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公开(公告)号：KR1020170034721A
公开(公告)日：2017-03-29
申请号：KR1020150133384
申请日：2015-09-21
Applicant: 국방과학연구소
Abstract: 본발명은고체추진제및 화포추진제의주요소물질인결합제로사용되는에너제틱열가소성탄성체(Energetic Thermoplastic Elastomer, ETPE) 및이의제조방법에관한것으로, 본발명의열가소성탄성체는테트라졸함유고무와열가소성수지(예컨대, 열가소성폴리올레핀계수지)와 120-150℃에서용융혼합하여제조한다. 본발명의열가소성탄성체는높은파단신율및 낮은영구인장변형율같은우수한기계적물성을가질뿐 아니라용융가공성이용이하여용융혼합을통해간편하게제조됨에따라대량생산에도효율적이다. 특히, 본발명의열가소성탄성체를포함하는가소제조성물은충진제의변형을진행시키지않는고에너지가소제로서기능할수 있는우수한물성및 안정성을가져화약(예컨대, 복합화약) 또는추진제에효과적으로적용될수 있다.
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公开(公告)号：KR101742127B1
公开(公告)日：2017-06-15
申请号：KR1020150133384
申请日：2015-09-21
Applicant: 국방과학연구소
Abstract: 본발명은고체추진제및 화포추진제의주요소물질인결합제로사용되는에너제틱열가소성탄성체(Energetic Thermoplastic Elastomer, ETPE) 및이의제조방법에관한것으로, 본발명의열가소성탄성체는테트라졸함유고무와열가소성수지(예컨대, 열가소성폴리올레핀계수지)와 120-150℃에서용융혼합하여제조한다. 본발명의열가소성탄성체는높은파단신율및 낮은영구인장변형율같은우수한기계적물성을가질뿐 아니라용융가공성이용이하여용융혼합을통해간편하게제조됨에따라대량생산에도효율적이다. 특히, 본발명의열가소성탄성체를포함하는가소제조성물은충진제의변형을진행시키지않는고에너지가소제로서기능할수 있는우수한물성및 안정성을가져화약(예컨대, 복합화약) 또는추진제에효과적으로적용될수 있다.
Abstract translation: 本发明中，本发明的热塑性弹性体是橡胶并且在高能热塑性弹性体（含能热塑性弹性体，ETPE）和制造的方法的热塑性树脂含有四唑被用作固体推进剂和火炮推进剂钉材料的粘合剂（ 例如，热塑性聚烯烃树脂）在120-150폚。 本发明的热塑性弹性体是有效的大规模生产，以及有断裂和优异的机械特性的高伸长率，如低的永久拉伸应变在可熔融加工的使用易于通过熔融混合制备。 特别地，含有本发明的热塑性弹性体增塑剂的组合物可以适用于获得优良的物理性能和稳定性，可以用作高能量增塑剂不与填料粉末的有效的修饰（例如，复合粉末）或推进剂进行。
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3.发明公开
公开(公告)号：KR1020110092520A
公开(公告)日：2011-08-18
申请号：KR1020100011985
申请日：2010-02-09
Applicant: 국방과학연구소
Abstract: PURPOSE: An energy containing thermoplastic elastomer including azidated poly(epichlorohydrin) rubber and a thermoplastic resin is provided to easily implement a mixing process with explosive compositional components by melting commercialized rubber and plastic. CONSTITUTION: Thermoplastic elastomer includes 50 to 80 weight% of azidated poly(epichlorohydrin) rubber and 20 to 50 weight% of a thermoplastic resin. The molecular weight of the azidated poly(epichlorohydrin) is between 200000 and 700000. The azidated poly(epichlorohydrin) is obtained by substituting 50 to 100% of chlorine group with azide group. The thermoplastic resin is a polyethylene resin includes 10 to 40 weight% of maleic anhydride, vinyl acetate, or carboxylic group, and the crystalline melting temperature of the thermoplastic resin is between 60 and 120 degrees Celsius.
Abstract translation: 目的：提供包含叠氮化聚（表氯醇）橡胶和热塑性树脂的含热塑性弹性体的能量，通过熔化市售的橡胶和塑料容易地实现与爆炸性成分组分的混合过程。 构成：热塑性弹性体包括50至80重量％的叠氮化聚（表氯醇）橡胶和20至50重量％的热塑性树脂。 叠氮化聚（表氯醇）的分子量在200000〜700000之间。叠氮化聚（表氯醇）通过用叠氮化物基团取代50〜100％的氯基而得到。 热塑性树脂是聚乙烯树脂，含有10〜40重量％的马来酸酐，乙酸乙烯酯，或羧基，热塑性树脂的结晶熔融温度为60〜120℃。
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公开(公告)号：KR101144098B1
公开(公告)日：2012-05-24
申请号：KR1020100011985
申请日：2010-02-09
Applicant: 국방과학연구소
Abstract: PURPOSE: An energy containing thermoplastic elastomer including azidated poly(epichlorohydrin) rubber and a thermoplastic resin is provided to easily implement a mixing process with explosive compositional components by melting commercialized rubber and plastic. CONSTITUTION: Thermoplastic elastomer includes 50 to 80 weight% of azidated poly(epichlorohydrin) rubber and 20 to 50 weight% of a thermoplastic resin. The molecular weight of the azidated poly(epichlorohydrin) is between 200000 and 700000. The azidated poly(epichlorohydrin) is obtained by substituting 50 to 100% of chlorine group with azide group. The thermoplastic resin is a polyethylene resin includes 10 to 40 weight% of maleic anhydride, vinyl acetate, or carboxylic group, and the crystalline melting temperature of the thermoplastic resin is between 60 and 120 degrees Celsius.
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