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    METHOD OF MANUFACTURING A HYDROGENATION CATALYST
    1.
    发明申请
    METHOD OF MANUFACTURING A HYDROGENATION CATALYST 审中-公开
    用于生产加氢催化剂

    公开(公告)号：WO1997037758A1

    公开(公告)日：1997-10-16

    申请号：PCT/EP1997001617

    申请日：1997-04-01

    Applicant: BASF AKTIENGESELLSCHAFT ,  HEINEKE, Daniel ,  ACHHAMMER, Günther ,  SCHNEIDER, Heinz-Walter ,  THOME, Alfred

    Inventor： BASF AKTIENGESELLSCHAFT

    IPC: B01J23/42

    CPC classification number: B01J23/42 ,  C01B21/1418

    Abstract: The invention concerns the manufacture of a hydrogenation catalyst by the reduction of platinum from an oxidation state of not less than two with a reducing agent in an aqueous medium in the presence of a carbon-containing support following partial poisoning, the method using a compound of general formula (I) in which X, Y and Z, which may be the same or different, are hydrogen, C1-C18 alkyl, C5-C10 cycloalkyl, halogen, hydroxyl, C1-C6 alkoxy or-NR'R'', whereby R, R' and R'', which may by the same or different, are hydrogen, C1-C18 alkyl or C5-C10 cycloalkyl. The invention also concerns a hydrogenation catalyst manufactured by this method, its use in the production of hydroxylammonium salts, a method of producing hydroxylammonium salts and a method of regenerating platinum-based hydrogenation catalysts of this kind.

    Abstract translation: 通过在局部中毒后的碳质载体的存在下，在含水介质中还原铂中的不少于两个的氧化态与还原剂由等同通式（I）的化合物制备的加氢催化剂，其中X，Y和Z 可以或不同，并代表氢，C1-C18烷基，C5-C10环烷基， ''，其中R，R '是卤素，羟基，C1-C6烷氧基和-NR'R和R'“是相同或不同 可以是，并且可以是氢，C1-C18烷基，C5-C10环烷基，被用作以及通过本发明的方法制备的氢化催化剂，其用于制备羟铵盐的，对羟铵盐的制备方法以及再生氢化催化剂的方法中使用 基于铂。

    PROCESS FOR PRODUCING n-BUTYRALDEHYDE AND/OR n-BUTANOL
    3.
    发明申请
    PROCESS FOR PRODUCING n-BUTYRALDEHYDE AND/OR n-BUTANOL 审中-公开
    用于生产正丁醛和/或正丁醇

    公开(公告)号：WO1995019334A1

    公开(公告)日：1995-07-20

    申请号：PCT/EP1995000114

    申请日：1995-01-12

    Applicant: BASF AKTIENGESELLSCHAFT ,  KANAND, Jürgen ,  RÖPER, Michael ,  PINKOS, Rolf ,  PACIELLO, Rocco ,  THOME, Alfred

    Inventor： BASF AKTIENGESELLSCHAFT

    IPC: C07C45/51

    CPC classification number: C07C41/32 ,  C07C29/172 ,  C07C41/06 ,  C07C45/513 ,  C07C47/02 ,  C07C43/15 ,  C07C31/12

    Abstract: In a process for producing n-butyraldehyde and/or n-butanol, (a) 1,3-butadiene is reacted with an alcohol having the formula ROH, in which the residue R stands for a non-substituted C2-C20-alkyl or alkenyl group that may also be substituted by 1 or 2 C1-C10-alkoxy or hydroxy groups, a C6-C10-aryl or C7-C11-aralkyl group or the methyl group, at a higher temperature and pressure in the presence of a Brönsted acid or in the presence of a compound of an element from groups IB, VIIb or VIIIb of the periodic table of elements with phosphoric or nitrogenated ligands, so as to produce a mixture of addition compounds having the formulas (II) and (III); (b) the addition compound III is isomerised into the addition compound II; (c) the addition compound II is isomerised in the presence of a homogeneous or heterogeneous transition metal element catalyst in liquid phase or in the presence of a heterogeneous transition metal element-containing catalyst in gaseous phase, so as to produce an enol ether having the formula (IV); and (d) n-butyraldehyde and/or n-butanol are generated by reacting said enol ether IV with hydrogen and water or with water in the presence of a homogeneous or heterogeneous transition metal element catalyst in the liquid phase or in the presence of a heterogeneous transition metal element-containing catalyst in the gaseous phase. The alcohol ROH released is recycled into the partial reaction (a).

