯里密炼机，研磨混合机等。 本发明更具体地公开了具有重复单元的橡胶状聚合物，其包含（1）选自共轭二烯烃单体和单烯烃单体的烯烃单体和（2）共轭三烯单体。 本发明还揭示了一种橡胶组合物，其由（I）具有重复单元的橡胶状聚合物的反应产物组成，所述重复单元包括（1）选自共轭二烯烃单体和单烯烃单体的烯烃单体和（2 ）共轭三烯单体和（II）亲二烯体和/或亲二烯体，其可以与能够与选自炭黑，二氧化硅，淀粉和纤维素的填料反应的基团官能化。

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