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公开(公告)号：KR100513980B1
公开(公告)日：2005-09-09
申请号：KR1020020086381
申请日：2002-12-30
Applicant: 제일모직주식회사
IPC: C08F212/08
Abstract: 본 발명의 난연성 스티렌계 열가소성 수지 조성물은 (A) 고무와 방향족 모노알케닐 단량체 및/또는 알킬 에스테르 단량체를 혼합하여 중합시켜 제조된 고무강화 폴리스티렌수지 100 중량부; (B) 테트라 브로모 비스페놀 A 비스(2,3-디브로모프로필 에테르) 화합물 1 내지 5 중량부; (C) 2,4,6-트리(2,4,6-트리브로모페녹시)-1,3,5-트리아진 화합물 5 내지 10 중량부; 및 (D) 난연 보조제 1 내지 3 중량부로 이루어지는 것을 특징으로 한다.
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公开(公告)号：KR1020050070922A
公开(公告)日：2005-07-07
申请号：KR1020030101519
申请日：2003-12-31
Applicant: 제일모직주식회사
Abstract: 본 발명의 난연성 스티렌계 열가소성 수지 조성물은 (A) 고무와 방향족 모노알케닐 단량체 및/또는 알킬 에스테르 단량체를 혼합하여 중합시켜 제조된 고무강화 폴리스티렌수지 100 중량부; (B) 테트라브로모비스페놀 A의 디글리시딜 에테르 중합체인 브롬화에폭시수지 화합물 10 내지 20 중량부; (C) 2,4,6-트리(2,4,6-트리브로모페녹시)-1,3,5-트리아진 화합물 3 내지 10 중량부; 및 (D) 난연 보조제 3 내지 7 중량부로 이루어지는 것을 특징으로 한다.
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公开(公告)号：KR1020050049786A
公开(公告)日：2005-05-27
申请号：KR1020030083519
申请日：2003-11-24
Applicant: 제일모직주식회사
Abstract: 본 발명의 난연성 스티렌계 열가소성 수지 조성물은 (A) 고무와 방향족 모노알케닐 단량체 및/또는 알킬 에스테르 단량체를 혼합하여 중합시켜 제조된 고무강화 폴리스티렌수지 100 중량부; (B) 브롬화 에폭시 올리고머(brominated epoxy oligomer) 화합물 10 내지 15 중량부 ; 및 (C) 난연 보조제 1 내지 3 중량부로 이루어지는 것을 특징으로 한다.
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公开(公告)号：KR100443364B1
公开(公告)日：2004-08-09
申请号：KR1020020025877
申请日：2002-05-10
Applicant: 제일모직주식회사
Abstract: PURPOSE: Provided is a fire-retardant styrene-based resin composition, which is excellent in fire retardancy, weather resistance, and heat stability and can be used at high temperature. CONSTITUTION: The fire-retardant styrene-based resin composition comprises 100pts.wt. of a rubber-reinforced polystyrene resin produced by polymerizing a rubber and an aromatic monoalkenyl monomer and/or an alkyl ester monomer, wherein the rubber is selected from the group consisting of a butadiene rubber, an isoprene rubber, a copolymer of butadiene and styrene, and an alkylacrylated rubber; 1-5pts.wt. of 2,2-bis(4-2-3-dibromopropoxy)'-3,5-dibromophenyl propane(formula I); 5-10pts.wt. of 2,4,6-tri(2,4,6-tribromophenoxy)-1,3,5-triazine(formula II); and 0.5-5pts.wt. of a fire-retardant selected from the group consisting of antimony trioxide, chlorinated paraffin, potassium sulfone sulfate, and a mixture thereof.