    Abstract translation: ROH，其中R是未取代的或具有1至2个C 1 -C 10烷氧基或：一种用于生产正丁醛和/或正丁醇，在其中一个）1,3-丁二烯与式醇的方法 羟基取代的C2至C20烷基或链烯基，C6至C10芳基或C7-C11芳烷基团或甲基基团，在升高的温度和在布朗斯台德酸的存在下升高的压力或在存在 从Ib族，VIIB或用含磷或含氮配体的元素的周期表VIIIb的元素的复合物，以得到式的加合物（II）的混合物和（III）中，b）加合物（III），得到加合物（ II），异构化从本C）在均相或非均相过渡金属元素催化剂的在液相中或在非均相，含过渡金属元素的催化剂的在气相中存在的式（IV）的烯醇醚的存在异构化加合物（II），以及d） 伊诺 醚（IV）是通过将其与氢和水或水在均相或非均相过渡金属元素催化剂的存在下在液相或在非均相含过渡金属元素的催化剂的在气相中的正丁醛和/或正丁醇的存在下反应而生产，和醇 ROH（I）再次释放和释放的醇ROH（I）引回定义为部分反应：a）反应。

    PROCESS FOR PREPARING A HYDROGENATION CATALYST
    4.
    发明申请
    PROCESS FOR PREPARING A HYDROGENATION CATALYST 审中-公开
    用于生产加氢催化剂

    公开(公告)号：WO1997012673A1

    公开(公告)日：1997-04-10

    申请号：PCT/EP1996004203

    申请日：1996-09-26

    Applicant: BASF AKTIENGESELLSCHAFT ,  HEINEKE, Daniel ,  RIEKER, Christopher, William ,  OOSTVOGELS, Jozef ,  POSTELMANS, Dany ,  SCHNEIDER, Heinz-Walter ,  THOME, Alfred ,  ACHHAMMER, Günther

    Inventor： BASF AKTIENGESELLSCHAFT

    IPC: B01J23/42

    CPC classification number: B01J23/42 ,  B01J23/96 ,  B01J37/16 ,  C01B21/1418 ,  Y02P20/584

    Abstract: The invention relates to a hydrogenation catalyst by the reduction from platinum in the stage of oxidation of +4 (Pt (IV)) with a selective reducing agent in an acidic aqueous medium in the presence of a carbon-containing carrier to platinum in the stage of oxidation +2 (Pt (II)), subsequent poisoning of the platinum thus obtained with a sulphur-containing selective reducing agent, and subsequent reduction of the platinum thus partially poisoned to form metallic platinum (Pt(0)) and subsequent processing as known per se in that (a) Pt (II) is partially poisoned with a sulphur-containing selective reducing agent, wherein the sulphur-containing selective reduction agent is used in an amount which corresponds to from 15 to 70 mol % of the amount of the sulphur-containing selective reducing agent which might be needed to reduce Pt(IV) to Pt (II), provided that the amount of Pt (IV) corresponds to the amount of Pt (II) used and to be poisoned, and subsequently the partially poisoned Pt (II) is reduced with an alkali metal formate to Pt (0); or (b) platinum in the stage of oxidation of greater than +2 is partially poisoned and subsequently or simultaneously reduced with an alkali metal formate to Pt (0). The invention also relates to a hydrogenation catalyst, use of the hydrogenation catalyst for preparing hydroxylammonium salts, a process for the preparation of hydroxylammonium salts, and a process for regenerating platinum-containing hydrogenation catalysts.

