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公开(公告)号：KR101432763B1
公开(公告)日：2014-10-01
申请号：KR1020130007107
申请日：2013-01-22
Applicant: 한국과학기술연구원 , 성균관대학교산학협력단
Abstract: 본 발명은 합성가스로부터 액체 탄화수소를 제조하는 피셔-트롭쉬 합성(Fischer-Tropsch synthesis ; FTS) 반응에 이용되는 촉매로 Al
2 O
3 -SiC
지지체에 코발트 전구체를 담지시켜 제조되는 코발트 담지촉매의 제조방법에 관한 것으로, 더욱 상세하게는 실리콘카바이드(silicon carbide, SiC)를 알콕시실란 화합물으로 미리 전처리하여 메조포러스한 기공을 형성시킨 후에 졸-겔법에 의해 알루미나(Al
2 O
3 ) 코팅하여 제조된 Al
2 O
3 -SiC
지지체상에 활성 성분으로서 코발트를 담지시켜 피셔-트롭쉬 합성용 코발트 담지촉매를 제조하는 방법에 관한 것이다. 본 발명의 코발트 담지촉매는 Al
2 O
3 -SiC
지지체의 비표면적이 크게 향상되면서 활성성분인 코발트의 분산성 증대 및 C
5 + 탄화수소 화합물의 선택성을 향상시키는 효과를 나타낸다.-
2.发明授权피셔-트롭시 합성용 코발트 담지 촉매의 제조 방법 및 고비점 액체 탄화수소의 공급을 통한 촉매의 재생 방법 有权通过加入高沸点液态烃制备用于费 - 托合成和催化剂再生的钴负载型催化剂的方法
公开(公告)号：KR101792630B1
公开(公告)日：2017-11-02
申请号：KR1020150101872
申请日：2015-07-17
Applicant: 성균관대학교산학협력단 , 한국과학기술연구원
Abstract: 본발명은피셔-트롭시합성용코발트담지촉매의제조방법및 고비점액체탄화수소의공급을통한촉매의재생방법에관한것으로, 더욱상세하게는카본블랙을하드템플레이트(hard template)로하여메조포러스구조의알루미나지지체를제조하고, 코발트를담지시켜비표면적이높은 FTS 반응용코발트담지촉매를제조하는방법과 FTS 반응생성물중의액체탄화수소의공급을통한상기촉매의실시간재생방법에관한것이다.
Abstract translation: 本发明的费 - 通过在托匹配音频处理用于制造钴担载催化剂，和高沸点通过液体烃的供给，并且更具体地说，涉及一种硬模板（硬模板）中孔结构的炭黑涉及催化剂的再生方法 制备氧化铝载体，并正在通过与液态烃在FTS反应产物供给的制造方法FTS钴的负载型催化剂用于反应的高比表面积支撑在催化剂的实时播放方法钴。
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公开(公告)号：KR1020140094363A
公开(公告)日：2014-07-30
申请号：KR1020130007107
申请日：2013-01-22
Applicant: 한국과학기술연구원 , 성균관대학교산학협력단
CPC classification number: B01J37/02 , B01J23/75 , B01J27/224 , B01J35/1014 , B01J37/08
Abstract: The present invention relates to a method of fabricating a supported cobalt catalyst fabricated by carrying a cobalt precursor in a Al_2O_3-SiC support as a catalyst used for a Fisher-Tropsch synthesis (FTS) which produces a liquid hydrocarbon from a synthetic gas and, more specifically, to a method of fabricating a supported cobalt catalyst for an FTS including: preprocessing a silicon carbide (SiC) with an alkoxysilane compound in advance to form mesoporous pores in the silicon carbide; and then carrying a cobalt as an active ingredient on an Al_2O_3-SiC support produced by coating the silicon carbide with an alumina (Al_2O_3) by a sol-gel process. According to the present invention, since a specific surface area of an Al_2O_3-SiC support is increased significantly, the effects of the dispersibility of the cobalt as an active ingredient is increased, and selectivity of a hydrocarbon compound C5+ improved.