Abstract translation: 目的：提供一种阻燃苯乙烯基树脂组合物，其具有优异的阻燃性，耐候性和热稳定性，并且可以在高温下使用。 构成：阻燃苯乙烯基树脂组合物包含100重量份。 的由橡胶和芳族单链烯基单体和/或烷基酯单体聚合生产的橡胶增强聚苯乙烯树脂，其中所述橡胶选自丁二烯橡胶，异戊二烯橡胶，丁二烯和苯乙烯的共聚物， 和烷基丙烯酸酯橡胶; 1-5pts.wt。 的2,2-双（4-2-3-二溴丙氧基）-1,3,5-二溴苯丙烷（式I）; 5-10pts.wt。 2,4,6-三（2,4,6-三溴苯氧基）-1,3,5-三嗪（式II）; 和0.5-5pts.wt。 的选自三氧化锑，氯化石蜡，硫酸钾硫酸钾及其混合物的阻燃剂。
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公开(公告)号：KR1020030087492A
公开(公告)日：2003-11-14
申请号：KR1020020025877
申请日：2002-05-10
Applicant: 제일모직주식회사
CPC classification number: C08K5/03 , C08J2300/22 , C08K5/3492 , C08L25/10 , C08L2201/02 , C08L2201/08
Abstract: PURPOSE: Provided is a fire-retardant styrene-based resin composition, which is excellent in fire retardancy, weather resistance, and heat stability and can be used at high temperature. CONSTITUTION: The fire-retardant styrene-based resin composition comprises 100pts.wt. of a rubber-reinforced polystyrene resin produced by polymerizing a rubber and an aromatic monoalkenyl monomer and/or an alkyl ester monomer, wherein the rubber is selected from the group consisting of a butadiene rubber, an isoprene rubber, a copolymer of butadiene and styrene, and an alkylacrylated rubber; 1-5pts.wt. of 2,2-bis(4-2-3-dibromopropoxy)'-3,5-dibromophenyl propane(formula I); 5-10pts.wt. of 2,4,6-tri(2,4,6-tribromophenoxy)-1,3,5-triazine(formula II); and 0.5-5pts.wt. of a fire-retardant selected from the group consisting of antimony trioxide, chlorinated paraffin, potassium sulfone sulfate, and a mixture thereof.
Abstract translation: 目的：提供阻燃苯乙烯类树脂组合物，其阻燃性，耐候性和热稳定性优异，可以在高温下使用。 构成：阻燃苯乙烯类树脂组合物含有100pts.wt。 通过聚合橡胶和芳族单烯基单体和/或烷基酯单体制备的橡胶增强聚苯乙烯树脂，其中橡胶选自丁二烯橡胶，异戊二烯橡胶，丁二烯和苯乙烯的共聚物， 和烷基丙烯酸酯化橡胶; 1-5pts.wt。 的2,2-双（4-2,3-二溴丙氧基）' - 3,5-二溴苯基丙烷（式I）; 5-10pts.wt。 的2,4,6-三（2,4,6-三溴苯氧基）-1,3,5-三嗪（式II）; 和0.5-5pts.wt。 的阻燃剂，其选自三氧化锑，氯化石蜡，硫酸钾砜及其混合物。
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Patent Agency Ranking
公开(公告)号：KR1020030055445A
公开(公告)日：2003-07-04
申请号：KR1020010084984
申请日：2001-12-26
Applicant: 제일모직주식회사
CPC classification number: C08L55/02 , C08J2300/22 , C08K5/005 , C08L25/12 , C08L2201/02 , C08L2205/025 , C08L2207/324
Abstract: PURPOSE: A thermoplastic resin composition is provided, which is improved in tensile strength, elongation and heat resistance and is useful as the housing of an electronic product and the interior and exterior material of an automobile. CONSTITUTION: The thermoplastic resin composition comprises (A) 5-30 parts by weight of an ABS resin comprising (a1) 40-47 wt% of a graft ABS resin prepared by graft copolymerizing a small particle size rubber with an average particle size of 0.08-0.18 micrometers and (a2) 53-60 wt% of a graft ABS resin prepared by graft copolymerizing a medium particle size rubber with an average particle size of 0.28-0.38 micrometers; and (B) 25-45 parts by weight of an SAN resin comprising (b1) an N-(substituted) maleimide copolymer and (b2) a low molecular weight SAN resin. The N-(substituted) maleimide copolymer(b1) comprises 40-60 wt% of an N-(substituted) maleimide monomer and maleic anhydride and 40-60 wt% of an aromatic vinyl monomer; and the low molecular weight SAN resin(b2) comprises 65-78 wt% of styrene and 22-35 wt% of acrylonitrile and has a weight average molecular weight of 80,000-120,000.
