公开(公告)号：KR100863460B1

公开(公告)日：2008-10-16

申请号：KR1020070079749

申请日：2007-08-08

Applicant: 국방과학연구소

Inventor： 박대인 ,  오창호 ,  한정식

IPC: C07C13/54 ,  C07C13/32

Abstract: A polycyclic hydrocarbon compound containing a triangular ring, a method for preparing the polycyclic hydrocarbon compound, and a liquid fuel containing the compound are provided to obtain a high density and high energy liquid fuel. A polycyclic hydrocarbon compound containing a triangular ring is the tetracyclo[6.2.1.0^2.6 .0^8 .10]undecane represented by the formula. The tetracyclo[6.2.1.0^2.6 .0^8 .10]undecane is prepared by diluting dicyclopentadiene with a mixture solution comprising CH2Cl2 and Et2O; dissolving N-methyl-N-nitrosourea and Pd(OAc)2 in CH2Cl2 with maintaining the external temperature of a reactor to be 10-20 deg.C to react the obtained solution with the diluted one by cyclization; and hydrogenating the obtained one.

Abstract translation: 提供含有三角环的多环烃化合物，制备多环烃化合物的方法和含有该化合物的液体燃料以获得高密度和高能量的液体燃料。 包含三角环的多环烃化合物是由式表示的四环[6.2.1.0 ^ 2.6.08.8.10]十一烷。 通过用包含CH 2 Cl 2和Et 2 O的混合物溶液稀释二环戊二烯制备四环[6.2.1.0 ^ 2.6.08.8.10]十一烷; 将N-甲基-N-亚硝基脲和Pd（OAc）2溶解在CH 2 Cl 2中，保持反应器的外部温度为10-20℃，通过环化将所得溶液与稀释的溶液反应; 并氢化所得的一种。