-
公开(公告)号：KR100478437B1
公开(公告)日：2005-03-23
申请号：KR1020020081322
申请日：2002-12-18
Applicant: 제일모직주식회사
IPC: C08L51/00
Abstract: 본원발명의 광택도가 낮고 유동성이 우수한 열가소성 수지 조성물은 (A)부타디엔계 고무 30∼70 중량%와 방향족비닐계 단량체 및 불포화 니트릴계 단량체의 혼합물 70∼30 중량%를 그라프트 공중합하여 얻어지는 그라프트 공중합체; (B)중량평균분자량이 50,000∼200,000인 시안화비닐화합물과 방향족비닐화합물의 공중합체; (C)중량평균분자량이 1,000,000∼2,000,000인 시안화비닐화합물과 방향족비닐화합물의 고분자량 공중합체; 및 (D)중량평균분자량이 2,000,000∼5,000,000인 시안화비닐화합물과 방향족비닐화합물의 초고분자량 공중합체로 이루어지고, 상기 (A)성분이 20∼50 중량부, (B)+(C)가 50∼80 중량부, 그리고 (D)성분이 0.1∼10 중량부로 구성되는 것을 특징으로 한다.
-
公开(公告)号：KR100474830B1
公开(公告)日：2005-03-08
申请号：KR1020010081715
申请日：2001-12-20
Applicant: 제일모직주식회사
IPC: C08L51/04
Abstract: 본 발명의 스티렌계 열가소성 수지 조성물은 (A) 고무입자 크기가 1000Å∼5000Å의 크기를 갖는 폴리부타디엔 라텍스 30-60 중량부, 아크릴로니트릴 10-30 중량부 및 스티렌 70-90 중량부를 유화중합하여 제조된 그라프트 공중합체 10-50 중량%; (B) 시안화비닐화합물 20-40 중량부 및 방향족비닐화합물 60-80 중량부를 중합하여 제조된 시안화 비닐-방향족 비닐계 공중합체 40-80 중량%; 및 (C) 시안화비닐화합물 20-40 중량부 및 방향족비닐화합물 60-80 중량부로 이루어진 단량체 혼합물 100 중량부에 대하여, 다관능성 비닐벤젠계 화합물0.01-2.0 중량부 및 도데실 머캡탄과 다관능성 머캡탄의 혼합물 0.01-2.0 중량부를 투입하여 제조된 중량 평균 분자량이 700,000-1,800,000의 범위의 비선형 구조를 갖는 초고분자량 공중합체 0.5-50 중량%로 이루어진다.
-
公开(公告)号：KR100413089B1
公开(公告)日：2003-12-31
申请号：KR1020010045121
申请日：2001-07-26
Applicant: 제일모직주식회사
IPC: C08L55/02
CPC classification number: C08L51/04 , C08F279/02 , C08F279/04 , C08K3/01 , C08K3/22 , C08L25/12 , C08L55/02 , C08L2205/02 , C08L2666/02 , C08L2666/04 , C08L2666/06
Abstract: 본 발명의 열가소성 수지 조성물은 (A) 고무질 중합체에 시안화 비닐 화합물과 방향족 비닐 화합물을 공중합하여 얻어진 그라프트 공중합체 20-60 중량부; (B) 시안화 비닐 화합물과 방향족 비닐 화합물을 공중합하여 얻어진 공중합체 40-80 중량부; (C) 2가 금속화합물 0.1-2 중량부; 및 (D) 시안화 비닐 화합물과 방향족 비닐 화합물을 공중합하여 얻은 중량 평균 분자량이 1,000,000-5,000,000인 초고분자량 공중합체 0.1-30 중량부로 이루어진다.
