불소화합물이 첨가된 리튬이차전지 양극 활물질 및 그제조방법
    1.
    发明公开
    불소화합물이 첨가된 리튬이차전지 양극 활물질 및 그제조방법 有权
    用于锂二次电池添加氟化合物的阴极活性材料及其生产方法

    公开(公告)号:KR1020060133615A

    公开(公告)日:2006-12-27

    申请号:KR1020050053304

    申请日:2005-06-21

    Inventor: 선양국 한정민

    Abstract: Provided are a positive electrode active material for a lithium secondary battery to improve the charge/discharge characteristics, lifetime characteristics, high voltage characteristics and high rate characteristics of a battery, and its preparation method. The positive electrode active material contains a fluorine compound in the form of a complex in a positive electrode active material. The method comprises the steps of adding a solution wherein F is dissolved to a fine powder element precursor solution of high dispersity to react it at 50-150 deg.C for 1-48 hours, thereby preparing a fluorine compound fine powder in the form of a complex having a high dispersity; drying the fluorine compound fine powder at 110 deg.C for 6-24 hours; heat treating the dried one at 150-900 deg.C for 1-20 hours under the oxidative or reductive condition or in vacuum; and adding 0.05-10 parts by weight of the heat treated one to 100 parts by weight of a positive electrode active material and mixing them uniformly.

    Abstract translation: 提供一种用于锂二次电池的正极活性物质及其制备方法,其特征在于提高电池的充放电特性,寿命特性,高电压特性,高电流特性。 正极活性物质在正极活性物质中含有络合物形式的氟化合物。 该方法包括以下步骤:将F溶解到高分散度的细粉末前体溶液中,在50-150℃下反应1-48小时,由此制备氟化合物细粉末 具有高分散性的复合物; 将氟化合物细粉末在110℃干燥6-24小时; 在氧化或还原条件下或真空中,将干燥的物质在150-900℃下热处理1-20小时; 并加入0.05-10重量份的热处理1至100重量份的正极活性物质并均匀混合。

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