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公开(公告)号:KR101226191B1
公开(公告)日:2013-01-24
申请号:KR1020110027663
申请日:2011-03-28
Applicant: 전남대학교산학협력단
Abstract: 본 발명은 탄소섬유 및 그 제조방법에 관한 것으로, 리그닌을 단량체 화합물과 공중합하여 제조된 리그닌계 공중합체를 이용하여 탄소섬유를 제조함으로써, 고가의 단량체 화합물의 합량을 줄이고 탄화 수율을 향상시켜 저가로 탄소섬유를 제조할 수 있는 리그닌계 공중합체를 이용한 탄소섬유제조방법 및 그 방법으로 제조된 탄소섬유에 관한 것이다.
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公开(公告)号:KR1020120109227A
公开(公告)日:2012-10-08
申请号:KR1020110027663
申请日:2011-03-28
Applicant: 전남대학교산학협력단
CPC classification number: D01F9/17 , D01D1/02 , D01D1/065 , D01D5/06 , D01D10/02 , D01F2/24 , D01F6/78 , D10B2101/12
Abstract: PURPOSE: A carbon fiber and a method for fabricating the same are provided to improve carbonization yield and to cheaply obtain the carbon fiber. CONSTITUTION: A method for fabricating carbon fibers using a lignin-based copolymer comprises: a step of synthesizing the lignin-based copolymer; a step of preparing lignin-base copolymer spinning solution containing 10-50 wt% of the synthesized lignin-based copolymers; a step of wet-spinning the spinning solution to obtain a wet-spun fiber; a step of oxidation-stabilizing of the wet-spun fiber; and a step of carbonizing the stabilized fibers. A step of synthesizing the lignin-based copolymer comprises: a step of dissolving lignin and anhydrous halogen salt to prepare a lignin solution; a step of adding oxidation/reduction inhibitor to the lignin solution; a step of adding monomer compounds or monomer compound-dissolved solution to the lignin solution and performing graft copolymerization; and a step of terminating the graft copolymerization and drying the lignin-based copolymer. [Reference numerals] (AA) Lignin/AN; (BB) Lignin copolymer; (CC) Wet spinning; (DD) Thermal treatment; (EE) Lignin-based carbon fiber
Abstract translation: 目的:提供碳纤维及其制造方法,以提高碳化收率并廉价地获得碳纤维。 构成:使用木质素类共聚物制造碳纤维的方法包括:合成木质素类共聚物的工序; 制备含有10-50重量%的木质素基共聚物的木素基共聚物纺丝溶液的步骤; 将纺丝溶液湿纺以获得湿纺纤维的步骤; 湿纺纤维的氧化稳定步骤; 以及将稳定纤维碳化的步骤。 合成木素基共聚物的步骤包括:将木质素和无水卤素盐溶解以制备木质素溶液的步骤; 向木质素溶液中加入氧化/还原抑制剂的步骤; 将单体化合物或单体化合物溶解溶液加入到木质素溶液中并进行接枝共聚的步骤; 以及终止接枝共聚和干燥木质素基共聚物的步骤。 (AA)木质素/ AN; (BB)木质素共聚物; (CC)湿纺; (DD)热处理; (EE)木质素基碳纤维
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