Abstract translation: 本发明涉及一种通过在Al_2O_3-SiC载体中载带钴前体作为用于从合成气体产生液态烃的费 - 托合成（FTS）的催化剂制备的负载钴催化剂的方法， 具体地说，涉及制造用于FTS的负载钴催化剂的方法，包括：预先用烷氧基硅烷化合物预处理碳化硅（SiC）以在碳化硅中形成介孔孔; 然后在通过溶胶 - 凝胶法将氧化铝（Al_2O_3）涂覆碳化硅制成的Al_2O_3-SiC载体上作为活性成分载带钴。 根据本发明，由于Al_2O_3-SiC载体的比表面积显着增加，所以作为活性成分的钴的分散性提高，烃化合物C5 +的选择性提高。
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4.发明公开피셔-트롭시 합성용 코발트 담지 촉매의 제조 방법 및 고비점 액체 탄화수소의 공급을 통한 촉매의 재생 방법 有权- 钴基费 - 托催化剂的制备方法及其在FTS反应过程中形成的液态烃的再生方法
公开(公告)号：KR1020170010276A
公开(公告)日：2017-01-26
申请号：KR1020150101872
申请日：2015-07-17
Applicant: 성균관대학교산학협력단 , 한국과학기술연구원
Abstract: 본발명은피셔-트롭시합성용코발트담지촉매의제조방법및 고비점액체탄화수소의공급을통한촉매의재생방법에관한것으로, 더욱상세하게는카본블랙을하드템플레이트(hard template)로하여메조포러스구조의알루미나지지체를제조하고, 코발트를담지시켜비표면적이높은 FTS 반응용코발트담지촉매를제조하는방법과 FTS 반응생성물중의액체탄화수소의공급을통한상기촉매의실시간재생방법에관한것이다.
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公开(公告)号：KR101569638B1
公开(公告)日：2015-11-17
申请号：KR1020140184904
申请日：2014-12-19
Applicant: 성균관대학교산학협력단
CPC classification number: B01J35/10 , B01J23/75 , B01J29/064 , B01J35/1014 , B01J37/0018 , B01J37/0246 , B01J37/082
Abstract: 본발명은피셔-트롭쉬합성용메조다공성코발트산화물촉매및 이의제조방법에관한것으로서, 더욱상세하게는환원분위기하에서도메조구조의안정성증대에따른촉매의급속한비활성화가억제된피셔-트롭쉬합성용메조다공성코발트산화물촉매및 이의제조방법에관한것이다.
Abstract translation: 本发明涉及用于费 - 托合成的介孔氧化钴催化剂及其制造方法，更具体地说，涉及用于费 - 托合成的介孔钴氧化物催化剂及其制造方法，其被催化剂快速灭活抑制 关于在还原气氛下的介观结构的稳定性的增加。
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Patent Agency Ranking
公开(公告)号：KR101466470B1
公开(公告)日：2014-12-02
申请号：KR1020130025343
申请日：2013-03-08
Applicant: 성균관대학교산학협력단
IPC: B01J37/02 , B01J23/755 , B01J6/00
Abstract: 본발명은유기산이용해된용매에알루미나지지체를첨가하고함침및 건조하여유기산이처리된알루미나지지체를제조하는단계; 및상기알루미나지지체를니켈전구체가용해된용매에첨가하고함침및 건조하여코어-셀구조의니켈-알루미나촉매를제조하는단계를통하여제조된코어-셀구조의혼합개질반응용촉매및 이의제조방법에관한것이다. 이에따른, 코어-셀구조의혼합개질반응용니켈-알루미나촉매는 pKa 3.5 이하의유기산으로알루미나지지체를처리하여알루미나지지체기공에유기산을포함함으로써코어-셀구조를용이하게형성하여지지체표면에활성성분인니켈이고르게분포된촉매를제조할수 있다. 또한, 상기촉매는표면에니켈이고르게분포되어있는코어-셀구조를가짐으로써일반조건은물론높은공간속도의조건에서도안정성이높아반응활성이우수하며, 국부적으로가열된촉매내부에서일어나는니켈의소결현상을억제함으로써촉매의비활성화를억제하는효과가있다.
