公开(公告)号：KR100839055B1

公开(公告)日：2008-06-19

申请号：KR1020070005996

申请日：2007-01-19

Applicant: 고려대학교 산학협력단

Inventor： 이종협 ,  김우영 ,  주지봉 ,  김영훈 ,  김필 ,  송인규 ,  이관영

IPC: B01J21/04 ,  B01J23/72 ,  B01J23/10

CPC classification number: B01J21/04 ,  B01J23/72 ,  B01J37/04 ,  B01J37/08

Abstract: A mesoporous alumina-ceria composite catalyst supported with copper oxide by using copper oxide as an active material, and utilizing ceria for improving activity of an oxidation reaction and alumina for increasing structural stability of ceria is provided, and a method for selectively oxidizing carbon monoxide using the alumina-ceria composite catalyst supported with copper oxide is provided. A preparation method of a copper oxide-supported alumina-ceria composite catalyst comprises the steps of: (a) mixing an alumina precursor, a ceria precursor, and a copper oxide precursor with a mixed solvent of a surfactant and alcohol to form a micelle; (b) adding water into the solution obtained in the step(a) and agitating a mixture of water and the solution to subject the mixture to a hydrolysis reaction and a condensation reaction; and (c) drying a resulting material of the step(b) and heat-treating the dried resulting material at 350 to 550 deg.C.

Abstract translation: 提供一种通过使用氧化铜作为活性材料负载氧化铜的介孔氧化铝 - 二氧化铈复合催化剂，并且利用二氧化铈提高氧化反应活性和氧化铝以提高二氧化铈的结构稳定性的方法，以及使用 提供了以氧化铜负载的氧化铝 - 二氧化铈复合催化剂。 氧化铜负载氧化铝 - 二氧化铈复合催化剂的制备方法包括以下步骤：（a）将氧化铝前体，二氧化铈前体和氧化铜前体与表面活性剂和醇的混合溶剂混合以形成胶束; （b）向步骤（a）中得到的溶液中加入水，并搅拌水和溶液的混合物以使混合物进行水解反应和缩合反应; 和（c）干燥步骤（b）的所得材料，并将所干燥的所得材料在350至550℃下热处理。