公开(公告)号：KR1020030053056A

公开(公告)日：2003-06-27

申请号：KR1020020081702

申请日：2002-12-20

Applicant: 로레알

Inventor： 페롱베아트리스 ,  레스틀르세르쥬 ,  무갱나탈리

IPC: C08F20/34

CPC classification number: A61Q5/06 ,  A61K8/8152 ,  A61K8/8158 ,  A61K2800/5426 ,  A61K2800/5428 ,  C08F220/34

Abstract: PURPOSE: Provided is a self-adhesive cationic or amphoteric free-radical polymer with a high level of self-adhesion, which has sufficient substantivity and very good styling power. CONSTITUTION: The cationic or amphoteric free-radical polymer has a self-adhesion value, expressed by the maximum tensile force (Fmax (in N)), of greater than or equal to 2 N. The polymer includes at least one tertiary or quaternary amine function and comprises one or more units derived from monomers chosen from those of formulae (Ia), (Ib), (Ic), (Id) and (Ie), in which R1 represents a hydrogen atom or a methyl group, R2 represents a linear, branched, cycloaliphatic or aromatic C1-30 divalent hydrocarbon-based group, which may contain one or more hetero atoms chosen from O, N and P, R3, R4 and R5 each independently represent a linear, branched, cycloaliphatic or aromatic C1-30 hydrocarbon-based group, which may contain one or more hetero atoms chosen from O, N and P, X represents an oxygen atom or an NH group, A represents the counterion of the quaternary amine, preferably chosen from halide, sulphate, phosphate and carboxylate ions such as acetate, Ring represents a monocyclic or fused bicyclic, cycloaliphatic or aromatic system, comprising a tertiary or quaternary amine function, and possibly containing one or more additional hetero atoms chosen from O, N and P; R6 represents a hydrogen atom or a linear or branched C1-4 alkyl group, R8 and R9 each independently represent a hydrogen atom or a linear or branched C1-4 alkyl group optionally bearing a COO , SO3 or PO3H group, R7 and R10 each independently represent a divalent hydrocarbon-based group, in particular a group -(CH2)n with n being between 1 and 4 inclusive, optionally interrupted with an oxygen atom, p and q are 0 or 1, Z represents a COO , SO3 or PO3H group, R7 may form with R8, R9 or X, when the latter represents an NH group, an aromatic or non-aromatic 5-, 6- or 7-membered heterocycle, R11 represents a hydrogen atom or a methyl group, R12 represents a divalent C1-4 hydrocarbon-based group, r is 0 or 1.

Abstract translation: 目的：提供具有高水平自粘性的自粘阳离子或两性自由基聚合物，其具有足够的亲和性和非常好的造型力。 构成：阳离子或两性自由基聚合物具有大于或等于2N的最大拉伸力（Fmax（N））表示的自粘附值。聚合物包括至少一个叔胺或季胺 并且包含一种或多种衍生自选自式（Ia），（Ib），（Ic），（Id）和（Ie）的单体的单元，其中R 1表示氢原子或甲基，R 2表示 可以含有一个或多个选自O，N和P的杂原子的直链，支链，脂环族或芳族C1-30二价烃基基团，各自独立地表示直链，支链，脂环族或芳族C1- 30烃基，其可以含有一个或多个选自O，N和P的杂原子，X表示氧原子或NH基团，A'表示季胺的抗衡离子，优选选自卤化物，硫酸盐 ，磷酸盐和羧酸根离子如乙酸酯，环+代表单环 或稠合双环，脂环族或芳族体系，其包含叔胺或季胺官能团，并且可能含有一个或多个另外的选自O，N和P的杂原子; R6表示氢原子或直链或支链C 1-4烷基，R 8和R 9各自独立地表示氢原子或任选具有COO - ，SO 3 - 或PO 3 H的直链或支链C 1-4烷基， - 基团，R 7和R 10各自独立地表示二价烃基基团，特别是基团 - （CH 2）n，其中n在1和4之间，包括任选被氧原子间隔，p和q是0或1， Z表示COO - ，SO 3 - 或PO 3 H - 基团，当后者表示NH基团时，R 7可以与R 8，R 9或X形成，芳族或非芳族的5-，6-或7 R 11表示氢原子或甲基，R 12表示二价C 1-4烃基，r为0或1。