Abstract translation: 目的：提供一种热塑性树脂组合物，其拉伸强度，伸长率和耐热性得到改善，并且可用作电子产品的外壳和汽车的内部和外部材料。 构成：热塑性树脂组合物包含（A）5-30重量份的ABS树脂，其包含（a1）40-47重量％的通过接枝共聚平均粒径为0.08的小粒径橡胶制备的接枝ABS树脂 -0.18微米和（a2）53-60重量％的通过接枝共聚平均粒度为0.28-0.38微米的中等粒径橡胶制备的接枝ABS树脂; 和（B）25-45重量份的包含（b1）N-（取代的）马来酰亚胺共聚物和（b2）低分子量SAN树脂的SAN树脂。 N-（取代的）马来酰亚胺共聚物（b1）包含40-60重量％的N-（取代的）马来酰亚胺单体和马来酸酐和40-60重量％的芳族乙烯基单体; 并且低分子量SAN树脂（b2）包含65-78重量％的苯乙烯和22-35重量％的丙烯腈，其重均分子量为80,000-120,000。
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公开(公告)号：KR100602849B1
公开(公告)日：2006-07-19
申请号：KR1020030101519
申请日：2003-12-31
Applicant: 제일모직주식회사
Abstract: 본 발명의 난연성 스티렌계 열가소성 수지 조성물은 (A) 고무와 방향족 모노알케닐 단량체 및/또는 알킬 에스테르 단량체를 혼합하여 중합시켜 제조된 고무강화 폴리스티렌수지 100 중량부; (B) 테트라브로모비스페놀 A의 디글리시딜 에테르 중합체인 브롬화에폭시수지 화합물 10 내지 20 중량부; (C) 2,4,6-트리스(2,4,6-트리브로모페녹시)-1,3,5-트리아진 화합물 3 내지 10 중량부; 및 (D) 난연 보조제 3 내지 7 중량부로 이루어지는 것을 특징으로 한다.
난연성 스티렌계 열가소성 수지조성물, 2,4,6-트리스(2,4,6-트리브로모페녹시)-1,3,5-트리아진, 브롬화에폭시 수지계 화합물, 난연 보조제, 삼산화 안티몬-
公开(公告)号：KR1020040042354A
公开(公告)日：2004-05-20
申请号：KR1020020070626
申请日：2002-11-14
Applicant: 제일모직주식회사
IPC: C08L25/10 , C08L63/00 , C08L25/06 , C08K5/3492
CPC classification number: C08L25/10 , C08J5/00 , C08J2300/22 , C08K5/3492 , C08L63/00 , C08L2201/02
Abstract: PURPOSE: A styrene-based resin composition and a molded product prepared by using the composition are provided, to improve flame resistance and thermal stability. CONSTITUTION: The styrene-based resin composition comprises 100 parts by weight of a rubber reinforced polystyrene resin; 1-5 parts by weight of a brominated epoxy oligomer represented by the formula I; 5-10 parts by weight of 2,4,6-tri(2,4,6-tribromophenoxy)-1,3,5-triazine represented by the formula II; and 0.5-5 parts by weight of a flame-resistant material. Preferably the rubber part of the rubber reinforced polystyrene resin is selected from the group consisting of butadiene-based rubbers, isoprene-based rubbers, butadiene-styrene copolymer-based rubbers and alkyl acrylate-based rubbers; and the monomer of the polystyrene resin is selected from the group consisting of aromatic monoalkenyl monomers, alkyl ester monomers of acrylic acid or methacrylic acid and their mixtures.
