公开(公告)号：KR101300141B1

公开(公告)日：2013-08-26

申请号：KR1020110080117

申请日：2011-08-11

Applicant: 재단법인대구경북과학기술원

Inventor： 김참 ,  김동환 ,  김종숙 ,  김호영

IPC: H01L35/34 ,  H01L35/14 ,  H01L35/16 ,  H01L35/18

Abstract: Bi 및 Sb 전구체를 용매 중에 투입하여 Bi-Sb 용액을 형성하는 단계, Te 분말을 산과 용매의 혼합용액에 투입하여 Te 용액을 형성하는 단계, 상기 Bi-Sb 용액과 상기 Te 용액을 혼합하여 반응시켜 Bi
x Sb
2 -xTe
3 반응물을 형성하는 단계, 상기 Bi
x Sb
2 -xTe
3 반응물을 여과 및 건조하여 Bi
x Sb
2 -xTe
3 나노입자를 얻는 단계, 및 상기 Bi
x Sb
2 -xTe
3 나노입자를 열처리하는 단계를 포함하는 나노화합물 열전재료 제조방법이 제공된다.

公开(公告)号：KR1020130036638A

公开(公告)日：2013-04-12

申请号：KR1020110100841

申请日：2011-10-04

Applicant: 재단법인대구경북과학기술원

Inventor： 김참 ,  김종숙 ,  김동환 ,  김호영

IPC: H01L35/34 ,  H01L35/16 ,  H01L35/18

CPC classification number: H01L35/12 ,  H01L35/16 ,  H01L35/18 ,  H01L35/24 ,  H01L35/34

Abstract: PURPOSE: A method for manufacturing BixTe3-ySey nanocompound thermoelectric materials and the nanocompound thermoelectric materials manufactured by the same are provided to control a temperature to show the maximum thermoelectric performance index by controlling the charge carrier density of a nanocompound. CONSTITUTION: Bi(III)-stabilizer complex solutions are made by injecting a Bi precursor, a reducing agent, and a stabilizer into solvents(A1). BixTe3-ySey is made by reacting a Te precursor with the Bi(III)-stabilizer complex solutions(A2). BixTe3-ySey nanoparticles are obtained by filtering and drying the BixTe3-ySey(A3). The BixTe3-ySey nanoparticles are thermally processed(A4). [Reference numerals] (A1) Making Bi(III)-stabilizer complex solutions; (A2) Forming BixTe3-ySey by reacting a Te precursor with the Bi(III)-stabilizer complex solutions; (A3) Obtaining BixTe3-ySey nanoparticles by filtering and drying the BixTe3-ySey; (A4) Thermally processing the BixTe3-ySey nanoparticles; (AA) Start; (BB) End;

Abstract translation: 目的：提供一种制造BixTe3-ySey纳米复合热电材料的方法及其制造的纳米复合热电材料，以通过控制纳米复合材料的载流子密度来控制温度显示最大热电性能指标。 构成：通过将Bi前体，还原剂和稳定剂注入溶剂（A1）中制备Bi（III） - 稳定剂络合物溶液。 BixTe3-ySey是通过使Te前体与Bi（III） - 稳定剂络合物溶液（A2）反应来制备的。 通过过滤和干燥BixTe3-ySey（A3）获得BixTe3-ySey纳米颗粒。 BixTe3-ySey纳米粒子经热处理（A4）。 （A1）制备Bi（III） - 稳定剂复合溶液; （A2）通过使Te前体与Bi（III）稳定剂络合物溶液反应形成BixTe3-ySey; （A3）通过过滤和干燥BixTe3-ySey获得BixTe3-ySey纳米颗粒; （A4）热处理BixTe3-ySey纳米粒子; （AA）开始; （BB）结束;

公开(公告)号：KR1020130017589A

公开(公告)日：2013-02-20

申请号：KR1020110080117

申请日：2011-08-11

Applicant: 재단법인대구경북과학기술원

Inventor： 김참 ,  김동환 ,  김종숙 ,  김호영

IPC: H01L35/34 ,  H01L35/14 ,  H01L35/16 ,  H01L35/18

CPC classification number: H01L35/14 ,  H01L35/16 ,  H01L35/18 ,  H01L35/24 ,  H01L35/34

Abstract: PURPOSE: A method for manufacturing BixSb2-xTe3 nanocompound thermoelectric materials and the nanocompound thermoelectric materials manufactured by the same are provided to increase a thermoelectric performance index by synthesizing BixSb2-xTe3 nanocompounds for a low temperature through a wet chemical process. CONSTITUTION: Bi-Sb solutions are made by injecting a Bi and Sb precursor to solvents(A1). Te solutions are made by injecting Te powder to mixture of acid and solvents(A2). BixSb2-xTe3 reactants are made by mixing the Bi-Sb solutions with the Te solutions(A3). BixSb2-xTe3 nanoparticles are obtained by filtering and drying the BixSb2-xTe3 reactants(A4). The BixSb2-xTe3 nanoparticles are thermally processed(A5). [Reference numerals] (A1) Forming Bi-Sb solutions; (A2) Making Te solutions; (A3) Reacting between the Bi-Sb solutions and Te solutions; (A4) Obtaining BixSb2-xTe3 nanoparticles by filtering and drying; (A5) Thermally processing the BixSb2-xTe3 nanoparticles; (AA) Start; (BB) End

Abstract translation: 目的：提供一种制造BixSb2-xTe3纳米复合热电材料的方法及其制造的纳米复合热电材料，以通过湿化学工艺合成BixSb2-xTe3纳米复合材料，以提高低温的热电性能指标。 构成：通过将Bi和Sb前体注入到溶剂（A1）中来制备Bi-Sb溶液。 Te溶液是通过将Te粉末注入到酸和溶剂（A2）的混合物中制成的。 BixSb2-xTe3反应物是通过将Bi-Sb溶液与Te溶液（A3）混合来制备的。 通过过滤和干燥BixSb2-xTe3反应物（A4）获得BixSb2-xTe3纳米颗粒。 BixSb2-xTe3纳米粒子经热处理（A5）。 （A1）形成Bi-Sb溶液; （A2）制作Te溶液; （A3）Bi-Sb溶液与Te溶液之间的反应; （A4）通过过滤和干燥获得BixSb2-xTe3纳米颗粒; （A5）热处理BixSb2-xTe3纳米粒子; （AA）开始; （BB）结束