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公开(公告)号：KR1020140111229A
公开(公告)日：2014-09-18
申请号：KR1020140088952
申请日：2014-07-15
Applicant: 성균관대학교산학협력단
IPC: C01B3/40 , B01J23/755 , B01J8/00 , C10G2/00
CPC classification number: Y02P20/52 , C01B3/40 , B01J21/04 , B01J23/755 , C01B2203/0233 , C01B2203/0238 , C01B2203/1041 , C01B2203/1058 , C01B2203/1241
Abstract: The present invention relates to a catalyst having a core-shell structure for a mixed reforming reaction and to a method for producing the same. The method of the present invention comprises the steps of: preparing an alumina support in which organic acid is treated by adding, dipping, and drying the alumina support in a solvent in which organic acid is dissolved; and producing a nickel-alumina catalyst of a core-shell structure by adding, dipping, and drying the alumina support in a solvent in which a nickel precursor is dissolved. The nickel-alumina catalyst having a core-shell structure for a mixed reforming reaction includes organic acid in alumina support pores by treating the alumina support using organic acid of pKa 3.5 or less, so that a core-shell structure is easily formed and nickel which is an active ingredient can be evenly distributed on the surface of the support. Moreover, the catalyst has the core-shell structure having the surface on which nickel is evenly distributed, so that the catalyst has high stability and excellent reaction activities not only under general conditions but also in high spatial speed conditions. The sintering of nickel occurring in a partially heated catalyst is controlled so that the inactivation of the catalyst is inhibited.
Abstract translation: 本发明涉及具有混合重整反应的核 - 壳结构的催化剂及其制造方法。 本发明的方法包括以下步骤：制备氧化铝载体，其中通过在溶解有机酸的溶剂中加入，浸渍和干燥氧化铝载体来处理有机酸; 并通过在其中溶解镍前体的溶剂中加入，浸渍和干燥氧化铝载体来制备核 - 壳结构的镍 - 氧化铝催化剂。 具有用于混合重整反应的核 - 壳结构的镍 - 氧化铝催化剂包括通过使用pKa 3.5或更小的有机酸处理氧化铝载体的氧化铝载体孔中的有机酸，使得容易形成核 - 壳结构和镍 是一种活性成分，可均匀分布在支撑体的表面。 此外，催化剂具有镍 - 镍均匀分布的表面的核 - 壳结构，因此催化剂不仅在一般条件下而且在高空速条件下具有高稳定性和优异的反应活性。 控制在部分加热的催化剂中发生的镍的烧结，从而抑制催化剂的失活。
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公开(公告)号：KR101466541B1
公开(公告)日：2014-12-01
申请号：KR1020140088952
申请日：2014-07-15
Applicant: 성균관대학교산학협력단
IPC: C01B3/40 , B01J23/755 , B01J8/00 , C10G2/00
Abstract: 본 발명은 유기산이 용해된 용매에 알루미나 지지체를 첨가하고 함침 및 건조하여 유기산이 처리된 알루미나 지지체를 제조하는 단계; 및 상기 알루미나 지지체를 니켈 전구체가 용해된 용매에 첨가하고 함침 및 건조하여 코어-셀 구조의 니켈-알루미나 촉매를 제조하는 단계를 통하여 제조된 코어-셀 구조의 혼합개질 반응용 촉매 및 이의 제조방법에 관한 것이다. 이에 따른, 코어-셀 구조의 혼합개질 반응용 니켈-알루미나 촉매는 pKa 3.5 이하의 유기산으로 알루미나 지지체를 처리하여 알루미나 지지체 기공에 유기산을 포함함으로써 코어-셀 구조를 용이하게 형성하여 지지체 표면에 활성 성분인 니켈이 고르게 분포된 촉매를 제조할 수 있다.