Abstract translation: 本发明的热塑性树脂组合物包含：（A）20-60重量份的与氰化乙烯基化合物和芳族乙烯基化合物共聚到橡胶状聚合物上的接枝共聚物; （B）80-40重量份与氰化乙烯基化合物和芳族乙烯基化合物共聚的共聚物; （C）0.1-2重量份的+2价金属化合物; 和（D）0.1-30重量份与氰化乙烯基化合物和芳族乙烯基化合物共聚的超大分子共聚物，其重均分子量为约1,000,000至约5,000,000。
-
公开(公告)号：KR1020030056030A
公开(公告)日：2003-07-04
申请号：KR1020010086183
申请日：2001-12-27
Applicant: 제일모직주식회사
CPC classification number: C08L51/04 , C08J2300/22 , C08K3/10 , C08K5/098 , C08L25/12 , C08L2203/16
Abstract: PURPOSE: A thermoplastic resin composition is provided, which is improved in the extrusion stability, the workability and the stability to decomposition, crosslinking, gelation, networking and carbonization and is free from the surface damage. CONSTITUTION: The thermoplastic resin composition comprises 100 parts by weight of a base resin comprising 20-50 wt% of a graft copolymer and 50-80 wt% of a SAN copolymer comprising 50-90 wt% of an aromatic vinyl-based monomer and 10-50 wt% of an unsaturated nitrile-based monomer; 0.1-2 parts by weight of a metal compound selected from the group consisting of a salt of divalent metal, a chloride of divalent metal, a carbonate of divalent metal, an oxide of divalent metal and their mixture; and 0.1-1 parts by weight of a stearate compound. The graft copolymer comprises 30-70 wt% of a butadiene-based rubber whose rubber particle content having a size of 500-3,500 Angstrom is 90% or more and whose gel content is 50 % or more and 30-70 wt% of a kind of an aromatic vinyl-based monomer and a kind of an unsaturated nitrile-based monomer, and has a degree of grafting of 50-100 % and a weight average molecular weight of 50,000-100,000.
Abstract translation: 目的：提供热塑性树脂组合物，其提高了挤出稳定性，加工性和分解，交联，凝胶化，联网和碳化的稳定性，并且没有表面损伤。 构成：热塑性树脂组合物包含100重量份的包含20-50重量％的接枝共聚物的基础树脂和50-80重量％的包含50-90重量％的芳族乙烯基类单体的SAN共聚物和10重量％ -50重量％的不饱和腈基单体; 0.1-2重量份选自二价金属盐，二价金属氯化物，二价金属碳酸盐，二价金属氧化物及其混合物的金属化合物; 和0.1-1重量份的硬脂酸酯化合物。 接枝共聚物包含30-70重量％的橡胶颗粒含量为500-3,500埃的丁二烯橡胶，其含量为90％以上，凝胶含量为50〜30重量％，种类为30〜70重量％ 的芳族乙烯基类单体和一种不饱和腈基单体，并且接枝度为50-100％，重均分子量为50,000-100,000。
-
公开(公告)号：KR1020030010239A
公开(公告)日：2003-02-05
申请号：KR1020010045121
申请日：2001-07-26
Applicant: 제일모직주식회사
IPC: C08L55/02
CPC classification number: C08L51/04 , C08F279/02 , C08F279/04 , C08K3/01 , C08K3/22 , C08L25/12 , C08L55/02 , C08L2205/02 , C08L2666/02 , C08L2666/04 , C08L2666/06
Abstract: PURPOSE: Provided is a thermoplastic resin composition excellent in extrusion-stability and extrusion-processability, which dose not have the change of extrusion amount, the lack of thickness uniformity, and scratches. CONSTITUTION: The thermoplastic resin composition comprises: 20-60pts.wt. of a graft copolymer obtained by copolymerizing a vinyl cyanide compound and an aromatic vinyl compound into a rubber polymer, wherein the graft copolymer has a graft rate of 50-100% and a weight average molecular weight of 50,000-100,000; 40-80pts.wt. of a copolymer obtained by copolymerizing a vinyl cyanide compound and an aromatic vinyl compound; 0.1-2pts.wt. of a divalent metal compound; 0.1-30pts.wt. of an ultrahigh molecular weight copolymer obtained by copolymerizing a vinyl cyanide compound and an aromatic vinyl compound and having an average molecular weight of 1,000,000-5,000,000.
