公开(公告)号：KR1020080112746A

公开(公告)日：2008-12-26

申请号：KR1020070061534

申请日：2007-06-22

Applicant: 성균관대학교산학협력단

Inventor： 김덕준 ,  박의수

IPC: C08F220/00 ,  C08F220/18 ,  C08F230/02

CPC classification number: C08F230/02 ,  C08F2/44 ,  C08F220/14 ,  C08F2220/281

Abstract: A method for preparing polymethylmetacylates copolymerized with a permanent antistatic agent is provided to save the costs due to excellent performance and copolymerization feature of PMMA and to be used for an anti-static film, a construction material for durability and a packing material. A method for preparing an antistatic copolymer comprises (i) a step for synthesizing a acryl phosphate monomer by reacting a compound indicated as the chemical formula I and a compound indicated as the chemical formula II, with a monomethyl hydroquinone under the nitrogen atmosphere; (ii) a step for mixing the acryl phosphate monomer synthesized in the step (i) and methylmethacrylate in the presence of an initiator; and (iii) a step for performing copolymerization by heating the mixture of the step (ii).

Abstract translation: 提供一种制备与永久性抗静电剂共聚的聚甲基甲酸酯的方法，以节省由于PMMA的优异性能和共聚特性而引起的成本，并用于抗静电膜，耐久性结构材料和包装材料。 制备抗静电共聚物的方法包括：（i）在氮气氛下使化学式I表示的化合物与表示为化学式II的化合物与单甲基氢醌反应合成丙烯酸磷酸酯单体的步骤; （ii）将在步骤（i）中合成的丙烯酸磷酸酯单体和甲基丙烯酸甲酯在引发剂存在下混合的步骤; 和（iii）通过加热步骤（ii）的混合物进行共聚的步骤。

公开(公告)号：KR100931650B1

公开(公告)日：2009-12-14

申请号：KR1020070061534

申请日：2007-06-22

Applicant: 성균관대학교산학협력단

Inventor： 김덕준 ,  박의수

IPC: C08F220/00 ,  C08F220/18 ,  C08F230/02

Abstract: A method for preparing polymethylmetacylates copolymerized with a permanent antistatic agent is provided to save the costs due to excellent performance and copolymerization feature of PMMA and to be used for an anti-static film, a construction material for durability and a packing material. A method for preparing an antistatic copolymer comprises (i) a step for synthesizing a acryl phosphate monomer by reacting a compound indicated as the chemical formula I and a compound indicated as the chemical formula II, with a monomethyl hydroquinone under the nitrogen atmosphere; (ii) a step for mixing the acryl phosphate monomer synthesized in the step (i) and methylmethacrylate in the presence of an initiator; and (iii) a step for performing copolymerization by heating the mixture of the step (ii).

Abstract translation: 提供一种制备与永久性抗静电剂共聚的聚甲基丙烯酸酯的方法，由于PMMA优异的性能和共聚特性而节约成本，并用于抗静电膜，耐用建筑材料和包装材料。 用于制备抗静电共聚物的方法包括（i）通过在氮气氛下使化学式I所示的化合物和化学式II所示的化合物与单甲基氢醌反应来合成丙烯酸磷酸酯单体的步骤; （ii）将步骤（i）中合成的丙烯酰磷酸酯单体和甲基丙烯酸甲酯在引发剂存在下混合的步骤; 和（iii）通过加热步骤（ii）的混合物进行共聚的步骤。