Abstract translation: 目的：提供苯乙烯类树脂组合物和使用该组合物制备的成型体，以提高阻燃性和热稳定性。 构成：苯乙烯类树脂组合物包含100重量份的橡胶增强聚苯乙烯树脂; 1-5重量份由式I表示的溴化环氧低聚物; 5-10重量份由式II表示的2,4,6-三（2,4,6-三溴苯氧基）-1,3,5-三嗪; 和0.5-5重量份的阻燃材料。 优选地，橡胶增强聚苯乙烯树脂的橡胶部分选自丁二烯基橡胶，异戊二烯橡胶，丁二烯 - 苯乙烯共聚物基橡胶和丙烯酸烷基酯橡胶; 聚苯乙烯树脂的单体选自芳族单烯基单体，丙烯酸或甲基丙烯酸的烷基酯单体及其混合物。
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公开(公告)号：KR1020040060029A
公开(公告)日：2004-07-06
申请号：KR1020020086541
申请日：2002-12-30
Applicant: 제일모직주식회사
CPC classification number: C08L25/10 , C08K3/22 , C08K5/03 , C08K2003/2282 , C08L2201/02 , C08L2205/025
Abstract: PURPOSE: Provided is a flame retardant styrene-based resin composition, which has excellent appearance, impact strength, thermal stability and flowability. CONSTITUTION: The flame retardant styrene-based resin composition comprises: (A) 100 parts by weight of a rubber-reinforced polystyrene resin consisting of (a1) 50-90 wt% of a rubber-reinforced polystyrene resin having an average rubber particle diameter of 0.2-0.8 micrometers and (a2) 50-10 wt% of a rubber-reinforced polystyrene resin having an average rubber particle diameter of 2.0-3.0 micrometers; (B) 5-30 parts by weight of a halogen-containing flame retardant; (C) 1-10 parts by weight of antimony trioxide; (D) 0.5-10 parts by weight of an impact reinforcing agent based on styrene-butadiene; and (E) 0.1-5 parts by weight of an olefin-based lubricant.
Abstract translation: 目的：提供具有优异的外观，冲击强度，热稳定性和流动性的阻燃苯乙烯类树脂组合物。 构成：阻燃苯乙烯类树脂组合物包含：（A）100重量份由（a1）50-90重量％的橡胶增强聚苯乙烯树脂组成的橡胶增强聚苯乙烯树脂，其橡胶粒径平均值为 0.2〜0.8微米，（a2）50-10重量％的橡胶增强聚苯乙烯树脂，其平均橡胶粒径为2.0-3.0微米; （B）5-30重量份含卤阻燃剂; （C）1-10重量份三氧化锑; （D）0.5-10重量份基于苯乙烯 - 丁二烯的冲击增强剂; 和（E）0.1-5重量份的烯烃基润滑剂。
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公开(公告)号：KR100431538B1
公开(公告)日：2004-05-12
申请号：KR1020010084984
申请日：2001-12-26
Applicant: 제일모직주식회사
Abstract: PURPOSE: A thermoplastic resin composition is provided, which is improved in tensile strength, elongation and heat resistance and is useful as the housing of an electronic product and the interior and exterior material of an automobile. CONSTITUTION: The thermoplastic resin composition comprises (A) 5-30 parts by weight of an ABS resin comprising (a1) 40-47 wt% of a graft ABS resin prepared by graft copolymerizing a small particle size rubber with an average particle size of 0.08-0.18 micrometers and (a2) 53-60 wt% of a graft ABS resin prepared by graft copolymerizing a medium particle size rubber with an average particle size of 0.28-0.38 micrometers; and (B) 25-45 parts by weight of an SAN resin comprising (b1) an N-(substituted) maleimide copolymer and (b2) a low molecular weight SAN resin. The N-(substituted) maleimide copolymer(b1) comprises 40-60 wt% of an N-(substituted) maleimide monomer and maleic anhydride and 40-60 wt% of an aromatic vinyl monomer; and the low molecular weight SAN resin(b2) comprises 65-78 wt% of styrene and 22-35 wt% of acrylonitrile and has a weight average molecular weight of 80,000-120,000.
Abstract translation: 目的：提供一种热塑性树脂组合物，其具有提高的拉伸强度，伸长率和耐热性，并且可用作电子产品的外壳和汽车的内部和外部材料。 本发明的热塑性树脂组合物包含：（A）5-30重量份的ABS树脂，其包含（a1）40-47重量％的接枝ABS树脂，所述接枝ABS树脂通过将平均粒度为0.08的小粒度橡胶 -0.18微米和（a2）53-60重量％的通过接枝共聚平均粒度为0.28-0.38微米的中等粒度橡胶制备的接枝ABS树脂; 和（B）25-45重量份包含（b1）N-（取代）马来酰亚胺共聚物和（b2）低分子量SAN树脂的SAN树脂。 N-取代马来酰亚胺共聚物（b1）包含40-60重量％的N-取代的马来酰亚胺单体和马来酸酐以及40-60重量％的芳族乙烯基单体; 并且低分子量SAN树脂（b2）包含65-78重量％的苯乙烯和22-35重量％的丙烯腈并具有80,000-120,000的重均分子量。
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