Abstract translation: 目的：提供挤出稳定性和挤出加工性优异的热塑性树脂组合物，其不会产生挤出量的变化，缺乏厚度均匀性和划痕。 构成：热塑性树脂组合物包含：20-60pts.wt。 通过将乙烯基氰化合物和芳族乙烯基化合物共聚合成橡胶聚合物而获得的接枝共聚物，其中接枝共聚物的接枝率为50-100％，重均分子量为50,000-100,000; 40-80pts.wt。 通过使乙烯基氰化合物和芳族乙烯基化合物共聚获得的共聚物; 0.1-2pts.wt。 的二价金属化合物; 0.1-30pts.wt。 通过共聚乙烯基氰化合物和芳香族乙烯基化合物而得到的超高分子量共聚物，其平均分子量为1,000,000-5,000,000。
-
Patent Agency Ranking
公开(公告)号：KR1020020050475A
公开(公告)日：2002-06-27
申请号：KR1020000079629
申请日：2000-12-21
Applicant: 제일모직주식회사
CPC classification number: C08L25/12 , C08L51/04 , C08L55/02 , C08L2205/02 , C08L2666/02 , C08L2666/24 , C08L2666/04
Abstract: PURPOSE: Provided is a thermoplastic resin composition excellent in chemical-resistance, vacuum formability, impact-resistance, and strength, which can be used for the inside wall and the door interior of a refrigerator. CONSTITUTION: The thermoplastic resin composition comprises: (A) a graft polymer graft-polymerized by emulsion-polymerizing 20-60pts.wt. of a diene synthetic rubber and 100pts.wt. of a mixture comprising 20-30wt% of a vinyl cyanide compound and 80-70wt% of an aromatic vinyl compound; (B) a graft polymer graft-polymerized by emulsion-polymerizing 20-60pts.wt. of an acryl synthetic rubber and 100pts.wt. of the mixture comprising 20-30wt% of the vinyl cyanide compound and 70-80wt% of the aromatic vinyl compound; (C) a linear vinyl cyanide compound-aromatic vinyl compound copolymer produced by copolymerizing 40-50wt% of the vinyl cyanide compound and 60-50wt% of the aromatic vinyl compound; (D) a branched vinyl cyanide compound-aromatic vinyl compound copolymer produced by copolymerizing 30-35wt% of the vinyl cyanide compound and 70-65wt% of the aromatic vinyl compound, wherein the weight ratio of (A)+(B):(C)+(B) is 50:50-20:80, the weight ratio of (A):(B) is 10:1-1:1, and the weight ratio of (C):(D) is 10:1-5:1. The vinyl cyanide compound is acrylonitrile or methacrylonitrile and the aromatic vinyl compound is selected from the group consisting of styrene, alpha-methylstyrene, p-methylstyrene, vinyl xylene, and etc.