    Abstract translation: 通过在的氧化态还原铂的制备氢化催化剂4（铂（IV）），与在碳质载体的存在下，铂的氧化态+2（铂（II））的酸性水性介质中的选择性还原剂，随后中毒 如此所得载铂用选择性还原剂，之后减少从而部分中毒铂成金属铂含硫铂（Pt（0）），并且向其中随后以常规方式后处理通过（a）铂（II）与含硫选择性还原剂反应 部分中毒，被使用，在其对应于从15到70％（摩尔），将在顺序的Pt（IV），以铂（II），以减少所需要的选择性还原剂含硫的量的，提供的量的含硫选择性还原剂 的Pt的量（IV）对应于到，插入的Pt（II）的中毒的量，然后将 部分中毒的Pt（II）与碱金属与Pt减少（0），或（b）铂在大于2部分中毒和随后或同时用碱金属降低到的Pt（0）以及氢化催化剂的氧化状态，使用氢化催化剂 对于羟铵盐的制备，处理用于羟铵盐的制备和用于再生铂的氢化催化剂的方法。

    PROCESS FOR PRODUCING N-BUTYRALDEHYDE AND/OR N-BUTANOL
    5.
    发明申请
    PROCESS FOR PRODUCING N-BUTYRALDEHYDE AND/OR N-BUTANOL 审中-公开
    用于生产正丁醛和/或正丁醇

    公开(公告)号：WO1996007630A1

    公开(公告)日：1996-03-14

    申请号：PCT/EP1995003358

    申请日：1995-08-24

    Applicant: BASF AKTIENGESELLSCHAFT ,  KANAND, Jürgen ,  RÖPER, Michael ,  PACIELLO, Rocco ,  THOME, Alfred

    Inventor： BASF AKTIENGESELLSCHAFT

    IPC: C07C45/51

    CPC classification number: C07D295/023 ,  C07C29/00 ,  C07C45/516 ,  C07C45/56 ,  C07C45/562 ,  C07C31/12

    Abstract: The proposed process for producing n-butyraldehyde and/or n-butanol involves the following steps: (a) 1,3-butadiene is allowed to react with an amine of formula (I) R R NH, in which the groups independently of one another represent hydrogen, optionally substituted aliphatic or cyclo-aliphatic groups, or aryl or aralkyl groups, or are connected to a bridging unit which can contain heteroatoms, at high temperature and pressure and in the presence of a compound of a group VIIIb element, in the presence of an alkali metal amide, or in the presence of a basic metal oxide, to form a mixture of addition compounds of formula (II) and (III); (b) addition compound (III) is isomerised to addition compound (II); (c) addition compound (II) is isomerised in the presence of a homogeneous or heterogeneous transition metal catalyst in liquid phase or in the presence of a heterogeneous catalyst containing transition metal in the gas phase to produce enamine of formula (IV); and (d) the enamine (IV) is converted, by reaction with hydrogen and water, or water, in the presence of a homogeneous or heterogeneous transition metal catalyst in liquid phase, in the presence of a heterogenous catalyst containing transition metal in the gas phase, in the presence of an acid or in the presence of one of the above mentioned catalysts and of an acid, to n-butyraldehyde and/or n-butanol, the amine (I) being released and the released amine (I) being led back into sub-reaction (a).

    Abstract translation: 一种制备正丁醛和/或正丁醇，其中a）1,3-丁二烯过程（具有式I的胺）R <1> [R <2> NH，其中，所述基团各自独立地为氢， 任选地或取代的脂族或脂环族基团，芳基或芳烷基，以一个桥接构件可以带有杂原子，被连接时，在升高的温度和在从所述元素的周期表第VIIIB族的元素的化合物的存在下升高的压力，在一个存在 （II）碱金属酰胺或在碱性金属氧化物的存在下式的加成物（III）的混合物，进行反应b）中异构化加合物（III）（以得到加合物II）中，c）在均相的存在下加合物（II）或 非均相过渡金属元素催化剂在液相或在非均相，含过渡金属元素的催化剂的在气相中存在的式（IV），和d的烯胺）从此恩异构化 胺（IV）通过将其与氢和水或水在液相均相或非均相过渡金属元素催化剂的存在下，反应在气相中的非均相过渡含金属元素的催化剂的存在下，在酸的存在下或在存在所述催化剂和 酸正丁醛和/或正丁醇产生的，其释放胺（I），并根据反应步骤a）在该反应中释放的胺（I）引回。

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