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公开(公告)号：KR1020130045741A
公开(公告)日：2013-05-06
申请号：KR1020110110149
申请日：2011-10-26
Applicant: 국방과학연구소
Abstract: PURPOSE: A method for preparing a cobalt complex containing a 5-chlorotetrazole ligand is provided to enable easy separation and purification, and to improve yield. CONSTITUTION: A method for preparing a cobalt complex comprises: a step of reacting 5-aminotetrazole of chemical formula 1 under the presence of hydrochloric acid, sodium nitrite, and copper chloride and preparing 5-chlorotetrazole of chemical formula 2; a step of reacting the compound of chemical formula 2 with a sodium compound and preparing 5-chlorotetrazole sodium salt of chemical formula 3; and a step of reacting the compound of chemical formula 3 with a cobalt compound of [Co(NH3)m(H2O)n](ClO4)x by a coordinate bond.
Abstract translation: 目的：提供一种制备含有5-氯四唑配体的钴络合物的方法，以便容易地分离和纯化，并提高产率。 构成：制备钴络合物的方法包括：在盐酸，亚硝酸钠和氯化铜存在下使化学式1的5-氨基四唑反应并制备化学式2的5-氯代四唑的步骤; 使化学式2的化合物与钠化合物反应并制备化学式3的5-氯代四唑钠盐的步骤; 和通过配位键使化学式3的化合物与[Co（NH 3）m（H 2 O）n]（ClO 4）x的钴化合物反应的步骤。
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公开(公告)号：KR101315221B1
公开(公告)日：2013-10-08
申请号：KR1020110110149
申请日：2011-10-26
Applicant: 국방과학연구소
Abstract: 본 발명은 점화용 폭약으로 유용한 5-클로로테트라졸 리간드를 포함하는 코발트 착물의 제조방법에 관한 것으로서, 더욱 상세하게는 5-아미노테트라졸을 출발물질로 사용하여 폭발 위험성이 현저히 감소된 반응 조건에서 5-클로로테트라졸 리간드를 포함하는 코발트 착물을 제조하는 방법에 관한 것이다.
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