Abstract translation: 目的：提供可用于冰箱的内壁和门内部的耐化学性，真空成型性，耐冲击性和强度优异的热塑性树脂组合物。 构成：热塑性树脂组合物包含：（A）通过乳液聚合20-60pts.wt。接枝聚合的接枝聚合物。 的二烯合成橡胶和100pts.wt。 的混合物，其包含20-30重量％的乙烯基氰化合物和80-70重量％的芳族乙烯基化合物; （B）通过乳液聚合20-60pts.wt。接枝聚合的接枝聚合物。 的丙烯酸合成橡胶和100pts.wt。 的混合物包含20-30重量％的乙烯基氰化合物和70-80重量％的芳族乙烯基化合物; （C）通过共聚40-50重量％的乙烯基氰化合物和60-50重量％的芳族乙烯基化合物制备的线性乙烯基氰化合物 - 芳族乙烯基化合物共聚物; （D）通过使30-35重量％的乙烯基氰化合物和70-65重量％的芳族乙烯基化合物共聚制备的支化乙烯基氰化合物 - 芳族乙烯基化合物共聚物，其中（A）+（B）:( C）+（B）为50:50〜20:80，（A）:( B）的重量比为10:1-1:1，（C）:( D）的重量比为10： 1-5：1。 乙烯基氰化合物是丙烯腈或甲基丙烯腈，芳族乙烯基化合物选自苯乙烯，α-甲基苯乙烯，对甲基苯乙烯，乙烯基二甲苯等。
-
公开(公告)号：KR1020050063133A
公开(公告)日：2005-06-28
申请号：KR1020030094484
申请日：2003-12-22
Applicant: 제일모직주식회사
IPC: C08L53/02
Abstract: 본 발명의 스티렌계 수지 조성물은 (A) 방향족비닐-불포화니트릴-부타디엔 그라프트 공중합체 20-50 중량% 및 (B) 방향족비닐-불포화니트릴 공중합체 50-80 중량%로 이루어진 기초수지 100 중량부에 대하여, (C
1 ) 포도상 응집고무입자 1-10 중량부; 및 (C
2 )중량평균분자량이 500,000 이상인 스티렌-아크릴로니트릴-메틸메타아크릴레이트의 2성분 또는 3성분으로 이루어진 공중합체 또는 단일 중합체로 선택되는 고분자량 첨가제 1-5 중량부로 이루어진다.-
公开(公告)号：KR100474817B1
公开(公告)日：2005-03-10
申请号：KR1020020074625
申请日：2002-11-28
Applicant: 제일모직주식회사
Abstract: 본 발명의 스티렌계 수지 조성물은 (A) 방향족비닐-불포화니트릴-부타디엔 그라프트 공중합체 20-50 중량% 및 (B) 방향족비닐-불포화니트릴 공중합체 50-80 중량%로 이루어진 기초수지 100 중량부에 대하여, (C) 저광용 첨가제로 (c1)중량평균분자량이 500,000 이상인 스티렌-아크릴로니트릴-메틸메타아크릴레이트의 2성분 또는 3성분으로 이루어진 공중합체 또는 단일 중합체로 선택되는 상용성 첨가제 1-10 중량부 및 (c2) CaCO3 또는 TiO2,로 선택되는 비상용성 첨가제 1-14 중량부로 이루어지며, 상기 저광용 첨가제는 기초수지 100 중량부에 대하여 10-15 중량부로 첨가된다.
-
公开(公告)号：KR100450110B1
公开(公告)日：2004-09-24
申请号：KR1020010083123
申请日：2001-12-22
Applicant: 제일모직주식회사
Abstract: PURPOSE: A styrene-based thermoplastic resin composition is provided, which exhibits excellent vacuum moldability and improved elongation and fluidity by employing a superhigh molecular weight SAN copolymer having a nonlinear structure. CONSTITUTION: The thermoplastic resin composition comprises 20-50 wt% of a graft copolymer which is prepared by graft polymerizing 30-70 wt% of a mixture of an aromatic vinyl-based monomer and a cyanovinyl-based monomer to 30-70 wt% of a butadiene-based rubber, and has an average weight molecular weight of 50,000-100,000; 40-70 wt% of a styrene-acrylonitrile copolymer which is prepared by copolymerizing 50-90 wt% of an aromatic vinyl-based monomer and 10-50 wt% of a cyanovinyl-based monomer, and has an average weight molecular weight of 100,000-300,000; and 0.1-30 wt% of a copolymer which is prepared by adding 0.01-5 parts by weight of a multifunctional mercaptan and 0.005-5 parts by weight of a multifunctional acryl-based monomer to 100 parts by weight of a monomer mixture comprising 50-90 wt% of an aromatic vinyl-based monomer and 10-50 wt% of a cyanovinyl-based monomer, and has a superhigh molecular weight and a nonlinear structure.