또한, 상기 촉매는 표면에 니켈이 고르게 분포되어 있는 코어-셀 구조를 가짐으로써 일반 조건은 물론 높은 공간속도의 조건에서도 안정성이 높아 반응 활성이 우수하며, 국부적으로 가열된 촉매 내부에서 일어나는 니켈의 소결 현상을 억제함으로써 촉매의 비활성화를 억제하는 효과가 있다.-
公开(公告)号：KR1020140110660A
公开(公告)日：2014-09-17
申请号：KR1020130025343
申请日：2013-03-08
Applicant: 성균관대학교산학협력단
IPC: B01J37/02 , B01J23/755 , B01J6/00
CPC classification number: B01J37/0201 , B01J23/755 , B01J37/08
Abstract: The present invention relates to a catalyst with a core-shell structure for mixed reforming reaction manufactured by the steps of: manufacturing an alumina support treated with an organic acid by adding an alumina support to a solvent which carries an organic acid dissolved therein and impregnating and drying the alumina support; and manufacturing a nickel-alumina catalyst with a core-shell structure by adding the alumina support to a solvent which carries nickel precursors dissolved therein and impregnating and drying the alumina support. In addition, the present invention relates to a manufacturing method thereof. Accordingly, the catalyst having an active component of nickel distributed evenly on the surface of the support can be manufactured as the nickel-alumina catalyst with a core-shell structure for mixed reforming reaction includes the organic acid in the pores of the alumina support thanks to the alumina support treated with an organic acid with a pKa of 3.5 or lower, thereby forming the core-shell structure easily. Also, the catalyst has high stability not only under general conditions but also under the conditions of high spatial speed, thereby having high reaction activity as the catalyst has the core-shell structure of nickel distributed evenly on the surface of the catalyst. In addition, the inactivation of the catalyst is inhibited by inhibiting the sintering of nickel, which is generated inside a locally heated catalyst.
Abstract translation: 本发明涉及一种具有用于混合重整反应的核 - 壳结构的催化剂，其通过以下步骤制备：制备用有机酸处理的氧化铝载体，通过将氧化铝载体加入到溶解有机酸的溶剂中并浸渍， 干燥氧化铝载体; 并通过将氧化铝载体加入到溶解有镍前体的溶剂中并浸渍和干燥氧化铝载体来制造具有核 - 壳结构的镍 - 氧化铝催化剂。 此外，本发明涉及其制造方法。 因此，具有均匀分布在载体表面上的镍的活性组分的催化剂可以制备为具有用于混合重整反应的核 - 壳结构的镍 - 氧化铝催化剂，包括氧化铝载体的孔中的有机酸，由于 用pKa为3.5以下的有机酸处理的氧化铝载体，容易形成核 - 壳结构。 此外，催化剂不仅在一般条件下而且在高空间速度的条件下具有高稳定性，因此具有高的反应活性，因为催化剂的镍 - 壳结构均匀分布在催化剂的表面上。 此外，通过抑制在局部加热的催化剂内产生的镍的烧结来抑制催化剂的失活。
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公开(公告)号：KR1020140028503A
公开(公告)日：2014-03-10
申请号：KR1020120094924
申请日：2012-08-29
Applicant: 한국과학기술연구원
CPC classification number: B01J27/224 , B01J21/04 , B01J21/12 , B01J23/75 , B01J35/002 , B01J35/1014 , B01J35/1061 , B01J35/109 , B01J37/0201 , B01J37/0244 , B01J37/031 , C10G2/33
Abstract: The present invention relates to a bimodal porous Co/Al_2O_3/SiC catalyst for Fischer-Tropsch reaction using an Al_2O_3/SiC support, which is manufactured by coating silicon carbide (SiC) having excellent thermoconductivity with alumina, as a catalyst having excellent heat and material transfer, and having cobalt (Co) supported as an active component; and a manufacturing method thereof. The present invention relates to a method for improving a stability of the catalyst and for increasing a conversion rate of syngas (carbon monoxide and hydrogen) by using the Al_2O_3/SiC support to enhance the dispersion of cobalt and interaction between the cobalt and the support, which inhibits a generation of cokes (filament carbon). [Reference numerals] (AA) Comparative example 1; (BB) Example 1
Abstract translation: 本发明涉及使用Al_2O_3 / SiC载体的用于费 - 托反应的双峰多孔Co / Al_2O_3 / SiC催化剂，其通过将具有优异的导热性的氧化铝的碳化硅（SiC）作为具有优异的热和材料的催化剂 转移，并具有作为活性组分的钴（Co）负载; 及其制造方法。 本发明涉及通过使用Al_2O_3 / SiC载体来提高催化剂稳定性和提高合成气（一氧化碳和氢气）的转化率以增强钴的分散和钴与载体之间的相互作用的方法， 其抑制焦炭的产生（细丝碳）。 （附图标记）（AA）比较例1; （BB）实施例1
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