公开(公告)号：KR101352015B1

公开(公告)日：2014-01-16

申请号：KR1020120006533

申请日：2012-01-20

Applicant: 서강대학교산학협력단

Inventor： 신운섭 ,  듀라이사미사라바나쿠마르 ,  송지은

IPC: C08L39/00 ,  C08K5/56 ,  C08F26/00 ,  B01J31/12

Abstract: 본원은, 유기금속/폴리머 복합체, 상기를 포함하는 이산화탄소 환원용 촉매 및 유기금속/폴리머 복합체의 제조 방법에 관한 것으로서, 상기 유기금속/폴리머 복합체를 전기화학촉매로서 이용하여 높은 효율로 이산화탄소를 일산화탄소로 환원시킬 수 있다.

公开(公告)号：KR1020140003233A

公开(公告)日：2014-01-09

申请号：KR1020120071265

申请日：2012-06-29

Applicant: 서강대학교산학협력단

Inventor： 신운섭 ,  송지은 ,  이종명

IPC: C25B3/04 ,  C25B11/18 ,  C07C53/02 ,  C25B9/08

CPC classification number: C25B3/04 ,  C07C53/02 ,  C25B9/08 ,  C25B11/18

Abstract: The present invention relates to a method for preparing formic acid by the electrochemical reduction of carbon dioxide and a device therefor. The method for preparing formic acid according to the present invention electrochemically reduces carbon dioxide using a metal-mercury amalgam electrode material. [Reference numerals] (AA) Formic acid; (BB) Formic acid

Abstract translation: 本发明涉及通过二氧化碳的电化学还原制备甲酸的方法及其装置。 根据本发明的制备甲酸的方法使用金属汞汞齐电极材料电化学地还原二氧化碳。 （AA）甲酸; （BB）甲酸

公开(公告)号：KR1020130085635A

公开(公告)日：2013-07-30

申请号：KR1020120006533

申请日：2012-01-20

Applicant: 서강대학교산학협력단

Inventor： 신운섭 ,  듀라이사미사라바나쿠마르 ,  송지은

IPC: C08L39/00 ,  C08K5/56 ,  C08F26/00 ,  B01J31/12

Abstract: PURPOSE: A metalorganic/ polymer composite, a manufacturing method thereof and a catalyst for deoxidization of carbon dioxide including the metalorganic/ polymer composite are provided to easily deoxidize carbon dioxide by using the metalorganic/ polymer composite with an organometallic compound bonded to a hydrophilic polymer by the pyridine linker as an electrochemical catalyst. CONSTITUTION: A metalorganic polymer composite includes an organometallic compound bonded to a hydrophilic polymer by the pyridine linker. The hydrophilic polymer comprises a polyallylamine group or a polyvinyl pyridine group polymer. A manufacturing method of the metalorganic / polymer composite comprises the steps of: reacting organometallic compound and 4-pyridine carbox aldehyde in a solvent to synthesize metalorganic-pyridine carbox aldehyde compound and reacting the organometallic-pyridine carbox aldehyde compound with the hydrophilic polymer to synthesize the metalorganic/ polymer composite bonded to the hydrophilic polymer by the pyridine linker.

Abstract translation: 目的：提供一种金属有机/聚合物复合材料，其制造方法和包含金属有机/聚合物复合材料的二氧化碳脱氧催化剂，通过使用金属有机/聚合物复合物与亲水性聚合物键合的有机金属化合物，容易地对二氧化碳进行脱氧， 吡啶接头作为电化学催化剂。 构成：金属有机聚合物复合物包括通过吡啶接头与亲水性聚合物键合的有机金属化合物。 亲水性聚合物包含聚烯丙基胺基或聚乙烯基吡啶基聚合物。 金属有机/聚合物复合材料的制造方法包括以下步骤：使有机金属化合物与4-吡啶羧醛在溶剂中反应合成金属有机吡啶羧醛化合物，并使有机金属 - 吡啶甲醛化合物与亲水性聚合物反应，合成 通过吡啶接头与亲水性聚合物结合的金属有机/聚合物复合物。