Abstract translation: 目的：提供一种苯乙烯基热塑性树脂组合物，其通过采用具有非线性结构的超高分子量SAN共聚物显示出优异的真空模塑性和改进的伸长率和流动性。 构成：热塑性树脂组合物含有20〜50重量％的接枝共聚物，该接枝共聚物通过将30〜70重量％的芳香族乙烯基系单体和氰乙烯基系单体的混合物接枝聚合30〜70重量％ 丁二烯系橡胶，平均分子量为50,000〜100,000; 40-70重量％的苯乙烯 - 丙烯腈共聚物，其通过共聚50-90重量％的芳族乙烯基类单体和10-50重量％的氰基乙烯基类单体而制备，并且具有100,000的平均重量分子量 300,000; 和0.1-30重量％的共聚物，所述共聚物通过将0.01-5重量份的多官能硫醇和0.005-5重量份的多官能丙烯酸类单体加入到100重量份的包含50- 90重量％的芳族乙烯基类单体和10-50重量％的氰乙烯基类单体，并且具有超高分子量和非线性结构。
-
公开(公告)号：KR1020030051990A
公开(公告)日：2003-06-26
申请号：KR1020010081715
申请日：2001-12-20
Applicant: 제일모직주식회사
IPC: C08L51/04
CPC classification number: C08L51/04 , C08J2300/22 , C08K5/37 , C08L25/12 , C08L55/02
Abstract: PURPOSE: Provided is a styrene based thermoplastic resin composition having excellent high temperature stretchability which uses a multi-functional vinyl benzene compound and a mixture of dodecyl mercaptan and a multi-functional mercaptan. CONSTITUTION: The styrene based thermoplastic resin composition comprises 10 to 50 wt% of a graft copolymer, 40 to 80 wt% of vinyl cyanide-aromatic vinyl copolymer; and 0.5 to 50 wt% of a super high molecular weight polymer. The graft copolymer is produced by emulsion polymerization of 30 to 60 weight parts of polybutadiene latex having a rubber particle size of 1000 to 5000 angstrom, 10 to 30 weight parts of acrylonitrile and 70 to 90 weight parts of styrene. The vinyl cyanide-aromatic vinyl copolymer is produced by polymerization of 20 to 40 weight parts of a vinyl cyanide compound and 60 to 80 weight parts of an aromatic vinyl compound. the super high molecular weight copolymer is produced by introducing 0.01 to 2.0 weight parts of multifunctional vinyl benzene compound and 0.01 to 2.0 weight parts of a mixture of dodecyl mercaptan and a multi-functional mercaptan, based on 100 weight parts of a monomer mixture of 20 to 40 weight parts of a vinyl cyanide compound and 60 to 80 weight parts of an aromatic vinyl compound.
Abstract translation: 目的：提供使用多官能乙烯基苯化合物和十二烷基硫醇与多功能硫醇的混合物的具有优异的高温伸缩性的苯乙烯类热塑性树脂组合物。 构成：苯乙烯类热塑性树脂组合物含有10〜50重量％的接枝共聚物，40〜80重量％的乙烯基氰化物 - 芳香族乙烯基共聚物; 和0.5〜50重量％的超高分子量聚合物。 接枝共聚物通过30〜60重量份橡胶粒径为1000〜5000埃的聚丁二烯胶乳，10〜30重量份丙烯腈，70〜90重量份苯乙烯的乳液聚合制造。 乙烯基氰化物 - 芳族乙烯基共聚物通过聚合20至40重量份的乙烯基氰化合物和60至80重量份的芳族乙烯基化合物来制备。 基于100重量份的20重量份的单体混合物，通过引入0.01〜2.0重量份的多官能乙烯基苯化合物和0.01〜2.0重量份的十二烷基硫醇和多官能硫醇的混合物来制造超高分子量共聚物 至40重量份的乙烯基氰化合物和60至80重量份的芳族乙烯基化合物。
-
-
-
-
-
-
-
-
-
Search Results
24
records
(took 0.025 seconds)
