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公开(公告)号：KR100787057B1
公开(公告)日：2007-12-21
申请号：KR1020060001548
申请日：2006-01-06
Applicant: 재단법인서울대학교산학협력재단
Abstract: 본 발명은 하기 화학식 1의 단위구조를 갖는 중합체, 그의 제조 방법, 및 그들의 분자 흡착 매체, 발광 매체, 또는 촉매로서의 특징에 관한 것이다.
[Co
II
2 (μ-OH)
2 Co
III
2 (μ-OH
2 )
2 MTB
2 (H
2 O)
n ]·xA·yB
상기 식에서
n은 0 내지 4 범위의 수이고,
x는 0 내지 20 범위의 수이며,
y는 0 내지 20 범위의 수이고,
A 및 B는 각각 독립적으로 디메틸포름아미드(DMF), 톨루엔, 벤젠, 피리딘, 테트라하이드로푸란(THF), 에탄올, 메탄올, 포름아마이드, 메틸포름아마이드, 에틸포름아마이드, 프로필포름아마이드, 부틸포름아마이드, 디메틸포름아마이드, 디에틸포름아마이드, 디프로필포름아마이드, 디부틸포름아마이드, 디에틸에테르, 메탄올, 에탄올, 프로판올, 메틸아민, 디메틸아민, 트리메틸아민, 에틸아민, 디에틸아민, 트리에틸아민, 디메틸설폭사이드, 물, 벤젠, 클로로벤젠, 톨루엔, 페놀, 피리딘 및 물로 구성된 그룹중에서 선택된 용매 분자를 나타낸다.
코발트, 분자 흡착제, 게스트 교환, 발광, 불균일 촉매제, 다공성 유기-금속 골격체-
公开(公告)号：KR1020070074014A
公开(公告)日：2007-07-12
申请号：KR1020060001548
申请日：2006-01-06
Applicant: 재단법인서울대학교산학협력재단
CPC classification number: C07F15/065 , C07C51/418 , C08F4/80
Abstract: Provided is a porous metal-organic polymer, which maintains an opened structure even after removing guest solvent molecules to show permanent porosity, and is useful as a molecular adsorption medium, light emission medium or catalyst. The porous metal-organic polymer has a repeating unit represented by the formula of [Co^II_2(mu-OH)_2Co^III_2(mu-OH_2)_2MTB_2(H_2O)_n].xA.yB, wherein n is a number of 0-4; x is a number of 0-20; y is a number of 0-20; and each of A and B independently represents a solvent molecule selected from the group consisting of dimethylformamide, toluene, benzene, pyridine, tetrahydrofuran, ethanol, methanol, formamide, methylformamide, ethylformamide, propylformamide, butylformamide, dimethylformamide, diethylformamide, dipropylformamide, dibutylformamide, diethyl ether, propanol, methylamine, dimethylamine, trimethyamine, ethylamine, diethylamine, triethylamine, dimethyl sulfoxide, water, chlorobenzene and phenol.
Abstract translation: 提供一种多孔金属有机聚合物，即使在除去客体溶剂分子以显示永久孔隙率之后也保持开放结构，并且可用作分子吸附介质，发光介质或催化剂。 多孔金属 - 有机聚合物具有由式[Co 2 II 2（mu-OH）2 Co 3 III 2（μ-OH 2）2 MTB 2（H 2 O）] n] x A y Y y表示的重复单元，其中n是0 -4; x是0-20的数; y是0-20的数; A和B各自独立地表示选自二甲基甲酰胺，甲苯，苯，吡啶，四氢呋喃，乙醇，甲醇，甲酰胺，甲基甲酰胺，乙基甲酰胺，丙基甲酰胺，丁基甲酰胺，二甲基甲酰胺，二乙基甲酰胺，二丙基甲酰胺，二丁基甲酰胺，二乙基 乙醚，丙醇，甲胺，二甲胺，三甲胺，乙胺，二乙胺，三乙胺，二甲基亚砜，水，氯苯和苯酚。
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公开(公告)号：KR1020080080870A
公开(公告)日：2008-09-05
申请号：KR1020070021142
申请日：2007-03-02
Applicant: 재단법인서울대학교산학협력재단
IPC: C07F3/06
CPC classification number: C07F3/06 , B01D53/04 , B01D2253/204 , B01J20/226
Abstract: A metal-organic framework is provided to have permanent porosity, be thermally stable at high temperature, show blue light emitting property and excellent storage capability regarding gaseous molecules such as nitrogen, hydrogen, CO2 and methane, thereby being used to a technique of isolating CO2 from gases emitted from factories, a technique of isolating H and methane gas from natural gases and a molecule sensor field utilizing the inner structure change during desolvation. A metal-organic framework has a structure unit represented by a formula(1) of [Zn3(NTB)2(SOL)2]. x(SOL), wherein NTB is 4,4',4"-nitrilotrisbenzoate, SOL is a solvent molecule, and x is an integer from 0 to 4. A method for preparing the metal-organic framework comprises a step of subjecting a Zn(II) compound and 4,4',4"-nitrilotrisbenzoic acid or a derivative thereof in the presence of a solvent to hydrothermal reaction at a temperature of 70-150 deg.C for 12-36 hours. Further, the SOL is ethanol and the solvent is ethanol.
Abstract translation: 提供金属 - 有机骨架以具有永久性孔隙率，在高温下是热稳定的，显示蓝色发光性能和对气态分子如氮气，氢气，二氧化碳和甲烷的优异储存能力，从而被用于分离CO 2的技术 从工厂排放的气体，从天然气中分离出H和甲烷气体的技术以及利用内部结构在分解过程中变化的分子传感器场。 金属 - 有机骨架具有由[Zn 3（NTB）2（SOL）2]的式（1）表示的结构单元。 x（SOL），其中NTB为4,4'，4“ - 次氮基三苯甲酸酯，SOL为溶剂分子，x为0至4的整数。一种制备金属 - 有机骨架的方法包括使Zn （II）化合物和4,4'，4“ - 次氮基三苯甲酸或其衍生物在溶剂存在下进行水热反应，在70-150℃的温度下反应12-36小时。 此外，SOL是乙醇，溶剂是乙醇。
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